Nanoparticles in natural systems II: The natural oxide fraction at interaction with natural organic matter and phosphate

Information on the particle size and reactive surface area of natural samples and its interaction with natural organic matter (NOM) is essential for the understanding bioavailability, toxicity, and transport of elements in the natural environment. In part I of this series (Hiemstra et al., 2010), a method is presented that allows the determination of the effective reactive surface area (A, m²/g soil) of the oxide particles of natural samples which uses a native probe ion (phosphate) and a model oxide (goethite) as proxy. In soils, the natural oxide particles are generally embedded in a matrix of natural organic matter (NOM) and this will affect the ion binding properties of the oxide fraction. A remarkably high variation in the natural phosphate loading of the oxide surfaces (Γ, μmol/m²) is observed in our soils and the present paper shows that it is due to surface complexation of NOM, acting as a competitor via site competition and electrostatic interaction. The competitive interaction of NOM can be described with the charge distribution (CD) model by defining a ≡NOM surface species. The interfacial charge distribution of this ≡NOM surface species can be rationalized based on calculations done with an evolved surface complexation model, known as the ligand and charge distribution (LCD) model. An adequate choice is the presence of a charge of −1 v.u. at the 1-plane and −0.5 v.u. at the 2-plane of the electrical double layer used (Extended Stern layer model).The effective interfacial NOM adsorption can be quantified by comparing the experimental phosphate concentration, measured under standardized field conditions (e.g. 0.01 M CaCl₂), with a prediction that uses the experimentally derived surface area (A) and the reversibly bound phosphate loading (Γ, μmol/m²) of the sample (part I) as input in the CD model. Ignoring the competitive action of adsorbed NOM leads to a severe under-prediction of the phosphate concentration by a factor ∼10 to 1000. The calculated effective loading of NOM is low at a high phosphate loading (Γ) and vice versa, showing the mutual competition of both constituents. Both constituents in combination usually dominate the surface loading of natural oxide fraction of samples and form the backbone in modeling the fate of other (minor) ions in the natural environment.Empirically, the effective NOM adsorption is found to correlate well to the organic carbon content (OC) of the samples. The effective NOM adsorption can also be linked to DOC. For this, a Non-Ideal Competitive adsorption (NICA) model is used. DOC is found to be a major explaining factor for the interfacial loading of NOM as well as phosphate. The empirical NOM-OC relation or the parameterized NICA model can be used as an alternative for estimating the effective NOM adsorption to be implemented in the CD model for calculation of the surface complexation of field samples. The biogeochemical impact of the NOM-PO₄ interaction is discussed.     

Oxygen Regime of the Channel Flow in the Small Maima River,Upper Ob Basin

Water Resources - The oxygen regime of the channel flow of the small Maima River (Upper Ob basin) has been considered. A study of the spatial and seasonal variations of oxygen regime...     

Diagenetic development of unstable and stable magnetization in the St. Bees Sandstone (Triassic) of northern England

Thermal demagnetization of red and drab sandstones from the St. Bees Sandstone shows a wide range of directional stability. After the removal of a metastable secondary magnetization at temperatures up to 300°C red sandstones may show stable or unstable magnetization. Experiments indicate that both the stable and unstable magnetization is carried by coarse haematite particles (specularite).Drab sandstones, which have been subject to reduction and dissolution of haematite are generally unstable but specimens with a stable NRM occur and this must be carried by specularite because the pigment has been removed from these specimens.The stable magnetization is believed to have developed during deposition and early diagenesis by the oxidation of detrital iron oxides. Pole positions correspond to known Triassic poles and there are abundant normal and reversed zones typical of the Lower Triassic.The unstable magnetization of the red sandstones is apparently due to the development of authigenic overgrowths of haematite on the detrital specularites. This phase of authigenesis may have taken place over a long time, and after significant changes in the ambient geomagnetic field resulting in complex magnetizations in individual grains and hence whole rocks.     

Compressive and Rarefactive Dust-acoustic Solitary Structures in a Magnetized Two-ion-temperature Dusty Plasma

A rigorous theoretical investigation has been made of obliquely propagating dust-acoustic solitary structures in a cold magnetized two-ion-temperature dusty plasma consisting of a negatively charged, extremely massive, cold dust fluid and ions of two different temperatures. The reductive perturbation method has been employed to derive the Korteweg-de Vries (K-dV) equation which admits a solitary wave solution for small but finite amplitude limit. It has been shown that the presence of second component of ions modifies the nature of dust-acoustic solitary structures and may allow rarefactive dust-acoustic solitary waves (solitary waves with density dip) to exist in such a dusty plasma system. The effects of obliqueness and external magnetic field on the properties of these dust-acoustic solitary structures are also briefly discussed.     

Comparison of the orientation of small-scale electron density irregularities and F region plasma flow direction

Results are shown from an experimental campaign where satellite scintillation was observed at three sites at high latitudes and, simultaneously, the F region plasma flow was measured by the nearby EISCAT incoherent scatter radar. The anisotropy parameters of field-aligned irregularities are determined from amplitude scintillation using a method based on the variance of the relative logarithmic amplitude. The orientation of the anisotropy in a plane perpendicular to the geomagnetic field is compared with the direction of F region plasma flow. The results indicate that in most cases a good agreement between the two directions is obtained.     

Quaternary sea level fluctuations on a tectonic coast: New 230Th234U dates from the Huon Peninsula,New Guinea

Emerged coral reef terraces on the Huon Peninsula in New Guinea were reported in a reconnaissance dating study by Veeh and Chappell 1970. Age definition achieved was not good for several important terraces, and we report here a series of new ${}^{230}\text{Th}{}^{234}\text{U}$ dates, which further clarify the history of late Quaternary eustatic sea level fluctuations. More than 20 reef complexes are present, ranging well beyond 250,000 yr old: we are concerned with the seven lowest complexes. Major reef-building episodes dated by ${}^{30}\text{Th}{}^{234}\text{U}$ are reef complex I at 5–9 ka (kilo anno = 1000 yr), r.c. IIIb at 41 ka (four dates), r.c. IV at 61 ka (four dates), r.c. V at 85 ka (two dates), r.c. VI at 107 ka (two dates), and r.c. VII at 118–142 ka. Complex II was previously dated by ¹⁴C at 29 ka: this age has not yet been confirmed, and may be only a lower limit. The reef crests were built during or immediately before intervals of sea level maxima, when rates of rising sea level and tectonic uplift briefly coincided. The culmination of each reef-building episode was only a few thousand years in duration, and multiple dates from the same reef complex generally group within the statistical errors of the individual dates.Several methods can be used to estimate the altitude of each sea level maximum relative to present sea level. The least complicated is to calculate mean tectonic uplift rate for each profile of the terraces, and use the mean rate to calculate the tectonic displacement of each dated reef complex on that profile. The difference between the present altitude of a reef complex and its calculated tectonic uplift gives the paleosea level at the time the reef grew. We estimate uplift rates for six surveyed sections by calibrating against published paleosea level estimates from Barbados and elsewhere, viz 125 ka, paleosea at +6 m; 103 ka, ?15 m; 82 ka, ?13 m. For each section the individual uplift rates for reefs V, VI, and VIIb are within 5% of their section means. Using the mean rates. paleosea level estimates for reef crests II, IIIB, and IV are made for each section. Consistency of estimates between sections is good, giving ?28 m for the 60 ka paleosea level, around ?38 m for the 42 ka level and ?41 m for the 28 ka level (if the age is older the paleosea level would be lower. Using the mean uplift rates, the 82 ka and 103 ka paleosea levels are also estimated for each section: all individual estimates are plotted graphically, and a sea level curve drawn. The reef stratigraphy indicates sea level lowerings between each dated reef crest: the crests probably represent the interstadials of the Wisconsin (Würm, Weichsel) Glaciation, and intervening lower levels correspond to stadials. Since the last time of eustatic sea level higher than the present (about 125 ka), five sea level maxima occurred at roughly 20-ka intervals, none being as high as the present.     

A fuzzy dynamic flood routing model for natural channels

A fuzzy dynamic flood routing model (FDFRM) for natural channels is presented, wherein the flood wave can be approximated to a monoclinal wave. This study is based on modification of an earlier published work by the same authors, where the nature of the wave was of gravity type. Momentum equation of the dynamic wave model is replaced by a fuzzy rule based model, while retaining the continuity equation in its complete form. Hence, the FDFRM gets rid of the assumptions associated with the momentum equation. Also, it overcomes the necessity of calculating friction slope (S_f) in flood routing and hence the associated uncertainties are eliminated. The fuzzy rule based model is developed on an equation for wave velocity, which is obtained in terms of discontinuities in the gradient of flow parameters. The channel reach is divided into a number of approximately uniform sub‐reaches. Training set required for development of the fuzzy rule based model for each sub‐reach is obtained from discharge‐area relationship at its mean section. For highly heterogeneous sub‐reaches, optimized fuzzy rule based models are obtained by means of a neuro‐fuzzy algorithm. For demonstration, the FDFRM is applied to flood routing problems in a fictitious channel with single uniform reach, in a fictitious channel with two uniform sub‐reaches and also in a natural channel with a number of approximately uniform sub‐reaches. It is observed that in cases of the fictitious channels, the FDFRM outputs match well with those of an implicit numerical model (INM), which solves the dynamic wave equations using an implicit numerical scheme. For the natural channel, the FDFRM outputs are comparable to those of the HEC‐RAS model. Copyright © 2009 John Wiley & Sons, Ltd.     

地面对晴空大气热辐射结构的影响

本文利用1987年美国FIFE资料及1986年6月TIPMEX资料,并利用大气长、短波一维辐射传输数值模式,计算了晴空大气状态下地面辐射参数(地面热辐射温度、地表反照率等)对大气长波冷却率、短波加热率廓线的影响。结果表明,地球表面对大气边界层内的热辐射结构影响很大,特别是在高原地区这种影响尤其显著。     

Linking gold mineralization to regional-scale drivers of mineral systems using in situ U–Pb geochronology and pyrite LA-ICP-MS element mapping

Proterozoic orogens commonly host a range of hydrothermal ores that form in diverse tectonic settings at different times. However, the link between mineralization and the regional-scale tectonothermal evolution of orogens is usually not well understood, especially in areas subject to multiple hydrothermal events.Regional-scale drivers for mineral systems vary between the different classes of hydrothermal ore, but all involve an energy source and a fluid pathway to focus mineralizing fluids into the upper crust. The Mount Olympus gold deposit in the Proterozoic Capricorn Orogen of Western Australia, was regarded as an orogenic gold deposit that formed at ca. 1738 Ma during the assembly of Proterozoic Australia. However,the trace element chemistry of the pyrite crystals closely resembles those of the Carlin deposits of Nevada,with rims that display solid solution gold accompanied by elevated As, Cu, Sb, Hg, and Tl, surrounding gold-poor cores. New SHRIMP UeP b dating of xenotime intergrown with auriferous pyrite and ore-stage alteration minerals provided a weighted mean~(207) Pb*/~(206) Pb* date of 1769 ± 5 Ma, interpreted as the age of gold mineralization. This was followed by two discrete episodes of hydrothermal alteration at 1727 ± 7 Ma and 1673 ± 8 Ma. The three ages are linked to multiple reactivation of the crustal-scale Nanjilgardy Fault during repeated episodes of intracratonic reworking. The regional-scale drivers for Carlin-like gold mineralization at Mount Olympus are related to a change in tectonic regime during the final stages of the intracratonic 1820 -1770 Ma Capricorn Orogeny. Our results suggest that substantial sized Carlin-like gold deposits can form in an intracratonic setting during regional-scale crustal reworking.