A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

Nutrient variability during El Niño 1997–98 in the California current system off central California

Nutrient conditions off central California during the 1997–98 El Niño are described. Data were collected on 11 cruises from March 1997 to January 1999 along a hydrographic section off central California, as well as every two weeks at a coastal station in Monterey Bay. Perturbations associated with El Niño are shown as anomalies of thermohaline and nutrient distributions along this section. The anomalies were obtained by subtracting seasonal averages for the period from April 1988 to April 1991 from the 1997–98 observations. The first indications of El Niño conditions (high sea levels) were observed at Monterey between late May and early June 1997, but the coastal nutricline did not begin to deepen until August 1997. It reached maximum depth of 130 dbar in January 1998 at the time that maximum sea level anomalies were observed. During this period: (1) the highest subsurface temperature anomalies coincided with subsurface nutrient anomaly minima at the depth of the pycnocline; (2) southern saline and nutrient-poor waters occupied the upper 80 dbar of the water column along the entire section; and (3) nitrate levels were close to zero in the euphotic zone, collapsing the potential new primary production in the coastal domain. At the end of February 1998, the nutricline shoaled to 40 dbar at the coast although it remained anomalously deep offshore. Higher temperatures and lower nutrient levels were observed for the entire section through August 1998 although in contrast with the previous winter, there was a strong freshening mainly due to an onshore movement of subarctic waters.     

Fractal Dimension and Fractals in Ocean Engineering

- This paper discusses the application of fractal dimension and fractals in ocean engineering. To handle some ocean environment problems, the existing fractal method, in which the fractal dimension is a constant, can be used. For some complicated problems in ocean engineering, this paper presents the concept of the variable dimension fractals (D = f(r)), i. e., the fractal dimension D is the function of characteristic scale r instead of a constant. By using variable dimension fractals, several deformation and stress states of offshore structures are described.     

Voracious planktonic hydroids: unexpected predatory impact on a coastal marine ecosystem

Hydroids are typically attached, benthic cnidarians that feed on a variety of small prey. During sampling on Georges Bank in spring 1994, we found huge numbers of hydroids suspended in the plankton. They fed on young stages of copepods that are an important prey for fish, as well as on young fish themselves. Two independent methods were used to estimate feeding rates of the hydroids; both indicate that the hydroids are capable of consuming from 50% to over 100% of the daily production of young copepods. These results suggest that hydroids can have a profound effect on the population dynamics of zooplankton and young fish on Georges Bank.     

Trace metal concentrations in sediments of the Eastern Mississippi Bight

Sediments collected from 3 onshore-offshore transects (12 stations total) in the Eastern Mississippi Bight at 5 different times during 1987–1988 have been analyzed for total Ag, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sn, Th and Zn. The data show considerable variation both spatially and temporally, largely as a result of natural variability in grain size and mineralogy. Clay-rich samples from deep water were always more metal-rich than sandy samples from shallow areas. Many samples from near the Mississippi River Delta appeared to be enriched in Ba by about a factor of two, probably as a result of contamination from oil well drilling mud, but there were few other indications of pollution influences. Many samples from throughout the area gave Mn/Fe and Cd/Fe ratios a factor of two or more lower than their Mississippi River source material. This shows that biochemical activity in the sediment is capable of solubilizing reducible and adsorbed metals.     

Scaling analysis of deposition from turbidity currents

Many oil-bearing sedimentary deposits are formed by the settling of particles from turbidity currents. Modeling sedimentary processes that form these turbidites enables the calculation of properties such as extent, depth, porosity and permeability of hydrocarbon-bearing reservoirs. This paper estimates the extent and thickness of turbidites from the initial conditions of the turbidity flow. This is achieved by the application of scaling analysis of the partial differential equations that govern the dynamics of and deposition from turbidity currents. We apply the results of scaling analysis to five modern submarine fans. The predicted and actual values of the dimensions of the fan deposits match well. We then compare the derived results against tabulated sizes of ancient turbidites. The comparisons are good as long as we correctly identify the flow regimes in which the deposition took place. The good agreements observed in the two cases show that the estimates obtained using scaling analysis can provide useful first-guess values for the dimensions of the deposits.     

Specific Features of the Structure and Dynamics of Waters and Their Influence on the Distribution of Krill and Salpae in the Weddell and Scotia Seas in March–April, 1997–1998

We present the results of biological and oceanographic investigations performed in the Weddell and Scotia Seas within the framework of the first (January–June, 1997) and second (January–June, 1998) Ukrainian Antarctic marine expeditions. We reveal some regularities in the space distribution of the aggregations of krill and salpae depending on the abiotic (hydrophysical) environmental factors and discuss possible mechanisms promoting the formation of aggregations of krill and salpae in the Antarctic waters.     

Estimation of Contamination of ERS-2 and POSEIDON Satellite Radar Altimetry Close to the Coasts of Australia

It is broadly acknowledged that the precision of satellite-altimeter-measured instantaneous sea surface heights (SSH) is lower in coastal regions than in open oceans, due partly to contamination of the radar return from the coastal sea-surface state and from land topography. This study investigates the behavior of ERS-2 and POSEIDON altimeter waveform data in coastal regions and estimates a boundary around Australia's coasts in which the altimeter range may be poorly estimated by on-satellite tracking software. Over one million 20 Hz ERS-2 (March to April 1999) and POSEIDON (January 1998 to January 1999) radar altimeter waveform data were used over an area extending 350 km offshore Australia. The DS759.2 (5'resolution) ocean depth model and the GSHHS (0.2 km resolution) shoreline model were used together to define the coastal regions. Using the 50% threshold retracking points as the estimates of expected tracking gate, we determined that the sea surface height is contaminated out to maximum distance of between about 8 km and 22 km from the Australian shoreline for ERS-2, depending partly on coastal topography. Using the standard deviation of the mean waveforms as an indication of the general variability of the altimeter returns in the Australian coastal region shows obvious coastal contamination out to about 4 km for both altimeters, and less obvious contamination out to about 8 km for POSEIDON and 10 km for ERS-2. Therefore, ERS-2 and POSEIDON satellite altimeter data should be treated with some caution for distances less than about 22 km from the Australian coast and probably ignored altogether for distances less than 4 km.     

Release into the environment of metals by two vascular salt marsh plants

Metals in contaminated salt marshes are mainly locked in the anaerobic layer of sediments, where they are tightly bound as sulfides and organic complexes. Vascular plants survive in saturated soils in part by pumping O2 into their root zones, changing their microenvironment to an oxic one. This, along with chelating exudates, mobilizes metals, allowing uptake by the roots. We compared the common reed Phragmites australis and cordgrass Spartina alterniflora in lab and field studies for ways in which they handle trace metals. Both plants store most of their metal burden in their roots, but some is transported to aboveground tissues. Spartina leaves contain approximately 2-3 x more Cr, Pb, and Hg than Phragmites leaves, but equivalent Cu and Zn. Furthermore, Spartina leaves have salt glands, so leaf excretion of all metals is twice that of Phragmites. In-depth studies with Hg indicate that Hg excretion correlates with Na release but not with transpiration, which is 2.2 x higher in Phragmites; and that more Hg accumulates in early-appearing leaves than in upper (i.e. later) leaves in both species. Spartina thus makes more metals available to salt marsh ecosystems than Phragmites by direct excretion and via dead leaves which will enter the food web as detritus.