Studies on the determination of inorganic iodine in seawater

Existing methods for the determination of the various forms of iodine present in seawater are laborious or unwieldy in use. This paper describes modified forms of the iodate and total iodine methods described by Barkley and Thompson (1960), a spectrophotometric procedure for iodate determination derived from Johannesson's (1958) work, and an automatic method for total iodine determination. Procedures for iodate and total-iodine determination which are suitable for use aboard ship, are recommended. Both procedures for iodate determination returned a standard deviation close to 0.5 μg/l when several replicate samples of a seawater containing approximately 30 μg/l of iodate-iodine were analysed. The automatic method for total iodine determination yielded a standard deviation of 0.8 μg/l by the repeated analysis of a seawater containing a total of approximately 50 μg/l of iodine. Suitable methods for the filtration and storage of seawater are also described.     

Kirsch problem and the lower natural frequencies of a clamped square-plate

A clamped square-plate is subjected to a uniform state of stress in the x-direction. The present study deals with the basic question of determining the variation of the lower natural frequencies of transverse vibration of a plate as a small diameter, central hole is made in it, introducing a stress concentration field.     

Transverse vibrations of a rectangular cantilever plate with thickness varying in a discontinuous fashion

A numerical solution is obtained for the title problem by means of the popular finite element method. An experimental investigation of the problem is also presented for plates of square planform. The agreement between theoretical and experimental values is very good in the case of the fundamental frequency, and reasonably good when the second and third normal modes of transverse vibration are considered. It is concluded that beneficial effects are obtained in the sense that one generates a lighter structural element with higher fundamental frequency of transverse vibration. Hence, dynamic stiffening is achieved.     

Experimental investigation of the combustive sound source

In this paper, we describe a unique low frequency underwater sound source called the combustive sound source (CSS). In this device, a combustible gas mixture is captured in a combustion chamber and ignited with a spark. The ensuing combustion produces expanding gases which in turn produce high intensity, low frequency acoustic pulses. With high-speed motion pictures of the CSS event, we relate the motion of the bubble to the acoustic waveform. We also compare the measured first bubble period in the CSS pressure signature with the predictions of the Rayleigh-Willis equation, including the dependence of the radiated acoustic waveform on the volume and depth of the bubble. Measurements of the first bubble period agree with Rayleigh-Willis theory in trend, but not in absolute value. In addition, we discuss the variation of the acoustic output with the fuel/oxygen mixture. Finally, several other factors that affect the acoustic output of CSS are discussed. These include the shape of the CSS combustion chamber, the type of oxidizer and fuel, and the ignition source     

Condition of coastal mesoplankton communities in the northeastern area of the Black Sea in 2005

The structure and distribution of mesoplankton in the northeastern part of the Black Sea along 6-mile and 100-mile sections in the area off Golubaya Bay (near the city of Gelendzhik) were analyzed. The studies were performed from R/V Akvanavt and the boat Ashamba. The observations were carried out during the vegetation season from the beginning of June to the first half of October 2005. Samples of mesoplankton were collected with use of a BSD net with an opening of 0.1 m² and a mesh size of 180 μm. Both the total (over the entire water column) and layer-by-layer (separately for the upper quasi-homogeneous layer, the seasonal thermocline, and the subthermocline layer) hauls were performed down to the bottom (at sea depths of less than 200 m) or down to the upper boundary of the hydrogen sulfide waters. The particular hydrophysical conditions that were observed in 2005 resulted in an approximately one-month advance of the phenological condition of the planktonic community as compared to the usual pattern. Beroe ovata appeared in the plankton at the end of July, the mass development of Mnemiopsis leidyi was suppressed, and the duration of its influence on edible zooplankton was essentially reduced. As a result, the total mesoplankton biomass in August–October 2005 was 1.5–2 times as great as that in 2004. The abundance of Acartia clausi increased approximately 4–5 times and the quantity of Sagitta setosa also considerably increased. At selected stations, Mnemiopsis leidyias, the main predator in the community, was replaced by Sagitta setosa.     

Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Simulation of Hydrophysical Processes in Coastal Regions of the Sea

In the present work, we generalize the results of our investigations in the field of simulation of hydrophysical and ecological processes in coastal regions of various seas and some closed basins. The developed and applied mathematical models and the results of numerical experiments are briefly analyzed.     

Imposex still evident in eastern Australia 10 years after tributyltin restrictions

A survey of imposex in Thais orbita (Neogastropoda) along the New South Wales (NSW) coast, Australia, found imposex was still widespread 10 years after a partial ban on tributyltin (TBT) based antifouling paints. Transplant experiments also revealed that imposex was induced in T. orbita over a period of 9 weeks in Sydney Harbour, NSW. A comparison of the imposex data with that collected shortly after the introduction of restrictions on TBT revealed a general decline in imposex frequency occurring at open coast sites, an exception being the site at South West Rocks. Sites located within harbour/bay areas did not display a decline in imposex frequency but a decline in the severity of imposex was apparent. The observed decrease in imposex values in T. orbita may reflect a general decrease of butyltin contamination within the coastal environment. However, the persistence of contamination "hotspots" within harbours and bays remains a concern.