Speleogenesis of an exhumed hydrothermal sulphuric acid karst in Cambrian carbonates (Mount San Giovanni,Sardinia)

In the past few years the systematic study of caves intercepted by mine workings in southwest Sardinia has permitted us to observe morphologies due to rare speleogenetic and minerogenetic processes related to ancient hydrothermal activity. These relic morphologies are slowly being overprinted by recent speleogenetic processes that tend to obscure the hypogene origin of these caves. A combined geomorphological and mineralogical investigation has permitted a fairly detailed reconstruction of the various phases of evolution of these caves. Cave formation had already started in Cambrian times, but culminated in the Carboniferous, when most of the large voids still accessible today were formed. A key role in carbonate dissolution was played by sulphuric acid formed by the oxidation of the polymetallic ores present in the rocks since the Cambrian. During the Quaternary a variety of minerals formed inside the caves: calcite and aragonite, that yielded sequences of palaeo‐environmental interest, and also barite, phosgenite, hydrozincite, hemimorphite and many others. These minerals are in part due to a phreatic thermal hypogenic cave forming phase, and in part to later epigene overprinting in an oxidizing environment rich in polymetallic ores. Massive gypsum deposits, elsewhere typical of this kind of caves, are entirely absent due to dissolution during both the phreatic cave formation and the later epigenic stage. Copyright © 2013 John Wiley & Sons, Ltd.     

Bank erosion in agricultural drainage networks: new challenges from structure‐from‐motion photogrammetry for post‐event analysis

Drainage channels are an integral part of agricultural landscapes, and their impact on catchment hydrology is strongly recognized. In cultivated and urbanized floodplains, channels have always played a key role in flood protection, land reclamation, and irrigation. Bank erosion is a critical issue in channels. Neglecting this process, especially during flood events, can result in underestimation of the risk in flood‐prone areas. The main aim of this work is to consider a low‐cost methodology for the analysis of bank erosion in agricultural drainage networks, and in particular for the estimation of the volumes of eroded and deposited material. A case study located in the Veneto floodplain was selected. The research is based on high‐resolution topographic data obtained by an emerging low‐cost photogrammetric method (structure‐from‐motion or SfM), and results are compared to terrestrial laser scanning (TLS) data. For the SfM analysis, extensive photosets were obtained using two standalone reflex digital cameras and an iPhone5® built‐in camera. Three digital elevation models (DEMs) were extracted at the resolution of 0.1 m using SfM and were compared with the ones derived by TLS. Using the different DEMs, the eroded areas were then identified using a feature extraction technique based on the topographic parameter Roughness Index (RI). DEMs derived from SfM were effective for both detecting erosion areas and estimating quantitatively the deposition and erosion volumes. Our results underlined how smartphones with high‐resolution built‐in cameras can be competitive instruments for obtaining suitable data for topography analysis and Earth surface monitoring. This methodology could be potentially very useful for farmers and/or technicians for post‐event field surveys to support flood risk management. Copyright © 2015 John Wiley & Sons, Ltd.     

Speciation and role of iron in cloud droplets at the puy de Dôme station

Iron is the most abundant transition metal in the atmosphere and can play a significant role in cloudwater chemistry where its reactivity is closely related to the partitioning between Fe(II) and Fe(III). The objective of this work is to determine the total iron content and the iron speciation in a free tropospheric site, and to understand which factors influence these parameters. We collected 147 samples of cloudwater during 34 cloud events over a period of four years at the puy de Dôme summit. Besides iron we measured other chemical compounds, solar radiation, physico-chemical and meteorological parameters potentially connected with iron reactivity. The total iron concentrations ranged from 0.1 to 9.1 μM with the major frequency occurring at low levels. The pH and presence of organic complexants seem to be the most significant factors connected with total dissolved iron; while the iron oxidation state seems to be an independent factor. Light intensity, presence of complexants or oxidants (H₂O₂) do not influence the Fe(II)/Fe(Total) ratio, that was quite constant at about 0.75. This could be due to the potential redox that forces the Fe(II)-Fe(III) couple to the reduced form or, more probably to the complexation by Natural Organic Matter, that can stabilize iron in its reduced form and prevent further oxidation. Our field measurements did not show the diurnal cycle observed in surface water and predicted by models of atmospheric chemistry. This result prompts a more careful review of the role of iron and, by analogy, all the transition metals in atmospheric liquid phase, often over-estimated in the literature.     

On the misinterpretation of the North Atlantic Oscillation in CMIP5 models

The representation of the wintertime North Atlantic Oscillation (NAO) and its relationship with atmospheric blocking and the Atlantic jet stream is investigated in a set of CMIP5 models. It is shown that some state-of-the-art climate models are unable to correctly simulate the physical processes connected to the NAO. This is especially true for models with a strongly underestimated frequency of high-latitude blocking over Greenland. In these models the first empirical orthogonal function (EOF1) of the Euro-Atlantic sector can represent at least three different categories of dominant modes of variability associated with different prevalent regions of blocking occurrence and jet stream displacements. It is therefore possible to show that such “biased NAOs” are connected with different dynamical processes with respect to the canonical NAO seen in observations. Since the NAO is a widely used concept in scientific community, the consequent “dynamical misinterpretation” of the NAO that can result when climate models are analyzed may have important implications for the NAO-related studies. This may be especially relevant for the ones involving climate scenarios, since these modeled NAOs may react differently to greenhouse gas forcing.     

On the displacement of marked pebbles on two coarse-clastic beaches during short fair-weather periods (Marina di Pisa and Portonovo, Italy)

The aim of the investigation was to define the mechanisms of sediment transport in the swash zone of microtidal coarse-clastic beaches in the very short term by evaluating the displacement rates of marked pebbles under low-energy wave conditions. Tests were performed at two sites (Marina di Pisa, Ligurian Sea, and Portonovo, central Adriatic Sea) to check the consistency of the data over a range of different grain sizes. Two recovery campaigns were carried out at both sites, one 6 h and the other 24 h after the injection. During the experiments wave action was at a minimum (wave heights never exceeded 0.3 m). The results show that 20% of pebbles ranging in diameter from 30–90 mm moved significantly (more than 0.5 m) already 6 h after the injection, with some tracers being lost (3%). After 24 h, 40% of the pebbles were significantly displaced and 10% were lost. The preferential downslope movement of tracers, which suggests that coarse sediment movement under low-energy conditions is mainly controlled by gravity processes enhanced by steep beachface slopes, represents the novelty of the results reported here. It would appear that swash processes on low-energy beaches cause a significant rate of pebble displacement through the destabilization induced by wave uprush and backwash. Despite the microtidal range, the position of the mean water level plays a major role in changing the beach level at which swash processes can actually trigger pebble movement. The results of this study show that considerable, and mostly seaward-directed, coarse sediment transport takes place even during short fair-weather periods.     

Correlations of cosmic tidal fields

We study correlations amongst tidal fields originated by the large-scale distribution of matter in the Universe. The two-point tidal correlation is described as a rank-4 tensor, the elements of which can be written in terms of four fundamental scalar functions ranging, with respect to the spatial separation, from purely transversal to purely longitudinal correlations. Tidal fields, on both galaxy and cluster scales, are revealed to be correlated over distances larger than the mass–density correlation length, although traceless tidal fields show anti-correlation between diagonal terms along orthogonal directions. The cross-correlation between mass and tidal field is also analysed. These results are relevant for galaxy formation and the interpretation of large-scale weak lensing phenomena.     

Development of Kinetic Inductance Detectors for Cosmic Microwave Background experiments

We describe the design, optimization, electrical and optical tests of Microwave Kinetic Inductance Detectors (MKIDs) for the mm-wave range. Our detectors are based on a novel resonator design, and are suitable for ground-based astronomical observations in the 143 GHz atmospheric window. The measured optical Noise Equivalent Power (NEP) at 0.3 K is $\sim 10^{-16}~\text{W}/\sqrt{\rm Hz}$ under a 300 K background load. This is equivalent or better than the performance of the best current bolometric detectors for the 140 GHz atmospheric window, limited by atmospheric noise in the best available sites. We also describe which improvements can be introduced to reduce the NEP of our detector, for lower background applications (narrow band or space-based).     

From river to shelf,anatomy of a high‐frequency depositional sequence: The Late Pleistocene to Holocene Tiber depositional sequence

The Late Pleistocene/Holocene Tiber delta succession represents the most recent and one of the best preserved, high‐frequency/low‐rank depositional sequences developed along the Latium continental margin of the Italian peninsula. Several previous studies have established a robust data set from which it has been possible to describe the stratigraphic architecture of the entire Tiber depositional sequence from the landward to seaward sectors and over a distance of 60 km. The Tiber depositional sequence shows many characteristics found in other Late Pleistocene to Holocene deltaic and coastal successions of the Mediterranean area. The stratigraphic architecture of the Tiber depositional sequence is controlled mainly by glacioeustasy, although factors such as tectonic uplift, volcanism and subsidence, exert an influence at a local scale. The resulting depositional model allowed discussion of some important points such as: (1) the genesis of the Tiber mixed bedrock‐alluvial valley, extending from the coastal plain to the innermost portion of the shelf, recording (i) multiple episodes of incision during relative sea‐level fall, and (ii) a downstream increase of depth and width of the valley during the base‐level fall and the subsequent base‐level rise; (2) the different physical expression of the Tiber depositional sequence boundary from landward to seaward, and its diachronous and composite character; (3) the maximum depth reached by the Tiber early lowstand delta at the end of the sea‐level fall is estimated at ca 90 m below the present sea‐level and not at 120 m as suggested by previous works; (4) the backward position of the Tiber late lowstand delta relative to the deposit of early lowstand; (5) the change of the channel pattern and of the stacking pattern of fluvial deposits within the Lowstand Systems Tract, Transgressive Systems Tract and Highstand Systems Tract. All of these features indicate that the Late Pleistocene/Holocene Tiber delta succession, even if deposited in a short period of time from a geological point of view, represents the result of the close interaction among many autogenic and allogenic factors. However, global eustatic variations and sediment supply under the control of climatic changes can be considered the main factors responsible for the stratigraphic architecture of this sedimentary succession, which has been heavily modified by human activity only in the last 3000 years.     

Comparing the adequacy of alternative ground motion intensity measures for the estimation of structural responses

Practical methods for the probability‐based seismic assessment of structures make use of estimates of demands produced by earthquakes of different intensities. The uncertainties associated with these estimates are highly dependent on the variable adopted as the intensity measure (IM, e.g., PGA, spectral acceleration, etc.). This generates the need to compare the efficiency of an originally adopted IMwith that of a new candidate. This implies comparing the dispersion of the demand measure (DM, e.g., maximum interstorey drift ratio, ductility demand, etc.) conditional to each of the two IMs. In order to obtain the demand estimates in a conventional way, a full set of dynamic response analyses should be performed for each IM under scrutiny, i.e., multiple records scaled at several fixed values of each IM. The procedure developed here serves to accelerate this comparison avoiding the effort required to evaluate the dynamic responses of the structure for all the ground motion time histories considered every time that a new IM is adopted. For this purpose, use is made of available results of analyses performed for a different (i.e., the original) IM. Two methods are proposed: the direct method involves performing a regression of the results obtained from the original analyses, taking the candidate IM as the independent variable. The indirect method involves rebuilding the probability density function of the DM given a defined value of the candidate IM by means of the total probability theorem, using the results of the original analyses and certain data relating the two IMs. The proposed methods have been tested by application to several SDOF systems with different periods and different cyclic‐response backbone curves. The conditions affecting their approximation are explored, and some criteria to improve them are identified. The procedure can also be used to determine the optimum value of a parameter to be used in a parameter‐based IM. Copyright © 2004 John Wiley & Sons, Ltd.