Physical and anthropogenic effects on observed long-term nutrient changes in the Irish Sea

The trend in Irish Sea nutrient concentrations over the last four decades has been considered to reflect changes in anthropogenic loading. Comparison of a long-term database for the Menai Strait, North Wales, with an established historic data set for the Cypris station, Isle of Man, indicates that climate also has a significant influence on observations of nutrient concentrations. Data are presented detailing long-term shifts in nitrate, phosphate and silicate measurements since the 1960s at these two fixed sampling sites in the Irish Sea. Broad systematic changes observed in all three nutrients over the decades show a rise from the 1960s through to the 1980s, followed generally by an overall decline in the 1990s. Decadal-scale salinity changes occur in the opposite sense to nutrient changes. Anthropogenic inputs from freshwater cannot fully account for observed nutrient trends, neither is there evidence for shifts in nutrient concentrations in oceanic waters over the past four decades. Climatically forced movement in the geographical position of the freshwater/seawater mixing zone over a decadal time scale could, however, give rise to the observed shifts in nutrient concentration and salinity. This cannot alter nutrient concentration and salinity per se, but causes the measurements taken at fixed sampling sites to fluctuate inversely over this time scale. It is concluded that there is complex interplay between anthropogenic loading and climate affecting the distribution of nutrients in the Irish Sea.     

Imbalance in the carbonate budget of surficial sediments in the North Atlantic Ocean: variations over the last millenium?

Fluxes contributing to the particulate carbonate system in deep-sea sediments were investigated at the BENGAL site in the Porcupine Abyssal Plain (Northeast Atlantic). Deposition fluxes were estimated using sediment traps at a nominal depth of 3000 m and amounted to 0.37±0.1 mmol C m⁻² d⁻¹. Dissolution of carbonate was determined using flux of total alkalinity from in situ benthic chambers, is 0.4±0.1 mmol C m⁻² d⁻¹. Burial of carbonate was calculated from data on the carbonate content of the sediment and sedimentation rates from a model age based on ¹⁴C dating on foraminifera (0.66±0.1 mmol C m⁻² d⁻¹). Burial plus dissolution was three times larger than particle deposition flux which indicates that steady-state is not achieved in these sediments. Mass balances for other components (BSi, ²¹⁰Pb), and calculations of the focusing factor using ²³⁰Th, show that lateral inputs play only a minor role in this imbalance. Decadal variations of annual particle fluxes are also within the uncertainty of our average. Long-term change in dissolution may contribute to the imbalance, but can not be the main reason because burial alone is greater than the input flux. The observed imbalance is thus the consequence of a large change of carbonate input flux which has occured in the recent past. A box model is used to check the response time of the solid carbonate system in these sediments and the time to reach a new steady-state is in the order of 3 kyr. Thus it is likely that the system has been perturbed recently and that large dissolution and burial rates reflect the previously larger particulate carbonate deposition rates. We estimate that particulate carbonate fluxes have certainly decreased by a factor of at least 3 and that this change has occurred during the last few centuries.     

Volcanogenic complexes of the Sea of Okhotsk and the Sea of Japan (Comparative analysis)

Several coeval volcanogenic complexes indicating synchronous volcanic events in the Sea of Japan and the Sea of Okhotsk are defined. Volcanics from different-age complexes of the Sea of Okhotsk show many features in common and are attributed to the Pacific type of calc-alkaline series. They were formed in geodynamic settings of the active continental margin and point to its origination on the continental crust of the fragmented Asian continent margin. The volcanic rocks developed in the Sea of Japan reflect different rifting stages. The initial stage was marked by an eruption of calc-alkaline lavas (Paleocene-Eocene complex). At the stage of the marginal-sea spreading, erupted volcanics of the middle Miocene-Pliocene complex were melted from the depleted mantle and magmatism terminated by an eruption of postspreading Pliocene-Holocene volcanics melted from the enriched mantle EM I. Along with the differences, the magmatism in the Sea of Japan and Sea of Okhotsk has some features in common. In both cases, the sialic component of the lithosphere substantially influenced the magma generation.     

Distribution of the Neogene Utsira Sand and the succeeding deposits in the Viking Graben area, North Sea

The sandy quartzose parts of the Utsira Formation, the Middle Miocene to mid Pliocene Utsira Sand, extends north–south along the Viking Graben near the UK/Norwegian median line for more than 450 km and 75–130 km east–west. The Utsira Sand is located in basin-restricted seismic depocentres, east of and below prograding sandy units from the Shetland Platform area with Hutton Sands. The Utsira Sand reaches thicknesses up to ca. 300 m in the southern depocentre and 200 m in the two northern depocentres with sedimentation rates up to 2–4 cm/ka. Succeeding Plio–Pleistocene is divided into seismic units, including Base Upper Pliocene, Shale Drape, Prograding Complex and Pleistocene. The units mainly consist of clay, but locally minor sands occur, especially at toes of prograding clinoforms (bottom-set sands) and in the Pleistocene parts, and the total thickness covering the Utsira Sand is in most places more than 800 m, but thins towards the margins.