The Cenozoic evolution of the Roer Valley Rift System integrated at a European scale

The Roer Valley Rift System (RVRS) is located between the West European rift and the North Sea rift system. During the Cenozoic, the RVRS was characterized by several periods of subsidence and inversion, which are linked to the evolution of the adjacent rift systems. Combination of subsidence analysis and results from the analysis of thickness distributions and fault systems allows the determination of the Cenozoic evolution and quantification of the subsidence. During the Early Paleocene, the RVRS was inverted (Laramide phase). The backstripping method shows that the RVRS was subsequently mainly affected by two periods of subsidence, during the Late Paleocene and the Oligocene–Quaternary time intervals, separated by an inversion phase during the Late Eocene. During the Oligocene and Miocene periods, the thickness of the sediments and the distribution of the active faults reveal a radical rotation of the direction of extension by about 70–80° (counter clockwise). Integration of these results at a European scale indicates that the Late Paleocene subsidence was related to the evolution of the North Sea basins, whereas the Oligocene–Quaternary subsidence is connected to the West European rift evolution. The distribution of the inverted provinces also shows that the Early Paleocene inversion (Laramide phase) has affected the whole European crust, whereas the Late Eocene inversion was restricted to the southern North Sea basins and the Channel area. Finally, comparison of these deformations in the European crust with the evolution of the Alpine chain suggests that the formation of the Alps has controlled the evolution of the European crust since the beginning of the Cenozoic.     

Occurrence of fossil organic matter in modern environments: Optical, geochemical and isotopic evidence

This study relates to the input and fate of fossil organic matter (FOM) in the modern environment, and focuses on two experimental watersheds overlying Jurassic marls: Le Laval and Le Brusquet (1 km² in area), located near Digne, Alpes-de-Haute-Provence, France. Considering that FOM delivery is mainly a result of different processes affecting sedimentary rocks [(bio)chemical and mechanical weathering], samples from different pools were collected: bedrocks, weathering profiles, soils and riverine particles. The samples were examined using complementary techniques: optical (palynofacies methods), geochemical (Rock-Eval 6 pyrolysis, C/N ratio), molecular (gas chromatography/mass spectrometry) and isotopic (stable C isotopic composition). As a result, FOM markers were identified and tracked through the different pools. The results highlight the contribution of FOM, which can be found in all the studied pools. Transfer of FOM between bedrocks/weathering profiles (governed mainly by chemical weathering) and bedrocks/riverine particles (governed mainly by mechanical weathering) reveals any qualitative change. Weathering profiles/soils transition [governed by (bio)chemical weathering] is characterized by alteration of the FOM, which is difficult to describe because fossil material is mixed with recent organic matter (ROM). Despite this latter point, the study provides evidence for a relative resistance of FOM to weathering processes and points to its contribution to the modern geosystem and the C cycle.     

Spatial and Temporal Variability of Sediment Organic Matter Recycling in Two Temperate Eutrophicated Estuaries

This paper deals with the spatial and seasonal recycling of organic matter in sediments of two temperate small estuaries (Elorn and Aulne, France). The spatio-temporal distribution of oxygen, nutrient and metal concentrations as well as the organic carbon and nitrogen contents in surficial sediments were determined and diffusive oxygen fluxes were calculated. In order to assess the source of organic carbon (OC) in the two estuaries, the isotopic composition of carbon (δ ¹³C) was also measured. The temporal variation of organic matter recycling was studied during four seasons in order to understand the driving forces of sediment mineralization and storage in these temperate estuaries. Low spatial variability of vertical profiles of oxygen, nutrient, and metal concentrations and diffusive oxygen fluxes were monitored at the station scale (within meters of the exact location) and cross-section scale. We observed diffusive oxygen fluxes around 15 mmol m^?2 day^?1 in the Elorn estuary and 10 mmol m^?2 day^?1 in the Aulne estuary. The outer (marine) stations of the two estuaries displayed similar diffusive O₂ fluxes. Suboxic and anoxic mineralization was large in the sediments from the two estuaries as shown by the rapid removal of very high bottom water concentrations of NO _x ^? (>200 μM) and the large NH₄ ⁺ increase at depth at all stations. OC contents and C/N ratios were high in upstream sediments (11–15 % d.w. and 4–6, respectively) and decreased downstream to values around 2 % d.w. and C/N ≤ 10. δ ¹³C values show that the organic matter has different origins in the two watersheds as exemplified by lower δ ¹³C values in the Aulne watershed. A high increase of δ ¹³C and C/N values was visible in the two estuaries from upstream to downstream indicating a progressive mixing of terrestrial with marine organic matter. The Elorn estuary is influenced by human activities in its watershed (urban area, animal farming) which suggest the input of labile organic matter, whereas the Aulne estuary displays larger river primary production which can be either mineralized in the water column or transferred to the lower estuary, thus leaving a lower mineralization in Aulne than Elorn estuary. This study highlights that (1) meter scale heterogeneity of benthic biogeochemical properties can be low in small and linear macrotidal estuaries, (2) two estuaries that are geographically close can show different pattern of organic matter origin and recycling related to human activities on watersheds, (3) small estuaries can have an important role in recycling and retention of organic matter.     

Derivation of detrital rutile in the Yaoundé region from the Neoproterozoic Pan-African belt in southern Cameroon (Central Africa)

Rutile, as an important component in alluvial or eluvial heavy mineral deposits, is known in southern Cameroon. These deposits are underlain by the Neoproterozoic low- to high-grade Yaoundé Group. Geochemical, thermometric, fluid inclusion and Pb isotopic studies of the rutile from alluvial and eluvial concentrates and from medium-grade micaschist from the nearby Yaoundé region permit the following conclusions: (1) alluvial and eluvial rutile of the Yaoundé region are derived from the degradation of metapelites, metamafic rocks and pegmatites of the nearby Yaoundé Group; (2) rutile in the Yaoundé Group formed during the Pan-African metamorphism, or was inherited as detrital rutile from a 900 Ma source. The study also shows that the rutile can be used to trace the history of the Pan-African belt north of the Congo craton.     

Low resistivity zones at contacts of igneous intrusions emplaced in organic-rich formations and their implications on fluid flow and petroleum systems: A case study in the northern Neuquén Basin,Argentina

Igneous sills and laccoliths emplaced in sedimentary basins may significantly impact petroleum systems, both positively and negatively. Igneous intrusions provide heat to maturate regionally immature organic-rich host rocks, act as fractured reservoirs hosting commercial accumulations of hydrocarbons, and form structures affecting fluid flow and trapping at different scales. Nevertheless, the petrophysical implications of igneous intrusions on their host rock are poorly known. In this study, we analyse 200 wells in the Río Grande Valley oil field, Neuquén basin, Argentina, where the main reservoirs are in fractured igneous sills. This dataset represents a globally unique possibility to characterize the igneous–host rock interaction using both wireline logs and core material. We identify a systematic Contact Low Resistivity Zone (CLRsZ) at both the upper and lower contacts of the sills emplaced in the organic-rich Vaca Muerta and Agrio Formations. We characterize the nature of these CLRsZ and their petrophysical properties by integrating resistivity and gamma ray well logs, petrographic analyses, petrophysical tests and geochemical analyses. The low resistivity signal of the CLRsZ is dominantly carried by massive-sulphide deposits, mainly pyrite, observed both in the host rock and the chilled margin of the sills. Well log images and porosity-permeability analysis on core plugs show that both the sills and their associated CLRsZ can act as carrier for fluid flow and reservoir for hydrocarbons storage. The thickness of the upper and lower CLRsZ correlates linearly with the thickness of the sill, and the volume of both the upper and lower CLRsZ represents ca. 40% with respect to the volume of their associated sill. The thickness of the CLRsZ represents ca. 13% of the thickness of contact aureole induced by the sills. In the CLRsZ, a great proportion of kerogen was transformed to hydrocarbon, so that CLRsZ were restricted to the innermost contact aureole of the sills. Our results show that the CLRsZ can have major implications on fluid flow and should be considered in reservoir models in volcanic basins hosting sills emplaced in organic-rich formations.     

Comparison of UV and IR Laser Ablation ICP-MS on Silicate Reference Materials and Implementation of Normalisation Factors for Quantitative Measurements

Direct analysis of geological reference materials was performed by LA-ICP-MS using two Nd:YAG laser systems operating at 266 nm and 1064 nm. The aim of this work was to compare UV and IR laser ablation and to assess the potential of the technique for the quantitative bulk analysis of rocks, sediments and soils. The laser sampling process was investigated and the analytical performance of both systems was compared. The influence of the laser operating conditions and the nature of the matrix on ICP-MS response factors calculated for major, minor and trace elements was evaluated. Under consistent laser settings, the response factors appeared to be matrix dependent. For a given matrix, the response factors were also significantly different for the two lasers. Normalisation with a single matrix element was effective only for matrices with similar mineralogy. When operating at 266 nm instead of 1064 nm, matrix effects could be reduced but not overcome. However, variations of the response factors between the different matrices appeared to be similar within distinct groups of elements, reflecting geochemical associations. When using multiple internal standards, matrix effects but also effects of the laser wavelength, could be fully compensated.     

Modelling the global ocean tides: modern insights from FES2004

During the 1990s, a large number of new tidal atlases were developed, primarily to provide accurate tidal corrections for satellite altimetry applications. During this decade, the French tidal group (FTG), led by C. Le Provost, produced a series of finite element solutions (FES) tidal atlases, among which FES2004 is the latest release, computed from the tidal hydrodynamic equations and data assimilation. The aim of this paper is to review the state of the art of tidal modelling and the progress achieved during this past decade. The first sections summarise the general FTG approach to modelling the global tides. In the following sections, we introduce the FES2004 tidal atlas and validate the model against in situ and satellite data. We demonstrate the higher accuracy of the FES2004 release compared to earlier FES tidal atlases, and we recommend its use in tidal applications. The final section focuses on the new dissipation term added to the equations, which aims to account for the conversion of barotropic energy into internal tidal energy. There is a huge improvement in the hydrodynamic tidal solution and energy budget obtained when this term is taken into account.     

Shear strength behaviour of compacted clayey soils percolated with an alkaline solution

In the French model of deep nuclear wastes repositories, the galleries should be backfilled with excavated argillite after the site has been filled. After thousands of years, the degradation of the concrete lining of the galleries will generate an alkaline solute (pH > 12) that would circulate through the backfill. The goal of this paper is to describe the impact of such solute circulation on the properties of compacted argillite. Since additives (bentonite, sand or lime) are often introduced in the remoulded argillite for the backfill, such mixtures were also studied. Saturated-portlandite water was circulated through compacted samples for 3, 6 and 12 months at 60 °C. The shear strength behaviour of the samples was determined with triaxial tests. The microstructure of the samples was analysed via mercury intrusion porosimetry tests and scanning electron microscopy. The results showed that the influence of the alkaline fluid on the properties of the argillite is a function of the nature of the additive. In the case of the calcareous sand, no major changes were observed. The pure argillite underwent a slight decrease in its cohesion due to limited dissolution of its clayey particles. Conversely, intense alteration of the bentonite–argillite mixture was observed, and the shear strength behaviour was modified. Lime addition improved the mechanical characteristics of the argillite.