On the in situ aqueous alteration of soils on Mars

Early (>3 Gy) wetter climate conditions on Mars have been proposed, and it is thus likely that pedogenic processes have occurred there at some point in the past. Soil and rock chemistry of the Martian landing sites were evaluated to test the hypothesis that in situ aqueous alteration and downward movement of solutes have been among the processes that have transformed these portions of the Mars regolith. A geochemical mass balance shows that Martian soils at three landing sites have lost significant quantities of major rock-forming elements and have gained elements that are likely present as soluble ions. The loss of elements is interpreted to have occurred during an earlier stage(s) of weathering that may have been accompanied by the downward transport of weathering products, and the salts are interpreted to be emplaced later in a drier Mars history. Chemical differences exist among the sites, indicating regional differences in soil composition. Shallow soil profile excavations at Gusev crater are consistent with late stage downward migration of salts, implying the presence of small amounts of liquid water even in relatively recent Martian history. While the mechanisms for chemical weathering and salt additions on Mars remain unclear, the soil chemistry appears to record a decline in leaching efficiency. A deep sedimentary exposure at Endurance crater contains complex depth profiles of SO₄, Cl, and Br, trends generally consistent with downward aqueous transport accompanied by drying. While no model for the origin of Martian soils can be fully constrained with the currently available data, a pedogenic origin is consistent with observed Martian geology and geochemistry, and provides a testable hypothesis that can be evaluated with present and future data from the Mars surface.     

Mean wind-direction shear through a forest canopy

The equations of motion applying to the wind field in a forest canopy are simplified to a balance between the shearing stress gradient and either the form-drag of the leaves in the upper dense canopy, or the overall horizontal pressure gradient in the more open space beneath. The equations imply that, in descending through the forest, the stress and wind vectors turn through an angle which depends on the forest characteristics and on the stability and the speed of the airflow above the forest. The turning is roughly confirmed by an overall average measured on a very flat site near Thetford, Norfolk, covered by an extensive uniform pine forest.     

Calculations of the seasonal loadings of North Sea sediments with persistent aromatic organochlorines

The content and distribution of ΣPCB (as the sum of 24 individual components), HCB and p,p′-DDE was determined in sediments taken from the North Sea during two seasons. The mass-balance of aromatic organochlorine compounds in the upper 2 cm of sediments is calculated and dicussed in relation to pollutant dispersal.     

Assessment of hydrodynamic simulation results for eco‐hydraulic and eco‐hydrological applications: a spatial semivariance approach

Output from a three‐dimensional numerical flow model (SSIIM) is used in conjunction with high‐resolution topographic and velocity data to assess such models for eco‐hydraulic applications in river channel design and habitat appraisal. A new methodology for the comparison between field measurement and model output is detailed. This involves a comparison between conventional goodness‐of‐fit approaches applied to a spatially structured (riffle and pool) sample of model and field data, and a ‘relaxation’ method based upon the spatial semivariance of model/field departures. Conventional assessment indicates that the model predicts point‐by‐point velocity characteristics on a 0·45 m mesh to within ±0·1 m s⁻¹ over 80% of the channel area at low flow, and 50% of the area at high in‐bank flow. When a relative criterion of model fit is used, however, the model appears to perform less well: 60–70% of channel area has predicted velocities that depart from observed velocities by more than 10%. Regression analysis of observed and predicted velocities gives more cause for optimism, but all of these conventional indicators of goodness of fit neglect important spatial characteristics of model performance. Spatial semivariance is a means of supplementing model appraisal in this respect. In particular, using the relaxation approach, results are greatly improved: at a high in‐bank flow, the model results match field measurements to within 0·1 m s⁻¹ for more than 95% of the total channel area, provided that model and field comparisons are allowed within a radius of approximately 1 m from the original point of measurement. It is suggested that this revised form of model assessment is of particular relevance to eco‐hydraulic applications, where some degree of spatial and temporal dynamism (or uncertainty) is a characteristic. The approach may also be generalized to other environmental science modelling applications where the spatial attributes of model fits are of interest. Copyright © 2005 John Wiley & Sons, Ltd.     

The SCUBA 8-mJy survey – II. Multiwavelength analysis of bright submillimetre sources

We present the results of a multiwavelength study of the 19 most significant submillimetre (submm) sources detected in the SCUBA 8-mJy survey. As described in Scott et al. , this survey covers ≃260 arcmin² using the submillimetre camera SCUBA, to a limiting source detection limit   S _850 μm≃8 mJy  . One advantage of this relatively bright flux-density limit is that accurate astrometric positions are potentially achievable for every source using existing radio and/or millimetre-wave interferometers. However, an associated advantage is that spectral energy distribution (SED) based redshift constraints should be more powerful than in fainter submm surveys. Here we therefore exploit the parallel SCUBA 450-μm data, in combination with existing radio and Infrared Space Observatory ( ISO ) data at longer and shorter wavelengths to set constraints on the redshift of each source. We also analyse new and existing optical and near-infrared imaging of our SCUBA survey fields to select potential identifications consistent with these constraints. Our derived SED-based redshift constraints, and the lack of statistically significant associations with even moderately bright galaxies allow us to conclude that all 19 sources lie at   z >1  , and at least half of them apparently lie at   z >2  .