Differential damage in the semi-confined Munazio Ireneo cubicle in Cagliari (Sardinia): a correlation between damage and microclimate

The Early Christian Munazio Ireneo cubicle in Cagliari (Sardinia) is carved into the rock and is one of the rare monuments of Sardinia belonging to Early Christian Age. It is 166 cm under the planking level and is a semi-confined chamber in which a gate allows exchange with the outside. In 1888, when it was discovered, it was completely painted, but over the years, it suffered a serious damage and all the paintings are nearly disappeared. Now the site shows a high moisture and a differential damage characterised by delamination, powdering, salt crystallisation and biological colonisation. The research offers a multidisciplinary approach to study the salt crystallisation damage, which is a phenomenon still not completely understood today. Studies and analyses highlight that different kinds of damage can be recognised. The cement mortar and the air pollution cause crystallisation of the sulphates. Constant capillary rising and the presence of water infiltration due to the rains, which travelled into the site from the vault, were detected during qualitative inspection. Although the microclimate did not change much in the site and the humidity was almost constant during the monitoring period, the variations in temperature allowed the phase transitions of sodium sulphate, especially in summer. The greatest damage of the porous stone is associated with the phase transitions and crystallisation inside the stone of sodium sulphate, one of the most harmful salts for porous materials because of its high crystallisation pressure.     

The 18.7 ka phreatomagmatic flank eruption on Etna (Italy): relationship between eruptive activity and sedimentary basement setting

This paper documents a phreatomagmatic flank eruption that occurred 18 700 ± 100 a BP , on the lower north-eastern slope of Etna during the Ellittico volcano activity, which produced fall and surge deposits. This type of eruption is connected to a sedimentary basement ridge at Etna. The interaction between the rising magma and the shallow groundwater hosted in the volcanic pile overlying the impermeable sediments resulted in phreatomagmatic instead of strombolian activity. Three eruptive phases are distinguished based on field and analytical data: (i) an explosive phreatomagmatic opening, (ii) a main phase producing coarse lithic-rich fallout and a strombolian deposit, and (iii) the final pulsating surge-forming phase. The discovery of this phreatomagmatic flank eruption, which occurred at lower altitude, raises important issues for previous hazard assessments at Etna.     

Hazard assessment at volcanic fields: the Campi Flegrei case history

Volcanological analysis of the 10 000 yr –1538 explosive activity at Campi Flegrei shows that the most common explosive eruptions are characterized by the emplacement of flow or surge deposits, originating from the interaction between magma and shallow and/or sea water. The minimum volumes of pyroclastic products range between 0.04 and 0.7 km³; the proximal areas covered by these products range from 3–4 to 40–50 km². The pyroclastic flow and surge deposits occurring inside the caldera have been strongly controlled by pre-existent morphology; because of this, the area of present Napoli city was blanketed by approximately 5 m of pyroclastic deposits, during the last 5000 yr.Previous analysis suggests that the presence of even very low topographic obstacles may influence pyroclastic density current run out such that future eruptive deposits would mainly be confined inside the caldera rim. We suggest that a future eruption at Campi Flegrei would not seriously involve the urbanized area of Napoli city located on the hills. On the contrary, the plains located on the eastern side of the caldera (Fuorigrotta, Bagnoli) would be the most damaged area.     

Relationship between δO values for skeletal apatite from reindeer and foxes and yearly mean δO values of environmental water

The oxygen isotope composition of bone and tooth phosphate of 50 fox specimens and 30 reindeer specimens from various locations with different climatic and environmental conditions was measured. The existing relationship between these values and the mean oxygen isotope composition of local meteoric water has been calculated. In the case of foxes, specimens belonging to two genera (Vulpes and Alopex) and three different species were measured. The samples fit a straight line whose equation can be used for paleoclimatological studies either in Arctic or in temperate regions. For reindeer (Rangifer), a relatively large range of isotopic values was obtained from each location, suggesting imperfect equilibrium conditions with environmental water. The calculated equation can be used for semi-quantitative information on local paleowaters at high latitudes only.     

The large-scale dynamics of grain-size variation in alluvial basins, 1: Theory

We study the interplay of various factors causing vertical grain-size changes in alluvial basins using a simple coupled model for sediment transport and downstream partitioning of grain sizes. The sediment-transport model is based on the linear diffusion equation; by deriving this from first principles we show that the main controls on the diffusivity are water discharge and stream type (braided or single-thread). The grain-size partitioning model is based on the assumption that the deposit is dominated by gravel until all gravel in transport has been exhausted, at which point deposition of the finer fractions begins. We then examine the response of an alluvial basin to sinusoidal variation in each of four basic governing variables: input sediment flux, subsidence rate, supplied gravel fraction, and diffusivity (controlled mainly by water flux). We find that, except in the case of variable gravel fraction, the form of the basin response depends strongly on the time-scale over which the variation occurs. There is a natural time-scale for any basin, which we call the ‘equilibrium time’, defined as the square of basin length divided by the diffusivity. We define ‘slow’ variations in imposed independent variables as those whose period is long compared with the equilibrium time. We find that slow variation in subsidence produces smoothly cyclic gravel-front migration, with progradation during times of low sedimentation rate, while slow variation in sediment flux produces gravel progradation during times of high sedimentation rate. Slow variation in diffusivity produces no effect. Conversely, we define ‘rapid’ variations as those whose period is short compared with the equilibrium time. Our model results suggest that basins respond strongly to rapid variation in either sediment flux or diffusivity; in both cases, deep proximal unconformities are associated with abrupt gravel progradation. This progradation occurs during times of either low sediment flux or high diffusivity. On the other hand, basin response to variation in subsidence rate gradually diminishes as the time scale becomes short relative to the equilibrium time. Each of the four variables we have considered - input sediment flux, subsidence, gravel fraction, and diffusivity - is associated with a characteristic response pattern. In addition, the time scale of imposed variations relative to the equilibrium time acts in its own right as a fundamental control on the form of the basin response.     

Secondary flow in anabranch confluences of a braided,gravel-bed stream

Measurements of the primary and secondary velocity components were máde in two, active, braided river anabranch confluences with a simple Y-shaped plan form, in the gravelly Sunwapta River (D₅₀ of approximately 30 mm). Flow velocity was measured at regularly-spaced intervals using a bidirectional electromagnetic current meter and the measured downstream and cross-stream velocities were converted to primary and secondary velocities to yield the secondary circulation. The primary (downstream) velocity field shows two high velocity streams from the two tributaries which merge (and, in some cases, accelerate) into a single high velocity core over the thalweg. Primary flow velocity declines as the flow expands and diverges at the downstream end of the confluence. The secondary circulation is dominated by two helical cells, back-to-back, plunging over the thalweg and diverging at the bed. This is the first confirmation of this flow structure in confluences, based on field measurements. The strength of the secondary cells declines downstream through each confluence, and laterally away from the thalweg area in cross-section. There is also a tendency for one cell, from the larger of the tributaries, to override the other. The secondary and primary flow structure and strength differs slightly between the two confluences and this is reflected in differences in scour hole form.     

The island of Linosa (Sicily channel)

The volcanology and petrology of Linosa island are described. Linosa and Pantelleria are two quaternary volcanic islands located in the Sicily Channel, a NW-SE elongated continental rift structure of the southern Mediterranean Sea. Several hyaloclastitic rings mark the period of submarine explosive activity which formed Linosa. Lava flows and spatter cones, originated in a later period, prevented the complete destruction of this island by the sea. A typical (undersaturated) alkali basalt fractionation trend has been recognized at Linosa while Pantelleria is characterized by diflerentiation products originated from a mildly alkalic-transitional basaltic magma. These petrogenetic differences between Linosa and Pantelleria have tentatively been related to a different crustal thickness of the islands due to their tectonic location within the Sicily Channel: Linosa on a marginal area, Pantelleria just on the axis of a graben. The genesis and evolution of the Sicily Channel Rift Valley and of the associated basaltic magmatism are probably related to tensional stresses affecting the northwards migrating African plate, just behind its contact zone with the Eurasian plate.     

Oxidative stress in the mussel Mytella guyanensis from polluted mangroves on Santa Catarina Island,Brazil

Digestive glands of the mangrove mussel Mytella guyanensis, collected at one non-polluted site (site 1) and two polluted sites (sites 2 and 3), were analysed for different antioxidant defenses, lipid peroxidation and DNA damage. Thiobarbituric acid-reactive substance (TBARS) and 8-oxo-7,8-dihydro-2'-deoxyguanosine levels were enhanced at the polluted sites. With the exception of superoxide dismutase, the activities of catalase and glutathione peroxidase were also higher at the polluted sites. Greater increases were observed in glutathione reductase, glutathione S-transferase and etoxyresorufine-O-deethylase activities at the polluted sites. Conversely, reduced glutathione content was higher at the control site. Trace metal contents in mussels collected at polluted sites were increased compared to the control site, and there were strong positive correlations between TBARS and Cu and Pb contents. M. guyanensis is routinely exposed to an oxidative stress condition at both polluted sites, and considering xenobiotic bioaccumulation in bivalve molluscs, the mangrove mussel represents an excellent bioindicator for environmental monitoring studies.     

The use of predictive modeling techniques for optimal exploitation of spatial databases: a case study in landslide hazard mapping with expert system-like methods

. A case study is presented in which different probabilistic prediction models (Bayesian probability, fuzzy logic "and", "or", "sum", "product", "gamma" operations, and certainty factors) are used to produce landslide hazard maps for a hilly and mountainous region in the northern Apennines, Italy. Seven data layers are exploited to detect most vulnerable areas: lithology, distance from the geological lineaments, annual rainfall amount, land cover type, topographic slope and aspect, and the distance from hydrographic network segments. The results of the different predictions are compared using the prediction rate index and critically discussed, to evaluate the possibility of using readily available databases for land planning.     

Stochastic seismic analysis of hydrodynamic pressure in dam reservoir systems

Hydrodynamic seismic‐induced pressure requires careful consideration in the aseismic design of dams. Effects induced by earthquake excitation may cause many‐fold increments of hydrostatic pressure. In this study earthquake excitation has been modelled by means of random process theory obtaining the response statistics of a dam‐reservoir dynamical system. The analysis has been conducted assuming a rigid retaining wall of the reservoir and dissipative fluid. Copyright © 2002 John Wiley & Sons, Ltd.