How do granitoid magmas mix with each other? Insights from textures,trace element and Sr–Nd isotopic composition of apatite and titanite from the Matok pluton (South Africa)

In plutonic systems, magma mixing is often modelled by mass balance based on whole-rock geochemistry. However, magma mixing is a chaotic process and chemical equilibration is controlled by non-linear diffusive–advective processes unresolved by the study of bulk samples. Here we present textural observations, LA-(MC-)ICP-MS trace element and Sr–Nd isotopic data of accessory apatites and titanites from a hybrid granodiorite of the Neoarchean Matok pluton (South Africa), collected in a zone of conspicuous mixing between mafic and felsic magmas. Apatite grains mostly show a pronounced zoning in CL images, corresponding to abrupt changes in REE and HFSE concentrations recording their transfer through compositionally different melt domains during mixing. These grains crystallized early, at temperatures of 950–1000 °C. Titanite grains crystallized at temperatures of 820–900 °C (Zr-in-sphene thermometry). They show limited intra-grain chemical variations but huge inter-grain compositional scatter in REE and HFSE, pinpointing crystallization within a crystal mush, from isolated melt pockets having different composition from one another owing to incomplete chemical homogenization and variable Rayleigh fractionation. These chemical–textural characteristics, in combination with partitioning models and Polytopic Vector Analysis, point to “self-mixing” between co-genetic dioritic and granodioritic/granitic magmas. Both resulted from differentiation of mantle-derived mafic melts, showing that mixing does not necessarily involve magmas from contrasted (crust vs. mantle) sources. Systematic variations in εNd _t (?4.5 to ?2.5) and ⁸⁷Sr/⁸⁶Sr_(i) (0.703–0.707) of titanite and apatite grains/domains crystallized from the two magmas point to an isotopically inhomogeneous mantle source, which is not resolved by bulk-rock isotopic data. Interaction between the two magmas must have occurred at relatively high temperatures (ca. 900°C) so that their viscosity contrast remained low, allowing efficient mechanical mixing. Despite this, chemical homogenization was incomplete, as recorded by diffusive fractionation between REE–HFSE and Sr. Modelling thereof reveals that chemical exchange between the liquid phases of the two mixed magmas did not last more than a few tens to hundreds of years. The chemical equilibration between mixed magmas thus strongly depends on the considered elements and observational length scales.     

Dynamic of the freshwater–saltwater interface in a karstic aquifer under extraordinary recharge action: the Merida Yucatan case study

A hydraulic analysis of the interface between freshwater–saltwater behavior was done in the Merida Yucatan zone, two machines that constantly register the groundwater levels were installed, and three electric conductivity logs were taken from wells. When comparing the measured results with the ones obtained using theoretical equations developed to calculate the freshwater–saltwater interface position, it was proved that in some cases these equations can be applied, and in others not. Two effects that rule the behavior of karst aquifers in extraordinary conditions were found.     

Petrology of pumices of April 1993 eruption of Lascar (Atacama, Chile)

Lascar Volcano (Atacama, Chile) erupted on 18–20 April 1993. Several sub-Plinian explosions occurred, and some were mushroom-shaped. The highest column rose up to 23 km. Ash clouds crossed South America eastwards. Dacite pumice falls made of blocks and ashes were deposited on the flanks of the volcano as a result of collapsed columns. The pumice contains phenocrysts of plagioclase, enstatite, augite, biotite, magnetite and ilmenite and small crystals of apatite. The 1992 previous andesite dome inside the crater was destroyed. Banded blocks resulting from mingling of the dacitic pumice and andesite from the dome are found in the pumice flow. Both the lava dome and the pumice are representative of the Lascar high-K magma unit. Dacitic pumice is a product of crystal fractionation of the andesitic magma.     

Modal pushover‐based scaling of earthquake records for nonlinear analysis of single‐story unsymmetric‐plan buildings

The modal pushover‐based scaling (MPS) procedure, currently restricted to symmetric‐plan buildings, is extended herein to unsymmetric‐plan buildings. The accuracy of the extended MPS procedure was evaluated for a large set of three‐degree‐of‐freedom unsymmetric‐plan structures with variable stiffness and strength. The structures were subjected to nonlinear response history analysis considering sets of seven records scaled according to the MPS procedure. Structural responses were compared against the benchmark values, defined as the median values of the engineering demand parameters due to 30 unscaled records. This evaluation of the MPS procedure has led to the following conclusions: (i) the MPS procedure provided accurate estimates of median engineering demand parameter values and reduced record‐to‐record variability of the responses; and (2) the MPS procedure is found to be much superior compared to the ASCE/SEI 7‐10 scaling procedure for three‐dimensional analysis of unsymmetric‐plan buildings. Copyright © 2013 John Wiley & Sons, Ltd.     

The Southwest Atlantic intertidal burrowing crab Neohelice granulata modifies nutrient loads of phreatic waters entering coastal area

Along the coastal areas of the Southwest Atlantic estuaries and embayments, phreatic water often circulates through very extended areas (up to several hundred meters perpendicular to the coast), dominated by dense assemblages of deep burrows of the crab Neohelice granulata (formerly Chasmagnathus granulatus). This crab inhabits the intertidal area, from mudflats to marshes vegetated by species of Spartina, Sarcocornia and Juncus, generating extensive burrowing beds where burrow density may reach up to 60 burrows m⁻². Since the lower limit of the crab burrows is usually the water table, we investigated through field experiments the effect of N. granulata and their burrows on the chemical characteristics of this phreatic water. Water analysis from experimental (1) occupied burrows (with crabs), (2) unoccupied burrows (where crabs were excluded), and (3) sediment pore water show remarkable differences. Water oxygenation, and nitrate, ammonium and sulphate concentrations inside occupied burrows were higher than in the water inside unoccupied burrows or pore waters. Moreover, directed sampling of phreatic water entering and leaving the crab bed, shows that dissolved inorganic nitrogen concentration is enhanced as the water crosses the crab bed. These results may be ascribed to the fact that in the salt marsh the crabs spend most of their time within burrows, where presumably they store food (plants) and defecate. These activities generate an area of accumulation of excrements and nutrients in different decomposition states. The present work shows a novel way by which bioturbating organisms can affect nutrients exportation from salt marshes to the open waters.     

Predicting the optical properties of the West Florida Shelf: resolving the potential impacts of a terrestrial boundary condition on the distribution of colored dissolved and particulate matter

Predicting the distribution of Inherent Optical Properties (IOPs) in the water column requires predicting the physical, chemical, biological, and optical interactions in a common framework that facilitates feedback responses. This work focuses on the development of ecological and optical interaction equations embedded in a 2D hindcast model of the shallow water optical properties on the West Florida Shelf (WFS) during late summer/fall of 1998. This 2D simulation of the WFS includes one case with a Loop Current intrusion above the 40-m isobath and one with the Loop Current intrusion in addition to a periodic terrestrial nutrient supply below the 10-m isobath. The ecological and optical interaction equations are an expansion of a previously developed model for open ocean conditions (Bissett, W.P., Carder, K.L., Walsh, J.J., Dieterle, D.A., 1999a. Carbon cycling in the upper waters of the Sargasso Sea: II. Numerical simulation of apparent and inherent optical properties. Deep-Sea Research, Part I: Oceanographic Research Papers, 46 (2), 271–317; Bissett, W.P., Walsh, J.J., Dieterle, D.A., Carder, K.L., 1999b. Carbon cycling in the upperwaters of the Sargasso Sea: I. Numerical simulation of differential carbon and nitrogen fluxes. Deep-Sea Research, Part I: Oceanographic Research Papers, 46 (2), 205–269). The expansion includes an increase in the number of elemental pools to include silica, phosphorus, and iron, an increase in the number of phytoplankton functional groups, and a redevelopment of the Dissolved Organic Matter (DOM) and Colored Dissolved Organic Matter (CDOM) interaction equations. It was determined from this simulation that while the Loop Current alone was able to predict the water column conditions present during the summer, the Loop Current alone was not enough to simulate the magnitude of optical constituents present in the fall of 1998 when compared to satellite imagery. Simulating terrestrial inorganic and organic nutrients and CDOM pulses coinciding with significant meteorological events and high freshwater pulses released from the major rivers feeding the WFS were required to accurately predict the distribution and scale of the inherent optical properties at the surface during the fall months. Modeling the in situ light field for phytoplankton growth and community competition requires addressing the CDOM optical constituent explicitly. The majority of the annually modeled CDOM on WFS was created via in situ production; however, it was also rapidly removed via advection and photochemical destruction. A pulse of terrestrial nutrient and organic color was required to simulate the dramatic changes in surface color seen in satellite imagery on the WFS. The dynamics of the biogeochemical portion of the simulation demonstrate the importance of nonstoichiometric supplies of terrestrial nutrients on the WFS to the prediction of nutrient and CDOM fluxes.     

Predicting seasonal ocean variability around New Zealand using a coupled ocean-atmosphere model

We present a first assessment of the Sea Surface Temperature (SST) and 300m Heat Content (HC) ensemble mean skill of the Australian Community Climate and Earth-System Simulator-Seasonal v1.0 (ACCESS-S1) around New Zealand on seasonal timescales, using a set of retrospective ensemble forecasts for 1990-2012. This was verified against Reynolds AVHRR analysis and Bluelink ReANalysis 3.5 (BRAN3.5). For inshore areas with depth <300m, the model shows skill forecasting for summer at a lead time of 0 months, with 66% and 65% of model grid cells having correlation coefficients exceeding 0.6 for SST and 300m HC respectively. Regions of lower skill seem to be associated with the model representation of the complex and variable frontal systems around New Zealand, and an overly-strong response to the El Niño Southern-Oscillation (ENSO). Nevertheless, the skill of ACCESS-S1 around New Zealand suggests there is potential for the development of useful seasonal forecast products for the region.     

The Intertidal Burrowing Crab <Emphasis Type="Italic">Neohelice</Emphasis> (=<Emphasis Type="Italic">Chasmagnathus</Emphasis>) <Emphasis Type="Italic">granulata</Emphasis> Positively Affects Foraging of Rodents in South Western Atlantic Salt Marshes

The role of positive and indirect interactions is often crucial in communities with intense abiotic stress such as salt marshes. The burrowing crab, Neohelice (=Chasmagnathus) granulata, is the dominant benthic macroinvertebrate of southwest Atlantic marshes (southern Brazil to Northern Argentinean Patagonia), having strong direct and indirect effects on marsh soil and, in consequence, on marsh vegetation and primary consumers. In this work, we investigate if this crab indirectly modifies habitat use by the granivorous rodents, Akodon azarae and Oligoryzomys flavescens, by increasing nutrient availability and thus enhancing seed production by the marsh plant Spartina densiflora. The study was conducted at the Mar Chiquita Coastal Lagoon, Argentina (37°32′ S). Rodent frequencies in S. densiflora were positively correlated with crab densities throughout the low and middle marsh. Additionally, the highest quality of S. densiflora and inflorescence density was recorded at the highest crab densities. Experimental manipulation of crab densities shows that N. granulata indirectly enhances the performance of S. densiflora (e.g., decreased fiber content and C/N ratios) and increases density of seeds. Moreover, N. granulata also facilitates S. densiflora seed availability to rodents by concentrating them in sediment mound at their burrows entrances. Experimental rodent exclusions showed that rodent species used S. densiflora seeds, a variable positively related to crab burrow density. Thus, our results show that N. granulata drives the granivorous rodent distribution and the intensity of seeds–rodent interaction trough facilitative and indirect interactions in marsh community.     

Oscillatoria rubescens D.C. as an Indicator of Lago Maggiore Eutrophication

Zusammenfassung In der vorliegenden Arbeit wird das Auftreten vonOscillatoria rubescens D.C. im Lago Maggiore behandelt, welche Alge seit langem als biologischer Indikator für Trophiever?nderungen des Süsswassers gilt. Probenahmen an verschiedenen Stellen des Sees und aus bis 50 m Tiefe zeigen, dass die Art seit 10 Jahren betr?chtlich zugenommen hat, wobei im Herbst und Winter jeweils ein Maximum erreicht wird. Die Entwicklung vonOscillatoria rubescens D.C. weist auf eine Eutrophierung des Lago Maggiore durch h?usliche und industrielle Abw?sser hin.

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Résumé Mise en évidence de l'envahissement du Lac Majeur (Lago Maggiore) parOscillatoria rubescens D.C., qui depuis longtemps est considérée comme un indicateur biologique du changement des conditions trophiques des eaux douces. Des collections en différents points du lac et jusqu'à une profondeur de 50 m montrent un accroissement considérable de cette espèce depuis 10 ans, avec un maximum en automne et en hiver. Le développement de cette algue prouve une eutrophisation du Lac Majeur due à des pollutions domestiques et industrielles.

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This publication is contribution No. 395 of the Euratom Biology Division.