Anthropogenic platinum,palladium and rhodium concentrations in road dusts from Hyderabad city,India

This paper presents the first study of accessing the Pt, Pd and Rh levels in road dusts collected from Hyderabad city, India, as these metals, emitted from automobile catalytic converters, are accumulating in the environment causing concern about human health and ecological risks. Samples were analyzed by ICP-MS following preconcentration by NiS-fire assay and Te coprecipitation. Pt (1.5–43 ng/g), Pd (1.2–58 ng/g) and Rh (0.2–14.2 ng/g) concentrations obtained were above upper crust values, but were lower when compared with several other cities around the world. Dust samples from road junctions and traffic signals with heavy and erratic traffic flow showed higher PGE levels than those from roads with low and free flow traffic suggesting that traffic flow conditions greatly influenced emission of PGE from the catalyst. Significant correlation of Pt, Pd and Rh indicate a common source for these metals. PGE were also positively correlated with Ce, Zr, Hf and Y. These positive inter-element correlations identified traffic as the main source of PGE emission to the roadway environment. The results obtained indicate to an appreciable increase in auto catalyst-derived PGE. In consideration of the adverse effects of PGE, monitoring their level and transformation paths is of prime importance.     

花岗岩张拉和压剪裂隙渗透率演化研究

地下工程开挖造成围岩破坏,其破坏方式可归纳分析为两类：张拉型破坏和压剪型破坏,这两种破坏导致的裂隙面的细观形态并不相同,这种不同的细观形态导致张拉和压剪型裂隙的渗透率表现出不同的演化规律。为此,对花岗岩进行了不同围压下三轴压缩试验,产生张拉和压剪型裂隙,进行含裂隙岩样在静水压力加载条件下渗透系数试验。试验表明,相比于含压剪裂隙试样,含张拉裂隙试样的渗透率对静水压力更敏感。进而,分别对不同围压条件下的三轴压缩试验获得的张拉和压剪裂隙面进行扫描电镜试验,获得张拉和压剪裂隙面的细观形态,花岗岩单轴压缩试验所产生的裂隙面表现为典型的张拉型裂隙,破裂面比较光滑;随着围压的不断增大,破裂面的细观形态发生明显的变化,从破裂面上可以明显地观察到逐渐增多的压剪型裂隙,破裂面比较粗糙。在静水压力的作用下,张拉裂隙较快闭合;而压剪裂隙的锯齿能够一定程度上阻止裂隙的闭合。张拉和压剪裂隙面的不同细观结构决定了含张拉和压剪裂隙岩样的不同渗透率演化规律。研究结果对于地下工程分析中确定围岩的渗透率具有一定的意义。     

Geochemical characteristics and evaluation of minor and trace elements pollution in groundwater of Tuticorin city,Tamil Nadu,India using geospatial techniques

In this work the major and trace elements pollution levels in groundwater of Tuticorin city of Tamil Nadu was investigated. This coastal city with numerous large and small scale industries has increasingly affected the water quality by dumping effluents. The mean major and trace elements levels in groundwater in descending order: Si > Sr > Zn > Fe > Rb > Se > Al > Mn > Cu > As > Cr > Ba > V > Ni > Pb > Mo > Co > Sb > Cd > Ag. The concentrations of As, Se, Pb, Ba, Al, Fe and V (0.084, 0.150, 0.057, 0.837, 0.357 and 0.052) in some of the groundwater samples exceed the standard value of world health organization (WHO, 2004). Interrelationship between the elements was done by correlation matrix and factor analysis which indicates the contribution from industrial and irrigation fields. Spatial interpolation of inverse distance method (IDW) maps of all the elements suggested that discharge of effluents from chemical factory (STERLITE, TAC, SPIC, HEAVY WATER PLANT, NILA SEA FOODS), municipal wastewater, fertilizers were added to the natural sources. Results of this research suggests that proper measures should be taken to protect the vital groundwater resources in the Tuticorin city.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

Local ice caps in Finderup Land,North Greenland,survived the Holocene Thermal Maximum

Local glaciers and ice caps (GICs) comprise only ~5.4% of the total ice volume, but account for ~14–20% of the current ice loss in Greenland. The glacial history of GICs is not well constrained, however, and little is known about how they reacted to Holocene climate changes. Specifically, in North Greenland, there is limited knowledge about past GIC fluctuations and whether they survived the Holocene Thermal Maximum (HTM, ~8 to 5 ka). In this study, we use proglacial lake records to constrain the ice‐marginal fluctuations of three local ice caps in North Greenland including Flade Isblink, the largest ice cap in Greenland. Additionally, we have radiocarbon dated reworked marine molluscs in Little Ice Age (LIA) moraines adjacent to the Flade Isblink, which reveal when the ice cap was smaller than present. We found that outlet glaciers from Flade Isblink retreated inland of their present extent from ~9.4 to 0.2 cal. ka BP. The proglacial lake records, however, demonstrate that the lakes continued to receive glacial meltwater throughout the entire Holocene. This implies that GICs in Finderup Land survived the HTM. Our results are consistent with other observations from North Greenland but differ from locations in southern Greenland where all records show that the local ice caps at low and intermediate elevations disappeared completely during the HTM. We explain the north–south gradient in glacier response as a result of sensitivity to increased temperature and precipitation. While the increased temperatures during the HTM led to a complete melting of GICs in southern Greenland, GICs remained in North Greenland probably because the melting was counterbalanced by increased precipitation due to a reduction in Arctic sea‐ice extent and/or increased poleward moisture transport.     

Cyclic inelastic behavior and analytical modelling of pile–leg interaction in jacket type offshore platforms

Structures in locations susceptible to severe seismic disturbances should be designed properly in order to resist lateral forces induced by earthquake motions. Steel offshore platforms are some of those structures which are built to withstand environmental and accidental loads during oil exploitation operation. Particular attention is being paid to earthquake loads in seismic active areas because it directly influences the capacity of the offshore installations.

In this paper, a small-scaled planar platform has been modelled analytically using nonlinear finite element program, based on an experimental test, conducted simultaneously in order to assess the local and global behavior of pile–leg interaction in Jacket Type Offshore Platforms (JTOPs). A combination of nonlinear beam column elements and fatigue affected elements are used to capture the inelastic cyclic behavior of planar frame as accurately as possible. Results of analytical tests are to be compared with experiments and it is concluded that an analytical approach can be best used for modelling JTOPs with reasonable accuracy regardless of the type and scale of the structure. Moreover, a special study on joints has been carried out and the best model has been selected to simulate brittle behavior of joints resulting from heat affected zone.     

Microphysical Characteristics of Extreme-Rainfall Convection over the Pearl River Delta Region,South China from Polarimetric Radar Data during the Pre-summer Rainy Season

During the pre-summer rainy season, heavy rainfall occurs frequently in South China. Based on polarimetric radar observations, the microphysical characteristics and processes of convective features associated with extreme rainfall rates(ERCFs) are examined. In the regions with high ERCF occurrence frequency, sub-regional differences are found in the lightning flash rate(LFR) distributions. In the region with higher LFRs, the ERCFs have larger volumes of high reflectivity factor above the freezin...     

Variability of Raindrop Size Distribution during a Regional Freezing Rain Event in the Jianghan Plain of Central China

The characteristics of the raindrop size distribution(DSD) during regional freezing rain(FR) events that occur throughout the phase change(from liquid to solid) are poorly understood due to limited observations. We investigate the evolution of microphysical parameters and the key formation mechanisms of regional FR using the DSDs from five disdrometer sites in January 2018 in the Jianghan Plain(JHP) of Central China. FR is identified via the size and velocity distribution measured from a disdrom...     

Contrasting Regional Responses of Indian Summer Monsoon Rainfall to Exhausted Spring and Concurrently Emerging Summer El Ni?o Events

The inverse relationship between the warm phase of the El Ni?o Southern Oscillation(ENSO) and the Indian Summer Monsoon Rainfall(ISMR) is well established. Yet, some El Ni?o events that occur in the early months of the year(boreal spring) transform into a neutral phase before the start of summer, whereas others begin in the boreal summer and persist in a positive phase throughout the summer monsoon season. This study investigates the distinct influences of an exhausted spring El Ni?o(springtime)...     

Shock Wave Effects from the Impacts of Cosmic Objects with Diameters from 20 m to 3 km

Izvestiya, Physics of the Solid Earth - Abstract—Destruction on the Earth’s surface caused by a shock wave is one of the most important and dangerous effects from asteroid and comet...