Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.     

Intrinsic sample methods for mineral exploration and resource assessment

We report on an objective methodology, referred to as intrinsic sample methodology, for the delineation of exploration target areas or resource areas for assessment. Important features of the methodology include (1) identification of recognition criteria for critical genetic factors, (2) synthesis of new variables from enhanced geodata, (3) estimation of logit probability models, and (4) cutting of estimated logit probabilities to delineate exploration targets or resource areas. The methodology is demonstrated on the Walker Lake quadrangle of Nevada and California.     

山东省日照市蓝色经济区工程建设适宜性评价

本文以山东省日照市蓝色经济区为研究区, 通过野外地质调查和室内综合分析, 选取场地稳定性、工程地质条件、地下水条件, 地形排水条件、地质灾害及其他因素6个一级评价因子, 构造活动、场地土类型、建筑场地类别等13个二级评价因子, 利用专家-层次分析定权法进行区内工程建设适宜性评价, 得到了相应工程建设评价分区图。评价结果表明, 日照市场地工程建设适宜性总体较好, 大部分地区适宜进行高层建筑工程建设, 占84.50%; 地下空间开发利用条件优越, 全区多数地区属于城市地下空间建设适宜区, 适宜性差及不适宜区主要分布在付疃河两岸附近和海岸附近、大型高速公路和铁路沿线一带区域及城区; 轨道交通建设适宜性良好, 小部分不适宜区主要集中在付疃河下游夹仓和小古镇一带及其沿海地区。评价结果可有效地服务于该地区规划布局、建设发展和工程选址, 具有重要的理论和实践指导意义。     

流体在岩浆型铬铁矿和铂族元素成矿过程中的作用及意义

镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口，也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同：蛇绿岩以产出铬铁矿床为特征，阿拉斯加型岩体主要赋含铂族元素(PGE)矿床，大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关，但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程，而极少关注流体作用。近年来，实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用，同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为，刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素，已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题，总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录，提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用，强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。     

五大连池火山群新期火山渣丘成因的探讨

火山渣丘,是火山区内的一种特殊的地质现象,以前地其成因国内外尚无详细探讨和描述,有的学者曾经统称为副火山。笔者通过实地调查,对这一结论提出新的见解,认为火山渣丘的形成是一复杂的地质现象,其成因具有多元性。这对探讨火山喷发规律,对火山地质地貌的准确描述与具有积极作用。     

含煤层地质环境下地震波场的数值模拟

本文对含低速煤层地质环境下弹性波场多波多分量地震资料进行了二维数值模拟研究,对人工边界反射进行了有效处理,频散效应得到了有效的压制,对几种不同激发与观测排列方式下的弹性波资料进行了模型计算与分析。     

湘中“桃江式”锰矿含锰岩系的定量研究及其找矿意义

本文从分析地质体数学特征的思想出发,来研究“桃江式”锰矿的含矿母岩－“含锰岩系”的数学特征。含锰岩系主要由五种岩石组成：粘土岩、黑色页岩、条带状页岩、含锰灰岩和碳酸锰矿层,其数学特征研究包括其统计特征分析、结构特征分析和空间特征分析。文最后讨论了这些数学特征在寻找同类锰矿中的意义。     

多普勒声雷达对化音地区风场结构探测的初步分析

本文利用1990年8月多普勒声雷达在“HEIFE”区化音站探测的资料,对该地区的PBL结构进行了初步分析。结果表明,用声雷达回波强度的双对数廓线确定大气边界层高度仍不失为一有效的方法。大气边界层高度演变过程的特点是:白天对流层边界发展较快,但维持时间较短;而夜间稳定边界层维持时间较长,且在其发展较高时,在近地层又发展出一个新的稳定层结,呈现多层次的SBL结构。ML内垂直风速方差的归一化结果与Lenschow大致相同。另外,在一次冷锋过境天气背景下风场出现低空急流结构。     

Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China

Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (C_org), extractable extracellular carbon (C_ext), total soil nitrogen (N_t), alkali-hydrolyzable nitrogen (N_ah), total phosphorus (P_t), available phosphorus (P_a) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation–extraction, FE-C_mic, and by calculation from substrate-incubation respiration, SIR-C_mic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of C_mic/C_org and BR/C_mic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as C_org and C_ext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-C_mic, SIR, and SIR-C_mic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with the land degradation.