Giant versus small porphyry copper deposits of Cenozoic age in northern Chile: adakitic versus normal calc-alkaline magmatism

Cenozoic magmatic activity in northern Chile led to the formation of two contrasting porphyry copper belts: (1) a Paleocene-Early Eocene belt comprising small porphyry copper deposits (e.g., Lomas Bayas) of normal calc-alkaline affinity; and (2) a Late Eocene-Early Oligocene belt hosting huge porphyry copper deposits (e.g., Chuquicamata) of adakitic affinity. Although the first belt comprises both volcanic and plutonic rocks (andesitic-basaltic and rhyolitic lavas and tuffs, and associated sub-volcanic porphyries and felsic stocks), the latter only includes intrusions (mostly granodioritic types, including porphyry copper deposits). We suggest that the Late Eocene-Early Oligocene belt formed when fast and oblique convergence between the South America and Farallon plates led to flat subduction and direct melting of the subducting plate, hence giving rise to plutonic rocks of adakitic affinity. The absence of volcanism, under prevailing compressional conditions, prevented the escape of SO₂ from the adakitic, sulfur-rich, highly oxidized magmas ("closed porphyry system"), which allowed formation of huge mineral deposits. On the contrary, coeval volcanic activity during formation of the Paleocene-Early Eocene calc-alkaline porphyries allowed development of "open systems", hence to outgassing, and therefore, to small mineral deposits.     

Reply to the comment by F. Tornos et al.

We welcome the discussion of our paper by Tornos et al. The epithermal character of the Hiendelaencina veins might have been an assumption in the early to mid 1980s, however, this early idea has been reaffirmed after many years of research involving fieldwork and mineralogical, sulphur isotopes, and fluid inclusions studies. The same applies to the alleged extensional frame, a tectonic episode now well documented not only in central Spain (Spanish Central System: Doblas 1987; Doblas et al. 1988; Doblas 1991) but in France (French Central Massif: Ménard and Molnar 1988; Malavieille et al. 1990; Munoz et al. 1992).The deposits are hosted by metamorphic rocks and the nearest volcanic outcrops to Hiendelaencina are those of Atienza (andesites; some 12 km northward). This is the reason why the relationships between the Atienza volcanics and the Hiendelaencina veins were initially regarded as obscure. These Stephanian-Permian volcanic outcrops are only local evidence of the late Variscan magmatism, which in the case of Hiendelaencina remained concealed. It is evident that the geologic environments of Hiendelaencina and Atienza are very different (see Discussion, p. 88 of the paper). As a direct consequence of this, the local structural conditions led to contrasted expressions of the late Variscan magmatism i.e. subaereal at Atienza and hypabyssal at Hiendelaencina.     

Cu, Mn, and Ag mineralization in the Quebrada Marquesa Quadrangle, Chile: the Talcuna and Arqueros districts

The Quebrada Marquesa Quadrangle in Chile exhibits a series of mineralizations comprising manto-type manganese and copper deposits of Lower Cretaceous age, and copper and silver veins of Tertiary age. The deposits are hosted by volcanic and volcaniclastic units of the Arqueros (Hauterivian-Barremian) and Quebrada Marquesa (Barremian-Albian) Formations. Three episodes of manganese mineralization (Mn_1-3) are recognized within the study area. Hydrothermal activity leading to episodes 1 and 3 was of minor importance, while the second one (Mn₂) gave rise to major manto-type deposits of both manganese and copper in the Talcuna mining district. Extensional faulting during Tertiary time resulted in block faulting and the unroofing of the oldest andesitic volcanics and marine sediments (Arqueros Formation). This episode was accompanied by magmatic and hydrothermal activity leading to vein formation in the Arqueros (Ag) and Talcuna (Cu) districts. The latter veins cross-cut the previous manto-type copper deposits. Ore mineralogy is similar in both styles of mineralization (manto- and vein-type) and consists mainly of chalcopyrite and bornite, with variable amounts of galena, tetrahedrite (vein-related), chalcocite, sphalerite, pyrite, hematite, digenite and covellite. Alteration processes at Talcuna can be divided into two categories, those related to the Lower Cretaceous manto-type episode (LK alteration: chlorite-epidote-calcite-albite, prehnite, zeolite), and those associated with the locally mineralized normal faults of Tertiary age (Tt alteration: chlorite-calcite, sericite). The Arqueros silver veins display an ore mineralogy consisting of arquerite, argentite, native silver, polybasite, cerargyrite and pyrargyrite-proustite; associated alteration includes strong chloritization of the country rock. The manto-type deposits formed from fluids of salinity between 11 and 19 wt.% NaCl equivalent and temperatures between 120 and 205 °C. Mineralizing fluids during the vein-type stage circulated at lower temperatures, between 70 and 170 °C, with salinity values in a wide range from 3 to 27 wt.% NaCl equivalent. This distribution of salinities is interpreted as the result of the complex interplay of two different processes: boiling and fluid mixing; the former is considered to control the major mineralogical, textural and fluid inclusion features of the vein-type deposits. We suggest that the Lower Cretaceous mineralization (manto-type stage) developed in response to widespread hydrothermal activity (geothermal field-type) involving basinal brines. Received: 18 July 1997 / Accepted: 28 January 1998     

Progressive Build Up Of Co 2 In The AtmosphereOf Venus Through Multiple Volcanic Resurfacing Events

In absence of other mechanisms, the main input of CO₂into the Venusian atmosphere is via volcanic out gassing. Since Venus can be regarded as a planet-wide large igneous province, we can expect large quantities of CO₂ being transferred into its atmosphere via volcanic out gassing. We have quantified the maximum possible amount of CO₂ that can be out gassed via a single massive episode of resurfacing of the planet. This figure (5.6 × 10¹⁹ kg of CO₂) is about 8 times smaller than the total CO₂ present in the Venusian atmosphere (4.55 × 10²⁰ kg CO₂). The lack of planet-wide, efficient mechanisms for the recycling of CO₂ on Venus indicates that CO₂ has progressively accumulated in the atmosphere. Based on these considerations we suggest that the “equivalent” to eight global resurfacing episodes would be required to account for the present values of CO_{2 atmosphere}. This revised version was published online in July 2006 with corrections to the Cover Date.     

Are Coronae Restricted to Venus?: Corona-Like Tectonovolcanic Structures on Earth

Coronae may not be tectonovolcanic features ‘unique to Venus’ because both the processes that lead to corona formation, and their final tectonovolcanic output (formation of domes, plateaus, extensional rings, etc.), are also found on Earth. Large-scale corona formation processes on Earth may be restricted (because of plate motion) but not absent. The same applies to resurfacing processes. We here suggest that at least, the early stages of corona formation can be recognized in intraplate tectonic settings on Earth. The African plate displays many Cenozoic examples of plume-related domal uplifts and volcanism (e.g., Hoggar, Tibesti, Darfur, Ethiopia). Furthermore, the east African rift system (EARS) around lake Victoria displays many striking features that resemble those of the Venus coronae associated with extensional belts. Among these are the following: (1) an overall elliptical shape; (2) the existence of a mantle plume (Kenya plume) centered beneath lake Victoria; (3) a central plateau (east African plateau); (4) an external extensional belt (the EARS east and west branches); (5) doming processes (Kenya dome); and last but not least (6) volcanism. This revised version was published online in July 2006 with corrections to the Cover Date.     

First lead isotopic data for cinnabar in the Almadén district (Spain): implications for the genesis of the mercury deposits

The Almadén district constitutes the largest and probably the most intriguing mercury concentration in the world. Two types of mineralization are recognized: 1) stratabound, of Lower Silurian age, well represented by the large Almadén deposit; and 2) fully discordant mercury deposits of minor importance in terms of size, and exemplified by the deposit of Las Cuevas. The latter ones can be found at different positions along the Almadén stratigraphic column. Both types of deposits are always associated with the so-called frailesca rocks (diatremes of alkali basaltic composition). This paper reports the first lead isotope compositions of cinnabar in the district. Whole samples and stepwise leaching cinnabar aliquots display relatively homogeneous isotopic compositions (²⁰⁶Pb/²⁰⁴Pb = 18.112–18.460; ²⁰⁷Pb/²⁰⁴Pb = 15.635–15.705; ²⁰⁸Pb/²⁰⁴Pb = 38.531–38.826). Taken together with Jébrak et al.s (2002) pyrite lead isotope results, the new cinnabar isotopic data define a steep array trend on the ²⁰⁷Pb/²⁰⁴Pb– ²⁰⁶Pb/²⁰⁴Pb diagram, indicating a mixed contribution of lead and probably mercury from different sedimentary sources in the Almadén basin. The Almadén Hg deposits are related to a contemporaneous mafic magmatism that might have provided part of the mercury. Hydrothermal leaching of organic matter from sedimentary rocks and formation of Hg organic complexes enhanced metal solubility, promoting transport from and within the volcanic units.Editorial handling: M. Chiaradia     

Geochemical Characterization of Magnetite and Geological Setting of the Iron Oxide ± Iron Silicate ± Iron Carbonate Rich Pb–Zn Sulfides from the La Unión and Mazarrón Stratabound Deposits (SE Spain)

From a mineralogical point of view the La Unión ore field (SE Spain) can be regarded as an oddity as some of its hydrothermal, stratabound type deposits display an extremely unusual paragenesis comprising magnetite ± greenalite ± minnesotaite ± siderite and galena ± sphalerite (IOSC – LZS). Recent mineralogical studies have shown that this paragenesis is also present at the neighboring Mazarrón ore field. These ore fields share a similar geologic setting, involving metamorphic and sedimentary rocks (Paleozoic s.l. to Permian) hosting late Miocene high‐K calc‐alkaline volcanic and subvolcanic rocks. The latter have andesitic to dacitic composition, and triggered hydrothermal activity and ore deposition. This study discusses the detailed mineral chemistry of magnetite samples from Mazarrón and La Unión and provides some hints for the origin of the IOSC – LZS paragenesis. We performed electron microprobe (EPMA) analyses in magnetite samples from La Unión and Mazarrón to determine the contents of minor and trace elements (Zn, Ni, Mn, Cr, V, K, Ca, Ti, Al, Si, Mg). Given that some results fell below the detection limit for the EPMA instrumental conditions we used robust regression on order statistics (robust ROS), with the NADA package in R to deal with these data sets. The Ca + Al + Mn contents in magnetites from San Cristóbal and Emilia are equivalent to the mean contents of those of IOCG, Kiruna, BIF, Cu porphyry, skarn, VMS, hydrothermal and clastic Pb–Zn deposits, but they are low in Ti + V and Ni + Cr. The principal components analysis indicates that Zn, Ni, Cr, V, K, Ca, Ti, and Mg are roughly collinear, therefore correlated, being also independent from Fe. Besides, the function discriminant analysis of data shows that the magnetites from Emilia and San Cristóbal cluster in differentiated groups, thus probably reflecting some differences related to the distance to the magmatic source that triggered the hydrothermal system: proximal in the case of San Cristóbal and distal in Emilia.     

Bioenergetics of parental investment in two polychaete species with contrasting reproductive strategies: The planktotrophic Boccardia chilensis and the poecilogonic Boccardia wellingtonensis (Spionidae)

The level of parental investment for larval nutrition may determine the life cycle in marine invertebrate species laying egg masses or capsules, where the food available for enclosed individuals would determine time and developmental stage of hatching. Most species show a unique type of larval development. However, few species are poecilogonous and combine more than one development type. Poecilogony, although scarcely studied, allows comparing different patterns of parental reproductive investment, without the phylogenetic effect of the species ancestral modes of development (phylogenetic inertia), to help to understand the factors determining life strategy evolution in marine invertebrates. The poecilogonous polychaete worm Boccardia wellingtonensis encapsulates and incubates its offspring, which then hatches as either planktotrophic larvae or benthic juveniles; while Boccardia chilensis shows a non-poecilogonous reproductive type, producing only planktotrophic larvae. In this work, we estimated the bioenergetic and biochemical composition of brooding and non-brooding females of B. wellingtonensis and B. chilensis to compare the costs of reproduction in these two species. Results showed that glucose, protein, lipid, and energy content were significantly higher in non-brooding than in brooding females of B. wellingtonensis; but also contained significantly more glucose, protein, and lipid than females of B. chilensis (in absolute and relative dry weight values). The poecilogonous species showed higher energy content previous to laying offspring. Our results support the idea that the evolution of a certain reproductive and life history traits in marine invertebrates is related to adaptations in the female's reproductive investment.     

Porphyry copper and tin-bearing porphyries a discussion of genetic models

The paper briefly describes the characteristics of the Chilean porphyry copper deposits, emphasizing the volcanic characteristics observed in the youngest ore bodies. Mention is made of the polymetallic ore bodies that are associated with rhyolitic porphyries intruding Jurassic sedimentary formations in the north of Chile, and the similarities and differences between the Chilean porphyry coppers and the Bolivian tin-bearing porphyries are pointed out.The models proposed by Sillitoe (1972), Brousse and Oyarzún (1971), and Mitchell and Garson (1972), are discussed and a new model is proposed agreeing with that of Mitchell and Garson for the genesis of the tin-bearing porphyries (the transportation of Sn as volatile halogenide by F liberated in the Benioff zone), but suggesting different generating mechanism for the porphyry coppers and polymetallic deposits related with porphyries. This mechanism, as a part of the global tectonic model, is based on the separation at depth of hydrogen sulphide from pyrite and water introduced with the upper layers of the lithospheric plate. The ascending migration of H₂S to high levels in the crust would be responsible for the porphyry copper mineralization by segregating sulphides of Fe, Cu, Mo and other sulphophile metals contained in the calc-alkaline magmas, brines, or sedimentary-volcanic formations intruded by the porphyries. The excess of H₂S would give rise to the formation of sulphur deposits normally present in the volcanic belt situated along the same line but at a higher level than those of the emplacement of porphyry coppers.The generation of copper and tin-bearing porphyries would be a consequence of the upward migration of volatile substances from different depths in the subduction zone, which explain its different emplacement with regards to the continental margins.     

Soil erosion and overland flow in forested areas with pine plantations at coastal mountain range,central chile

The effects of timber-cutting on sediment concentrations, soil loss and overland flow in an insigne pine (Pinus radiata) plantation were studied in a mountain watershed of the Cordillera de la Costa, central Chile. Soil formation rates for the lithological conditions of the watershed were estimated. Soil loss measurements on the plantation were taken in 100 m² plots, equipped with Coshocton samplers, during the years 1991 and 1992. Treatments were: clear-cutting no residues/burned, clear-cutting with residues and undisturbed controls. First-year soil losses were greater from the no residues/burned (2128 kg ha^?1) than from the residues (1219 kg ha^?1) or undisturbed (48 kg ha^?1) plots. During the second post-treatment year, soil loss was greater from the burned plots (1349 kg ha^?1) than from the residues (243 kg ha^?1) or the undisturbed (72 kg ha^?1) plots. Sediment concentrations for the three treatments were 561, 340 and 59 mgl-¹ during the first year, and 400, 150 and 83 mgl^?1 in the second year. Runoff from the no residues/burned plots was greater than from residues or undisturbed plots during the two post-treatment years. Long-term soil losses were projected to average 240 kg ha^?1 yr^?1 from areas without residues/burned and 120 kg ha^?1 yr^?1 in areas with residues treatment, over a 25 year rotation period, whereas control areas were projected to average 60 kg ha^?1 yr^?1.