Quantitative models of sedimentary basin filling

Quantitative modelling of the filling of sedimentary basins was begun in earnest in the 1960s. Dozens of themes and variations have been proposed since then, and have yielded an abundance of idealized stratigraphic patterns as functions of both imposed changes and basin properties. Post‐plate‐tectonic modelling began with ‘rigid‐lid' models, which show the stratigraphic signature of subsidence variation. This work introduced the connection between stratigraphy and the rheology of the lithosphere. Rigid‐lid models are the simplest type of geometric model, in which the sediment surface is assigned prescribed geometries, usually corresponding to different depositional environments. These can reproduce many aspects of overall stratal geometry but are formally restricted to relatively long timescales, for which quasi‐steady surface topography can be assumed. So‐called dynamic models attempt to represent the morphodynamics of the sediment surface by abstracting and averaging short‐term transport processes. Most of the dynamic models proposed to date can be seen as special cases of a single general morpho‐dynamic equation. The most important result of the first wave of quantitative basin‐filling models is that even relatively simple models can produce reasonable stratal patterns. We now have a wide array of tools for exploring scenarios, searching for general behaviours and effects, and making initial quantitative predictions. We have also learned that basin response to external forcing as recorded in stratigraphy can be as sensitive to the characteristics of the basin as to the forcing. The main brake on the development of basin modelling is not computing power but lack of methods and data for testing the models we have already developed. Physical experiments, which are only just beginning, are one means of doing this. Experimental stratigraphy is a bridge to quantitative field tests, which will require collaboration among academic researchers from a wide range of areas, and between academia and industry, on projects of greater scale and degree of integration than we have seen so far. The advancement of quantitative sedimentary geology will also require significant changes in the way the subject is taught, at all levels.     

Evidence for onshore deposition of Pleistocene continental shelf clays

Clay balls deposited as a washover fan at Stone Harbor, New Jersey, are probably fragments of a bed of Pleistocene continental shelf clay, based on physical characteristics, clay mineralogy, and radiocarbon ages of 20,135–24,630 yr BP. They may not all originate in the same area and are probably undergoing mixing with modern organic material.     

Structural dynamics of bacterioplankton assemblages in the Lagoon of Venice

In this study we examined the spatial and temporal dynamics of planktonic bacterial assemblages at four different sites in the Lagoon of Venice. Samples were collected in January, April, July and October 2005 and several parameters (temperature, salinity, dissolved oxygen, chlorophyll a, dissolved macronutrients, dissolved and particulate organic carbon, viral and heterotrophic nanoplanktonic abundances) were determined in order to highlight the most important factors which are implied in shaping such assemblages. Furthermore we tested the relationship between similar assemblages and the patterns of activities (prokaryotic carbon production and several hydrolytic activities) that they perform in order to establish if, in this highly variable environment, similar assemblages behave in analogous ways. Results indicate that seasonality act as the main forcing on the communities. Moreover, we found a mismatch between community structure and patterns of activity possibly as a consequence of the heterogeneity of the lagoon which can affect in turn the assemblages' metabolic requirements (and thus their responses).     

Spatial and temporal prokaryotic variability in the northern Adriatic Sea

The prokaryotic community, both in terms of abundance and activity (exoenzymatic hydrolysis of proteins, polysaccharides and phosphorylated molecules and leucine uptake), was investigated seasonally for a 3‐year period (2004–2006) in the Gulf of Venice (northern Adriatic Sea). By focusing on spatial and temporal variability, the prokaryote dynamics showed significant variations on a horizontal and seasonal scale, but no substantial differences were observed among years. The basin‐scale variability was mainly influenced by allochthonous inputs from the Po river and the Venice Lagoon, which were the main source of nutrients, acting as a ‘bottom up’ control on prokaryotes. On a seasonal scale, all the microbial parameters (except the polysaccharide degradation) showed significant variations following the temperature fluctuations. The annual rate of change was very low for all the chemical, physical and biological parameters and only the abundance and phosphatase activity of the prokaryotes differed significantly among years.     

Geological,geochemical and mineralogical features of some bauxite deposits from Nurra (Western Sardinia,Italy): insights on conditions of formation and parental affinity

Bauxite deposits are widespread in NW Sardinia. They formed during the middle Cretaceous, in consequence of a period of emergence of the Mesozoic carbonate shelf. In the Nurra area the geometries derived by the Middle Cretaceous tectonic phases controlled the ore typologies. Two bauxite profiles, laying on different bedrocks, were sampled. The bauxitization proceeded from the surface downward, with the accumulation of Al₂O₃ and residual ‘immobile’ elements (Al, Ti, HFSE), and corresponding mobility and loss of SiO₂ and Fe₂O₃. Epigenetic kaolinite formed close to faults and joints, probably as a result of silicification, introduced by low temperature hydrothermal solutions. Rare earth elements, especially LREE, are concentrated in Fe-rich bauxite horizons, probably due to scavenging by goethite. REE-enrichment is not observed in the boehmite-rich horizons. Very high REE contents are observed in a Fe-depleted horizon due to the occurrence of REE accessory minerals, probably of the bastnäsite group. Conservative indices, including TiO₂/Al₂O₃ and Ti/Cr ratios, and Eu anomalies (Eu/Eu*), suggest that the deposits formed by weathering of sediments derived from mafic rocks of the Hercynian basement. This, in turn, implies that the basement was exposed during middle Cretaceous.     

The forced and free response of the South China Sea to the large-scale monsoon system

Non-tidal sea level anomalies (SLAs) can be produced by many different dynamical phenomena over many time scales, and they can induce serious damages in coastal regions especially during extreme events. In this work, we focus on the SLAs in the South China Sea (SCS) to understand whether and how they can be related to the large-scale, seasonal monsoon system which dominates the SCS circulation and dynamics. We have two major objectives. The first one is to understand whether the NE (winter) and SW (summer) monsoons can be responsible for the persistent SLAs, both positive and negative, observed at the SCS ends along the main monsoon path. The second objective is to understand the SCS response as a free system upon onset/relaxation or sudden changes in the forcing wind. It is well known that sudden changes in the forcing mechanism induce free oscillations, or seiches, in closed, semi-enclosed basins and harbors, and we want to identify the possible seiche modes of the SCS. To our knowledge, these two objectives have not been previously addressed. We address these objectives both through observational analysis and modeling simulations. Multi-year tide-gauge data from stations along the coastal regions of the SCS are analyzed examining their spatial correlations. Strong negative correlations are found between the northeast and southwest stations at the two ends of the SCS under the path of the NE/SW monsoons. They correspond to wind-induced positive/negative sea level set-ups lasting for the entire monsoon season and changing sign from winter to summer. Short periods of negative correlations are also found between the SLAs at eastern and western stations during El Niño years in which the monsoons are weaker and have an enhanced E/W component inducing corresponding sea level set-ups. The tide-gauge station at Tanjong Pagar at the southwest SCS end near Singapore is chosen to study four extreme SLAs events in the observational record during 1999. Modeling simulations are carried out to reproduce them. The observed and modeled extreme SLAs agree quite well, both in the amplitude of the highest peak and in phase. Three main peaks are identified in the observational energy spectrum of the de-tided SLAs at the same station in 1999. Using Merian’s formula to evaluate the periods of seiches in idealized basins Wilson (Adv Hydrosci 8:1–94, 1972) the first two peaks (24.4 h and 11.9 h) are found to correspond to the first two seiche modes in the direction of the main, longer axis of the SCS. The third peak (8.5 h) is found to correspond to the seiche in the transversal, shorter axis. Finally, modeling simulations are carried out by suddenly dropping a circular bump of water in the quiescent basin at different locations to excite the seiches. The periods of the modeled peaks agree quite well with the observational ones, the first two periods being actually identical.     

Our astrochemical heritage

Our Sun and planetary system were born about 4.5 billion years ago. How did this happen, and what is the nature of our heritage from these early times? This review tries to address these questions from an astrochemical point of view. On the one hand, we have some crucial information from meteorites, comets and other small bodies of the Solar System. On the other hand, we have the results of studies on the formation process of Sun-like stars in our Galaxy. These results tell us that Sun-like stars form in dense regions of molecular clouds and that three major steps are involved before the planet-formation period. They are represented by the prestellar core, protostellar envelope and protoplanetary disk phases. Simultaneously with the evolution from one phase to the other, the chemical composition gains increasing complexity. In this review, we first present the information on the chemical composition of meteorites, comets and other small bodies of the Solar System, which is potentially linked to the first phases of the Solar System??s formation. Then we describe the observed chemical composition in the prestellar core, protostellar envelope and protoplanetary-disk phases, including the processes that lead to them. Finally, we draw together pieces from the different objects and phases to understand whether and how much we inherited chemically from the time of the Sun??s birth.     

H<Subscript>2</Subscript>O storage capacity of olivine and low-Ca pyroxene from 10 to 13 GPa: consequences for dehydration melting above the transition zone

The onset of hydrous partial melting in the mantle above the transition zone is dictated by the H₂O storage capacity of peridotite, which is defined as the maximum concentration that the solid assemblage can store at P and T without stabilizing a hydrous fluid or melt. H₂O storage capacities of minerals in simple systems do not adequately constrain the peridotite water storage capacity because simpler systems do not account for enhanced hydrous melt stability and reduced H₂O activity facilitated by the additional components of multiply saturated peridotite. In this study, we determine peridotite-saturated olivine and pyroxene water storage capacities at 10–13 GPa and 1,350–1,450°C by employing layered experiments, in which the bottom ~2/3 of the capsule consists of hydrated KLB-1 oxide analog peridotite and the top ~1/3 of the capsule is a nearly monomineralic layer of hydrated Mg# 89.6 olivine. This method facilitates the growth of ~200-μm olivine crystals, as well as accessory low-Ca pyroxenes up to ~50 μm in diameter. The presence of small amounts of hydrous melt ensures that crystalline phases have maximal H₂O contents possible, while in equilibrium with the full peridotite assemblage (melt + ol + pyx + gt). At 12 GPa, olivine and pyroxene water storage capacities decrease from ~1,000 to 650 ppm, and ~1,400 to 1,100 ppm, respectively, as temperature increases from 1,350 to 1,450°C. Combining our results with those from a companion study at 5–8 GPa (Ardia et al., in prep.) at 1,450°C, the olivine water storage capacity increases linearly with increasing pressure and is defined by the relation C_{\textH2 \textO}^\textolivine ( \textppm ) = 57.6( ±16 ) ×P( \textGPa ) - 169( ±18 ). C_{{{\text{H}}_{2} {\text{O}}}}^{\text{olivine}} \left( {\text{ppm}} \right) = 57.6\left( { \pm 16} \right) \times P\left( {\text{GPa}} \right) - 169\left( { \pm 18} \right). Adjustment of this trend for small increases in temperature along the mantle geotherm, combined with experimental determinations of D_{\textH2 \textO}^{\textpyx/olivine} D_{{{\text{H}}_{2} {\text{O}}}}^{\text{pyx/olivine}} from this study and estimates of D_{\textH2 \textO}^{\textgt/\textolivine} D_{{{\text{H}}_{2} {\text{O}}}}^{{{\text{gt}}/{\text{olivine}}}} , allows for estimation of peridotite H₂O storage capacity, which is 440 ± 200 ppm at 400 km. This suggests that MORB source upper mantle, which contains 50–200 ppm bulk H₂O, is not wet enough to incite a global melt layer above the 410-km discontinuity. However, OIB source mantle and residues of subducted slabs, which contain 300–1,000 ppm bulk H₂O, can exceed the peridotite H₂O storage capacity and incite localized hydrous partial melting in the deep upper mantle. Experimentally determined values of D_{\textH2 \textO}^{\textpyx/\textolivine} D_{{{\text{H}}_{2} {\text{O}}}}^{{{\text{pyx}}/{\text{olivine}}}} at 10–13 GPa have a narrow range of 1.35 ± 0.13, meaning that olivine is probably the most important host of H₂O in the deep upper mantle. The increase in hydration of olivine with depth in the upper mantle may have significant influence on viscosity and other transport properties.