Hypoxia in the northern Gulf of Mexico: Does the science support the Plan to Reduce,Mitigate, and Control Hypoxia?

We update and reevaluate the scientific information on the distribution, history, and causes of continental shelf hypoxia that supports the 2001 Action Plan for Reducing, Mitigating, and Controlling Hypoxia in the Northern Gulf of Mexico (Mississippi River/Gulf of Mexico Watershed Nutrient Task Force 2001), incorporating data, publications, and research results produced since the 1999 integrated assessment. The metric of mid-summer hypoxic area on the LouisianaTexas shelf is an adequate and suitable measure for continued efforts to reduce nutrients loads from the Mississippi River and hypoxia in the northern Gulf of Mexico as outlined in the Action Plan. More frequent measurements of simple metrics (e.g., area and volume) from late spring through late summer would ensure that the metric is representative of the system in any given year and useful in a public discourse of conditions and causes. The long-term data on hypoxia, sources of nutrients, associated biological parameters, and paleoindicators continue to verify and strengthen the relationship between the nitratenitrogen load of the Mississippi River, the extent of hypoxia, and changes in the coastal ecosystem (eutrophication and worsening hypoxia). Multiple lines of evidence, some of them representing independent data sources, are consistent with the big picture pattern of increased eutrophication as a result of long-term nutrient increases that result in excess carbon production and accumulation and, ultimately, bottom water hypoxia. The additional findings arising since 1999 strengthen the science supporting the Action Plan that focuses on reducing nutrient loads, primarily nitrogen, through multiple actions to reduce the size of the hypoxic zone in the northern Gulf of Mexico.     

A Procedure for Determining the Reaction Curve of Shotcrete Lining Considering Transient Conditions

Summary The mechanical behaviour of a shotcrete lining is analysed in this paper using the convergence-confinement approach. A calculation procedure is presented which is able to provide the reaction curve of a lining with increasing stiffness, by taking into account the variability due to time of the shotcrete stiffness and strength, as well as the face advancement rate. The proposed procedure is also able to provide the change of the safety factor of the lining in time. This results to be a very useful tool for understanding the behaviour of this widely used support and for assigning its thickness to guarantee stability (also in transient conditions), with a known safety factor, during tunnel excavation. Received May 25, 2001; accepted July 18, 2002; Published online January 21, 2003 Acknowledgements The author would like to thank Prof. S. Pelizza and Dr. S. Xu for the help given during the preparation of this paper. The help of the Editor G. Barla is also acknowledged. Authors' address: Dr. P. P. Oreste, Department of Earth Resources and Land, Politecnics di Torino, corso Duca degli Abruzzi 24, 1-10129 Torino, Italy; e-mail: oreste@polito.it     

Annealing studies of fission tracks in allanite

The annealing characteristics of fission tracks in allanite have been studied. All the tracks in the mineral fade at 720° C for one hour heating. The activation energy of allanite ranges from 1.4 to 3.4 eV.     

85 Peg A: what age for a low-metallicity solar-like star?

We explore the possible evolutionary status of the primary component of the binary 85 Pegasi, listed as a target for asteroseismic observations by the MOST satellite. In spite of the assessed 'subdwarf' status, and of the accurate distance determination from the Hipparcos data, the uncertainties in the metallicity and age, coupled with the uncertainty in the theoretical models, lead to a range of predictions on the oscillation frequency spectrum. Nevertheless, the determination of the ratio between the small separation in frequency modes, and the large separation as suggested by Roxburgh, provides a very good measure of the star age, quite independent of the metallicity in the assumed uncertainty range. In this range, the constraint on the dynamical mass and the further constraint provided by the assumption that the maximum age is 14 Gyr limits the mass of 85 Peg A to the range from 0.75 to  0.82 M_⊙  . This difference of a few hundredths of a solar mass leads to well detectable differences both in the evolutionary stage (age) and in the asteroseismic properties. We show that the age determination which will be possible through the asteroseismic measurements for this star is independent either of the convection model adopted or the microscopic metal diffusion. The latter conclusion is strengthened by the fact that, although metal diffusion is still described in an approximate way, recent observations suggest that real stars suffer a smaller metal sedimentation compared with the models.     

Probabilities of occurrence of great earthquakes in the Himalaya

Long-term conditional probabilities of occurrence of great earthquakes along the Himalaya plate boundary seismic zone have been estimated. The chance of occurrence of at least one great earthquake along this seismic zone over a period of 100 years (beginning the year 1999) is estimated to be about 0.89. The 100-year probability of such an earthquake occurring in the Kashmir seismic gap is about 0.27, in the central seismic gap about 0.52 and in the Assam gap about 0.21. The 25-year probabilities of their occurrence in these gaps are 0.07, 0.17, and 0.05 respectively. These probability estimates may be used profitably to assess the seismic hazard in the Himalaya and the adjoining Ganga plains.     

The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as:

where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units):

$\text{pK}{}_{\mathrm{w}}\text{=}\text{3441.0}\text{T}\text{+2.256-0.7091}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(}\text{rms deviation 0.01}\text{)}$

where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.