Sediment yield and storage variations in the Négron River catchment (south western Parisian Basin,France) during the Holocene period

In the Négron River catchment area (162 km²), surface‐sediment stores are composed of periglacial calcareous ‘grèze’ (5 × 10⁶ t) and loess (21 × 10⁶ t), and Holocene alluvium (12·6 × 10⁶ t), peat (0·6 × 10⁶ t) and colluvium (18·5 × 10⁶ t). Seventy‐five per cent of the Holocene sediments is stored along the thalwegs. Present net sediment yield, calculated from solid discharge at the Négron outlet, is low (0·6 t km^?2 a^?1) due to the dominance of carbonate rocks in the catchment. Mean sediment yield during the Holocene period is 7·0 t km^?2 a^?1 from alluvium stores and 7·6 t km^?2 a^?1 from colluvium stores. Thus, the gross sediment yield during the Holocene period is about 18·7 t km^?2 a^?1 and the sediment delivery ratio 3 per cent. The yield considerably varies from one sub‐basin to another (3·9 to 24·5 t km^?2 a^?1) according to lithology: about 25 per cent and 50 per cent of initial stores of periglacial grèze and loess respectively were reworked during the Holocene period. Sediment yield has increased by a factor of 6 in the last 1000 years, due to the development of agriculture. The very high rate of sediment storage on the slope during that period (88 per cent of the yield) can be accounted for by the formation of cultivation steps (‘rideaux’). It is predicted that the current destruction of these steps will result in a sediment wave reaching the valley floors in the coming decades. Subboreal and Subatlantic sediments and pollen assemblages in the Taligny marsh, where one‐third of the alluvium is stored, show the predominant influence of human activity during these periods in the Négron catchment. Copyright © 2002 John Wiley & Sons, Ltd.     

重力场数学拟合模型解的影响因素探究

为了提高地球重力场模型不适定方程求解的精度,该文采用谱分析方法从级数展开阶数、数据采样率及数据缺失量3个方面探索影响数学拟合效果的根本因素:从常用的三角级数及勒让德级数模型出发,引出重力场拟合模型球谐函数模型,观察在改变级数展开阶数、数据采样率及数据缺失量等情况下所对应设计矩阵谱结构的变化,并从微观上研究影响误差分配的有关因素及最小奇异值对误差的决定性作用,为探求重力场模型解不准的原因及实现更高精度的全球重力场模型的建立提供参考。     

Elastoplastic model with loading memory surfaces (LMS) for monotonic and cyclic behaviour of geomaterials

A new elastoplastic model called loading memory surface based on the critical state concept and the multi‐surface framework is proposed for geomaterials. The model uses a hypoelastic formulation and two plastic mechanisms. The formulations of the model are made in three‐dimensional stress–strain space and work under both monotonic and cyclic loadings. A newly introduced formalism makes it possible to obtain the cyclic response directly from the monotonic loading one. This formalism gives a three‐dimensional generalization of the well‐known Masing rule. The model has been validated against test results of Hostun sand under several conditions: monotonic and cyclic, drained and undrained, tests in compression and in extension, and at different confining pressures and different densities. Copyright © 2014 John Wiley & Sons, Ltd.     

基于互信息量与BP神经网络的中长期径流预报方法研究

针对中长期径流预报因子的选择问题,采用互信息量方法筛选预报模型输入因子,在BP神经网络模型中,分别用均方误差和互信息量作为目标函数,衡量因子复合相关关系,优化选择最终预报因子并应用于碧流河汛期径流预报中。结果表明,基于互信息量筛选的预报因子与BP神经网络模型相结合,可有效识别多个预报因子与预报量间的复合相关性,对中长期径流预报因子的选择有很好参考价值。     

Short Term and Short Range Seismicity Patterns in Different Seismic Areas of the World

The aim of this work is to quantitatively set up a simple hypothesis for occurrence of earthquakes conditioned by prior events, on the basis of a previously existing model and the use of recent instrumental observations. A simple procedure is presented in order to determine the conditional probability of pairs of events (foreshock-mainshock, mainshock-aftershock) with short time and space separation. The first event of a pair should not be an aftershock, i.e., it must not be related to a stronger previous event. The Italian earthquake catalog of the Istituto Nazionale di Geofisica (ING) (1975–1995, M 3.4), the earthquake catalog of the Japan Meteorological Agency (JMA) (1983–1994, M 3.0) and that of the National Observatory of Athens (NOA) (1982–1994, M 3.8) were analyzed. The number of observed pairs depends on several parameters: the size of the space-time quiescence volume defining nonaftershocks, the inter event time, the minimum magnitude of the two events, and the spatial dimension of the alarm volume after the first event. The Akaike information criterion has been adopted to assess the optimum set of space-time parameters used in the definition of the pairs, assuming that the occurrence rate of subsequent events may be modeled by two Poisson processes with different rates: the higher rate refers to the space-time volume defined by the alarms and the lower one simulates earthquakes that occur in the nonalarm space-time volume. On the basis of the tests carried out on the seismic catalog of Italy, the occurrence rate of M 3.8 earthquakes followed by a M 3.8 mainshock within 10 km and 10 days (validity) is 0.459. We have observed, for all three catalogs, that the occurrence rate density for the second event of a couple (mainshock or aftershock) of magnitude M₂ subsequent to a nonaftershock of magnitude M₁ in the time range T can be modeled by the following relationship: (T, M₂) = 10^{a + b(M1 - M2)} with b varying from 0.74 (Japan) to 1.09 (Greece). The decrease of the occurrence rate in time for a mainshock after a foreshock or for large aftershocks after a mainshock, for all three databases, obeys the Omori's law with p changing from 0.94 (Italy) to 2.0 (Greece).     

Evaluating groundwater resource of an urban alluvial area through the development of a numerical model

As established in the European Water Framework Directive, the development of groundwater numerical models is fundamental for adopting water management plans aimed at preserving the water resource and reducing environmental risks. In this paper, authors present a methodology for the estimation of groundwater resource of an alluvial valley, in an urban area characterized by a complex hydrostratigraphic setting and scarcity of hydrogeological data; the study area is the urban and sub-urban area of Rome (Italy). A previous, elaborated hydrostratigraphic model set the base for the development of 3D, steady state, sub-basin scale numerical model, implemented by the finite-difference code MODFLOW 2000^®; the water system components were derived by elaboration of available data. The alluvial aquifer of the Tiber River Valley, which runs in the middle of the City in a NNW–SE direction, has been analyzed in detail, since it is covered by a densely populated area hosting most of Rome’s historical heritage, and it is characterized by low quality geotechnical parameters. Results suggest that in areas with high hydrostratigraphic complexity and scarcity of hydrogeological data, a sub-basin scale, and steady-state numerical model can be very helpful to verify the conceptual model and reduce the uncertainty on the water budget components. The proposed steady-state model constitutes the base for future applications of transient state and local scale models, required for sustainable water management.     

Experimental calibration of vanadium partitioning and stable isotope fractionation between hydrous granitic melt and magnetite at 800 °C and 0.5 GPa

Vanadium has multiple oxidation states in silicate melts and minerals, a property that also promotes fractionation of its isotopes. As a result, vanadium isotopes vary during magmatic differentiation, and can be powerful indicators of redox processes at high temperatures if their partitioning behaviour can be determined. To quantify the partitioning and isotope fractionation factor of V between magnetite and melt, piston cylinder experiments were performed in which magnetite and a hydrous, haplogranitic melt were equilibrated at 800 °C and 0.5 GPa over a range of oxygen fugacities (\({f_{{{\text{O}}_{\text{2}}}}}\)), bracketing those of terrestrial magmas. Magnetite is isotopically light with respect to the coexisting melt, a tendency ascribed to the VI-fold V³⁺ and V⁴⁺ in magnetite, and a mixture of IV- and VI-fold V⁵⁺ and V⁴⁺ in the melt. The magnitude of the fractionation factor systematically increases with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\) relative to the Fayalite–Magnetite–Quartz buffer (FMQ), from ?⁵¹V_mag-gl = ? 0.63?±?0.09‰ at FMQ ? 1 to ? 0.92?±?0.11‰ (SD) at ≈?FMQ?+?5, reflecting constant V³⁺/V⁴⁺ in magnetite but increasing V⁵⁺/V⁴⁺ in the melt with increasing log\({f_{{{\text{O}}_{\text{2}}}}}\). These first mineral-melt measurements of V isotope fractionation factors underline the importance of both oxidation state and co-ordination environment in controlling isotopic fractionation. The fractionation factors determined experimentally are in excellent agreement with those needed to explain natural isotope variations in magmatic suites. Furthermore, these experiments provide a useful framework in which to interpret vanadium isotope variations in natural rocks and magnetites, and may be used as a potential fingerprint the redox state of the magma from which they crystallise.     

阿尔金南缘阿克提山岩体锆石U- Pb定年、Hf同位素特征及构造意义

阿克提山花岗岩体位于阿尔金断裂南缘,其形成时代与区域内其他花岗岩体差异较大,该岩体走向明显地受阿尔金断裂带分支断裂控制。锆石LA-ICP-MS U-Pb年代学分析表明,该岩体结晶年龄约为262Ma,其形成可能与南阿尔金地区在华力西期-印支期发生的大规模线性构造运动有关。岩体的岩性主要为石英闪长岩、花岗闪长岩,其暗色矿物以角闪石、黑云母为主,岩石A/CNK值均小于1.1,显示准铝质—弱过铝质特征,属于高钾钙碱性系列;大离子亲石元素Rb、Th、K相对富集,高场强元素Nb、Ta、P、Sr、Ti明显呈负异常;稀土元素配分曲线具有中等负Eu异常,δEu的平均值为0.73,(La/Yb)_N平均值为14.57,说明该花岗岩体岩浆部分熔融程度较高。根据岩石学及地球化学特征可判断该岩体为I型花岗岩。锆石Lu-Hf同位素分析表明,锆石ε_(Hf)(t)值为+1.46～+9.14,均为正值,二阶段模式年龄的峰值平均为943Ma,表明其源岩主要为新元古代新生地壳物质的部分熔融。阿尔金断裂在印支期的走滑运动是从地壳深部的韧性变形开始的,随后在浅地表发生脆性断裂形成大规模走滑断裂带。阿克提山岩体的形成与地壳深部减压熔融有关。     

Geochemistry of igneous rocks associated with ultramafic–mafic-hosted Cu (Co, Ni, Au) VMS deposits from the Main Uralian Fault (Southern Urals, Russia)

Ultramafic–mafic- and ultramafic-hosted Cu (Co, Ni, Au) volcanogenic massive sulfide (VMS) deposits from ophiolite complexes of the Main Uralian Fault, Southern Urals, are associated with island arc-type igneous rocks. Trace element analyses show that these rocks are geochemically analogous to Early Devonian boninitic and island arc tholeiitic rocks found at the base of the adjacent Magnitogorsk volcanic arc system, while they are distinguished both from earlier, pre-subduction volcanic rocks and from later volcanic products that were erupted in progressively more internal arc settings. The correlation between the sulfide host-rocks and the earliest volcanic units of the Magnitogorsk arc suggests a connection between VMS formation and infant subduction-driven intraoceanic magmatism.     

Phosphate defects and apatite inclusions in coral skeletal aragonite revealed by solid-state NMR spectroscopy

Recent development of paleo-nutrient proxies based on the phosphorus/calcium (P/Ca) ratio in tropical- and deep-water corals (also known as cold-water corals) require an understanding of the processes by which P is incorporated into the coral skeletal aragonite. Here, we apply single- and double-resonance solid-state nuclear magnetic resonance (NMR) spectroscopy to determine the speciation of P in coral aragonite. The results show that the majority of P occurs as phosphate defects in the aragonite structure, but in many samples a significant fraction of the P occurs also in crystalline hydroxylapatite inclusions. Quantification of the amount of hydroxylapatite indicates that its presence is not related simply to external environmental factors and that it can occur at varying abundances in different parts of the same corallite. Since there is currently no model available to describe the relationship between dissolved inorganic phosphate and its incorporation as apatite inclusions into carbonates, careful screening of samples which contain only phosphate in the aragonite structure or selective microsampling could improve proxy development.