Heavy metals pollution of aquatic ecosystems in the vicinity of a recently closed underground lead-zinc mine (Basque Country, Spain)

A presentation is made of the study of an underground polymetallic sulphide mine and the pollution caused by this in the adjoining aquatic ecosystems. Troya Mine is in the Basque Cantabrian region (northern Spain). The annual production of the ore deposit of over 3.7 million tons of Pb (0.9%), Zn (11.2%) and Cu (0.2%) was 300,000 t. It was open and producing from 1986-1993. The mineralization was made up of pyrite, marcasite, sphalerite, galena, chalcopyrite and arsenopyrite. Only the Zn and the Pb were mined. We studied the distribution and behaviour of the heavy metals Zn, Pb, Fe, Mn, Cu, Cr and Cd in the water column, dissolved and suspended fractions, and in the sediments of Estanda Stream and of Gezala Creek. Zn, Cd and Mn tend to be found in the water; Fe, Pb, Cu and Cr appear as an adsorbed fractionin the solid phases. Those of the second group are significantly linked to the fluvial sediments and present very high levels. The concentrations of the metals are conditioned by the waters from the mine galleries, by the leached waste, by the surface runoff, and by overflow from the spillway of the tailings pond. Our observations provide knowledge on the extent of the polluting power of the metals, the physico-chemical effects in play and the subsequent chances of recovering these highly affected environments.     

Structural and kinematic analysis of the Corredoiras detachment: evidence for early Variscan synconvergent extension in the Ordenes Complex, NW Spain

 An important detachment is described in the allochthonous Ordenes Complex, in the NW Iberian Massif, and its meaning is related to the kinematics of contemporaneous convergent structures. The Corredoiras Detachment (CD) separates a hangingwall unit, characterised by a medium-pressure metamorphic gradient, from a footwall high-pressure and high-temperature unit and an underlying ophiolitic unit. An associated ductile shear zone, nearly 2000 m thick, developed in the lower part of the hangingwall unit, where the Corredoiras Orthogneiss, a Lower Ordovician metagranite, was progressively transformed into augengneisses, mylonitic and ultramylonitic gneisses. The attitude of the stretching and mineral lineation in the mylonites varies due to late refolding at map scale, but the sense of movement can be estimated, being roughly top to the SE. According to crosscutting relationships, the CD developed subsequent to the thrusting of the high-pressure/high-temperature unit onto the ophiolitic unit, and prior to younger extensional detachments, upright folding and strike-slip tectonics. The geometric relationships of the CD with the previous structures in the footwall unit, the subtractive character of the metamorphic gap between its hangingwall and footwall, and the available isotopic data suggest that the CD is an early Variscan, ductile extensional detachment, the movement of which was roughly simultaneous with the onset of thrusting of the allochthonous complexes over their relative autochthon. Received: 17 November 1998 / Accepted: 4 April 1999     

Radio Emission from Three-dimensional Relativistic Hydrodynamic Jets: Observational Evidence of Jet Stratification

High-resolution, high signal-to-noise ratio, blue-violet spectra of three red giant branch tip stars in M15 have been obtained with the Keck I High-Resolution Echelle Spectrograph. These spectra have been analyzed to determine the abundances of several neutron-capture elements, including the radioactive chronometer element thorium. There are two principal results of this study. First, the abundances of the heavier (Z>/=56) elements for each of the three stars is well matched by a scaled solar system r-process abundance distribution. Second, a weighted mean-observed Th/Eu ratio for the stars implies an age for the neutron-capture material in M15 stars of 14+/-3 Gyr, in reasonable agreement with other recent age estimates for Galactic globular clusters.     

Understory and small trees contribute importantly to stemflow of a lower montane cloud forest

Stemflow (Sf) measurements in tropical rain and montane forests dominated by large trees rarely include the understory and small trees. In this study, contributions of lower (1‐ to 2‐m height) and upper (>2‐m height and <5‐cm diameter at breast height [DBH]) woody understory, small trees (5 < DBH < 10 cm), and canopy trees (>10‐cm DBH) to Sf per unit ground area (Sf_a) of a Mexican lower montane cloud forest were quantified for 32 days with rainfall (P) during the 2014 wet season. Rainfall, stemflow yield (Sf_y), vegetation height, density, and basal area were measured. Subsequently, stemflow funneling ratios (SFRs) were calculated, and three common methods to scale up Sf_y from individual trees to the stand level (tree‐Sf_y correlation, P‐Sf_y correlation, and mean‐Sf_y extrapolation) were used to calculate Sf_a. Understory woody plants, small trees, and upper canopy trees represented 96%, 2%, and 2%, respectively, of the total density. Upper canopy trees had the lowest SFRs (1.6 ± 0.5 Standard Error (SE) on average), although the lower understory had the highest (36.1 ± 6.4). Small trees and upper understory presented similar SFRs (22.9 ± 5.4 and 20.2 ± 3.9, respectively). Different Sf scaling methods generally yielded similar results. Overall Sf_a during the study period was 22.7 mm (4.5% of rainfall), to which the understory contributed 70.1% (15.9 mm), small trees 10.6% (2.4 mm), and upper canopy trees 19.3% (4.4 mm). Our results strongly suggest that for humid tropical forests with dense understory of woody plants and small trees, Sf of these groups should be measured to avoid an underestimation of overall Sf at the stand level.     

Geological,geophysical and geochemical structure of a fault zone developed in granitic rocks: Implications for fault zone modeling in 3-D

The structure of a fault zone developed in granitic rocks can be established on the basis of the spatial variability of geological, geophysical and geochemical parameters. In the North Fault of the Mina Ratones area (SW Iberian Massif, Spain), fault rocks along two studied traverses (SR-2 and SR-3 boreholes) exhibit systematic changes in mineralogy, geochemistry, fabrics and microstructures that are related to brittle deformation and alteration of granite to form cataclasite and subsequent gouge. The spatial distribution and intensity of these changes suggest a North Fault morphology that is consistent with the fault-core/damage-zone model proposed by Chester et al. (1993) to describe a fault zone architecture. North Fault damage zone thickness can be defined by the development of mechanically related mesoscopic faults and joints, that produce a Fracture Index (FI)>10. High FI values are spatially correlated with relative low seismic velocity zones (V_P<5 km/s and V_S<2.5 km/s in the well-logs), more probably related to a high concentration of fractures and geochemical alteration produced by meteoric water-granite interaction along fault surfaces. This correlation is the base of a geostatistical model proposed in the final part of this study to image the fault zone architecture of a granitic massif.     

Low calcification rates and calcium carbonate production in Porites panamensis at its northernmost geographic distribution

Porites panamensis is a hermatypic coral present in the eastern Pacific Ocean. Skeletal growth parameters have been reported, but studies of the relationship between annual calcification rates and environmental controls are scarce. In this study, we investigated three aspects of the annual calcification rates of P. panamensis: growth parameters among three P. panamensis populations; the sea surface temperature as a calcification rate control spanning a latitudinal gradient; and calcium carbonate production among three sites. Growth parameters varied among the sites due to the colony growth form. Massive colonies in the north showed a higher calcification rate than encrusting colonies in the south (mean: 1.22–0.49 g CaCO₃ · cm^?2 · yr^?1), where variations in calcification rates were related to growth rate (0.91–0.38 cm · yr^?1) rather than to skeletal density differences (overall mean ± SD, 1.31 ± 0.04 g CaCO₃ · cm^?3). Our results showed a positive linear relationship between annual calcification rates and sea surface temperatures within these P. panamensis populations. Differences were related to distinct oceanographic environments (within and at the entrance of the Gulf of California) with different sea surface temperature regimes and other chemical properties. Different populations calcified under different environmental conditions. Calcium carbonate production was dependent upon the calcification rate and coral cover and so carbonate production was higher in the north (coral cover 12%) than in the south (coral cover 3.5). Thus, the studied sites showed low calcium carbonate production (0.25–0.43 kg CaCO₃ · m^?2 · yr^?1). Our results showed reduced calcification rates, regional temperature regime control over calcification rates, different growth forms, low coral cover and low calcium carbonate production rates in P. panamensis.     

Moving bed biofilm reactor to treat wastewater

This review carries out a comparative study of advanced technologies to design, upgrade and rehabilitate wastewater treatment plants. The study analyzed the relevant researches in the last years about the moving bed biofilm reactor process with only attached biomass and with hybrid biomass, which combined attached and suspended growth; both could be coupled with a secondary settling tank or microfiltration/ultrafiltration membrane as a separation system. The physical process of membrane separation improved the organic matter and NH₄ ⁺-N removal efficiencies compared with the settling tank. In particular, the pure moving bed biofilm reactor–membrane bioreactor showed average chemical oxygen demand, biochemical oxygen demand on the fifth day and total nitrogen removal efficiencies of 88.32, 90.84 and 60.17%, respectively, and the hybrid moving bed biofilm reactor–membrane bioreactor had mean chemical oxygen demand, biochemical oxygen demand on the fifth day and total nitrogen reduction percentages of 91.18, 97.34 and 68.71%, respectively. Moreover, the hybrid moving bed biofilm reactor–membrane bioreactor showed the best efficiency regarding organic matter removal for low hydraulic retention times, so this system would enable the rehabilitation of activated sludge plants and membrane bioreactors that did not comply with legislation regarding organic matter removal. As the pure moving bed biofilm reactor–membrane bioreactor performed better than the hybrid moving bed biofilm reactor–membrane bioreactor concerning the total nitrogen removal under low hydraulic retention times, this system could be used to adapt wastewater treatment plants whose effluent was flowed into sensitive zones where total nitrogen concentration was restricted. This technology has been reliably used to upgrade overloaded existing conventional activated sludge plants, to treat wastewater coming from textile, petrochemical, pharmaceutical, paper mill or hospital effluents, to treat wastewater containing recalcitrant compounds efficiently, and to treat wastewater with high salinity and/or low and high temperatures.     

Probabilistic calibration of a distributed hydrological model for flood forecasting

Abstract

The complexity of distributed hydrological models has led to improvements in calibration methodologies in recent years. There are various manual, automatic and hybrid methods of calibration. Most use a single objective function to calculate estimation errors. The use of multi-objective calibration improves results, since different aspects of the hydrograph may be considered simultaneously. However, the uncertainty of estimates from a hydrological model can only be taken into account by using a probabilistic approach. This paper presents a calibration method of probabilistic nature, based on the determination of probability functions that best characterize different parameters of the model. The method was applied to the Real-time Interactive Basin Simulator (RIBS) distributed hydrological model using the Manzanares River basin in Spain as a case study. The proposed method allows us to consider the uncertainty in the model estimates by obtaining the probability distributions of flows in the flood hydrograph.

Citation Mediero, L., Garrote, L. & Martín-Carrasco, F. J. (2011) Probabilistic calibration of a distributed hydrological model for flood forecasting. Hydrol. Sci. J. 56(7), 1129–1149.