Geochronology of anthropogenic pollutants in riparian wetland sediments of the Lippe River (Germany)

Anthropogenic pollutants were determined in a dated sediment core, collected from a riparian wetland of the Lippe River (Ruhr district, Germany). The historical trend in heavy metals, polycyclic aromatic hydrocarbons, organochlorines, polychlorinated biphenyls and linear alkylbenzenes as well as more recent contaminants such as industrial additives, organotins, synthetic musks, methyltriclosan and some other compounds were determined for the time period between 1930 and 1986. Emission sources, information on technical production and usage, as well as on the individual pollution pathways, with appropriate environmental stability, were considered in the interpretation of the sediment contamination over the past 50 years.Contaminants were analysed and interpreted according to two different criteria: (a) the origin of the main contaminants as related to mining and industrial activities as well as municipal sewage and agricultural effluents and (b) the pollution history. Due to a significant appearance of formerly missing contaminants in sediments deposited since 1970, we suggest classifying contaminants as either common (predating 1970) or modern (postdating 1970).In summary, the study provided a comprehensive reconstruction of the pollution history of the Lippe River system.     

Spatial and temporal patterns of dry spell lengths in the Iberian Peninsula for the second half of the twentieth century

Summary Daily pluviometric records of 43 meteorological stations across the Iberian Peninsula have permitted a detailed analysis of dry spell patterns for the period 1951–2000 by distinguishing daily amount thresholds of 0.1, 1.0, 5.0 and 10.0 mm/day. The analyses are based on three annual series, namely the number of dry spells, N, the average dry spell length, L, and the extreme dry spell length, L _max. First, the statistical significance of local trends for the annual series of N, L and L _max has been investigated by means of the Mann-Kendall test and significant field trends have been established by means of Monte Carlo simulations. Clear signs of negative field trends are detected for N (1.0 and 10.0 mm/day) and L (0.1 mm/day). Second, the Weibull model fits well the empirical distributions of dry spell lengths for all the rain gauges, whatever the daily amount threshold, with a well ranged spatial distribution of their parameters u and k. On the basis of the Weibull distribution, return period maps for 2, 5, 10, 25 and 50 years have been obtained for dry spell lengths with respect to the four daily threshold levels. While for 0.1 and 1.0 mm/day the longest dry spells are expected at the south of the Iberian Peninsula, for 5.0 and 10.0 mm/day they are mostly detected at the southeast. Finally, the elapsed time between consecutive dry spells has been analysed by considering the same rain amount thresholds and different dry spell lengths at increasing intervals of 10 days. This analysis makes evident a significant negative field trend of the elapsed time between consecutive dry spells of lengths ranging from 10 to 20 days for daily amount thresholds of 1.0, 5.0 and 10.0 mm/day. Authors’ addresses: X. Lana, C. Serra, Departament de Física i Enginyeria Nuclear, ETSEIB, Universitat Politècnica de Catalunya, Av. Diagonal 647 planta 11, 08028 Barcelona, Spain; M. D. Marínez, Departament de Física Aplicada, Universitat Politècnica de Catalunya, 08028 Barcelona, Spain; A. Burgue?o, Departament de Meteorologia i Astronomia, Universitat de Barcelona, 08028 Barcelona, Spain; J. Martín-Vide, L. Gómez, Grup de Climatologia, Universitat de Barcelona, 08028 Barcelona, Spain.     

Comparison of Vegetation Indices from Two Ground Based Sensors

The best and commonly used ground-based sensor to monitor crop growth, ASD FieldSpecPro Spectroradiometer (Analytical Spectral Devices, Boulder, CO, USA) is a passive sensor, which can be used under adequate light condition. However, now-a-days active sensors such as GreenSeeker? (GS) handheld crop response (Trimble Agriculture division, USA) are used for monitoring crop growth and are flexible in terms of timeliness and illumination conditions besides being cheaper than the ASD. Before its wide use, the suitability and accuracy of GS should be assessed by comparing the NDVI measured by this instrument with that by ASD, under diverse wheat growing conditions of India. Keeping this in view, the present experiment was undertaken with the following objectives: (1) to find out the temporal variation of NDVI measured both by ASD and GS treatments, (2) to find out relationship between the NDVI measured through ASD and GS and, (3) to evaluate the suitability of GS for NDVI measurements. It was observed that the numerical value of NDVI as measured by GS was always significantly (P < 0.05) lower than that measured by ASD for all the experiments under study. The NDVI-ASD and NDVI-GS were significantly positively correlated (P < 0.01) with the correlation coefficients being +0.94, +0.88 and +0.87 for irrigation and nitrogen experiment, irrigation and cultivars experiment, and tillage, residue and nitrogen experiments, respectively. Further, the regression equation developed between the NDVI-ASD and NDVI-GS: [NDVI-GS = 1.070 × (NDVI-ASD ? 0.292] can be successfully used to compute the NDVI of ASD from that computed by GS.     

Estimation of Partial Pressure of Carbon Dioxide and Air-Sea Fluxes in Hooghly Estuary Based on In Situ and Satellite Observations

An empirical model is developed and used with remotely sensed predictors: sea surface temperature (SST) and chlorophyll-a concentration (Chl-a), to compute surface water partial pressure of carbon dioxide (pCO_2w) and air-sea fluxes of CO₂ in the Hooghly estuary and its adjacent coastal oceans. In situ observations used here were based on measurements carried out in this region during winter and summer periods in 2008. The estimated pCO_2w compares well with the in situ observations at root mean square error ±18 μatm. In winter, estimated pCO_2w ranges between 320 and 500 μatm with large values (>400 μatm) on the south-western and south-eastern flanks of the coastal domain and lower values (340–375 μatm) on the main-channel. In summer, it remained spatially uniform at 450 μatm. Extrapolation of the results over the study region based on the Moderate Imaging Specroradiometer (MODIS) measured SST and Chl-a suggests that the region is a strong source of atmospheric CO₂ during the summer with net release of 0.095 Tg C year^?1 (equivalent to mean flux of 90 molC m^?2 year^?1) and is a weak source during the winter with net release of 0.006 Tg C yr^?1 (0.5 molC m^?2 year^?1) from the geographical extent of 6000 Km² area.     

Use of cartographic images by expert and novice field geologists in planning fieldwork routes

Topographic maps and aerial photographs are particularly useful when geoscientists are faced with fieldwork tasks such as selecting paths for observation, establishing sampling schemes, or defining field regions. These types of images are crucial in bedrock geologic mapping, a cognitively complex field-based problem-solving task. Geologic mapping requires the geologist to correctly identify rock types and three-dimensional bedrock structures from often partial or poor-quality outcrop data while navigating through unfamiliar terrain. This paper compares the walked routes of novice to expert geologists working in the field (n = 66) with the results of a route planning and navigation survey of a similar population of geologists (n = 77). Results show clearly that those geologists with previous mapping experience make quick and decisive determinations about field areas from available imagery and maps, regardless of whether they are or not physically present in the field area. Recognition of geologic features enabled experts to form and verbalize a specific plan for travel through a landscape based on those features. Novices were less likely to develop specific travel route plans and were less likely to identify critical landscape cues from aerial photographs.     

Nonlinear least-squares method via an isomorphic geometrical setup

The resolution of a nonlinear parametric adjustment model is addressed through an isomorphic geometrical setup with tensor structure and notation, represented by a u-dimensional “model surface” embedded in a flat n-dimensional “observational space”. Then observations correspond to the observational-space coordinates of the pointQ, theu initial parameters correspond to the model-surface coordinates of the “initial” pointP, and theu adjusted parameters correspond to the model-surface coordinates of the “least-squares” point . The least-squares criterion results in a minimum-distance property implying that the vector Q must be orthogonal to the model surface. The geometrical setup leads to the solution of modified normal equations, characterized by a positive-definite matrix. The latter contains second-order and, optionally, thirdorder partial derivatives of the observables with respect to the parameters. This approach significantly shortens the convergence process as compared to the standard (linearized) method.     

Seismic hazard monitoring in Kamchatka and its applications to the M = 6.6 earthquake of 6 October 1987

The earthquake of 6 October 1987 (M = 6.6), which occurred near the Shipunsky Cape, Kamchatka, was the largest crustal event in the vicinity of the main city of Kamchatka — Petropavlovsk-Kamchatsky — during the last three decades. It was followed by numerous aftershocks. This earthquake allowed us to test the effectiveness of the seismic hazard monitoring in Kamchatka, including the seismological, geodetic and hydrogeochemical surveys. The seismic survey provided the location and source nature of the main shock and aftershocks and the seismic environment of the main shock. The geodetic and hydrogeochemical surveys have yielded data on the response to earthquakes of the Earth's surface deformations, water level, and chemical elements concentration in the underground water. As a result, the following data were obtained:

u

The earthquake of 6 October had a seismic moment 4–10 E18 Nm, thrust type of faulting and the source volume of 20 × 20 × 10 km³. The maximum intensity was VI–VII (MSK-64 scale) and maximum acceleration 88 cm/s².

Before this event, a relative increase in the number of the upper mantle (depth more than 100 km) moderate magnitude earthquakes during 5 years and a one-year period of seismic quiescence for small shallow earthquakes, were recognized. Significant anomalies in HCO₃ and H₃BO₃ concentrations in the underground waters were observed in the wells a week before the main shock.