Effects of salinity on NH4 + adsorption capacity, nitrification, and denitrification in Danish estuarine sediments

The regulatory effect of salinity on nitrogen dynamics in estuarine sediments was investigated in the Randers Fjord estuary, Denmark, using sediment slurries and intact sediment cores and applying ¹⁵N-isotope techniques. Sediment was sampled at three representative stations varying in salinity, and all experiments were run at 0‰, 10‰, 20‰, and 30‰. The sediment NH₄ ⁺ adsorption capacity decreased markedly at all stations when salinity was increased from 0‰ to 10‰; further increase showed little effect. In situ nitrification and denitrification also decreased with increasing salinities, with the most pronounced reduction of approximately 50% being observed when the salinity was raised from 0‰ to 10‰. The salinity-induced reduction in NH₄ ⁺ adsorption capacity and stimulation of NH₄ ⁺ efflux has previously been argued to cause a reduction in nitrification activity since the nitrifying bacteria become limited by NH₄ ⁺ availability at higher salinities. However, using a potential nitrification assay where NH₄ ⁺ was added in excess, it was demonstrated that potential nitrification activity also decreased with increasing salinity, indicating that the inhibitory salinity effect may also be a physiological effect on the microorganisms. This hypothesis was supported by the finding that denitrification based on NO₃ ⁻ from the overlying water (D_w), which is independent of the nitrification process, and hence NH₄ ⁺ availability, also decreased with increasing salinity. We conclude that changes in salinity have a significant effect on nitrogen dynamics in estuarine sediments, which must be considered when nitrogen transformations are measured and evaluated.     

A focal plane detector design for a wide-band Laue-lens telescope

The energy range above 60 keV is important for the study of many open problems in high energy astrophysics such as the role of Inverse Compton with respect to synchrotron or thermal processes in GRBs, non thermal mechanisms in SNR, the study of the high energy cut-offs in AGN spectra, and the detection of nuclear and annihilation lines. Recently the development of high energy Laue lenses with broad energy bandpasses from 60 to 600keV have been proposed for a Hard X ray focusing Telescope (HAXTEL) in order to study the X-ray continuum of celestial sources. The required focal plane detector should have high detection efficiency over the entire operative range, a spatial resolution of about 1mm, an energy resolution of a few keV at 500keV and a sensitivity to linear polarization. We describe a possible configuration of the focal plane detector based on several CdTe/CZT pixelated layers stacked together to achieve the required detection efficiency at high energy. Each layer can operate both as a separate position sensitive detector and polarimeter or work with other layers to increase the overall photopeak efficiency. Each layer has a hexagonal shape in order to minimize the detector surface required to cover the lens field of view. The pixels would have the same geometry so as to provide the best coupling with the lens point spread function and to increase the symmetry for polarimetric studies.     

Long transequatorial interconnecting loops of the new solar cycle

We study two long transequatorial loops connecting high-latitude regions of the new solar cycle. These loops (with lengths of 47 and 61 heliographic degrees) provide evidence that the upper length limit of 37° found by Chase et al. (1976) from Skylab data was determined simply by the typical distances between northern and southern active regions during the period of Skylab observations. We find strong support for the idea that these long interconnecting loops originate through reconnection of field lines extending from the two active regions towards and beyond the equator, and confirm the earlier finding by Canfield, Pevtsov, and McClymont (1996) that only field lines from active regions with the same chirality reconnect. As we are not aware of any longitudinal (E–W) loops of comparable lengths, we suggest that it is mainly the solar differential rotation which drives the reconnection of latitudinal (N–S) field lines.     

Limnic Responses to Increased Effective Humidity during the 8200 cal. yr BP Cooling Event in Southern Sweden

Highly resolved sediment stratigraphic and stable isotope records from a lake in south-central Sweden give evidence of relatively humid summers during the wide-spread cold event at c. 8200 cal. BP. A transient lake-level rise led to increased catchment erosion followed by enhanced phytoplankton production and disturbance of the Chara-dominated algal community. An associated increase in the deposition of organic material resulted in hypolimnetic oxygen deficit and methane formation as inferred from elevated sulphur content of the sediments and strong depletion in ¹³C of bulk organic material. In combination with dry and cold winter conditions as revealed by other proxy records, these data suggest the development of a strongly seasonal climate in northwestern Europe in response to altered atmospheric circulation at this stage. Enhanced zonal circulation with frequent cyclonic activity and increased effective humidity probably characterized the summer climate of southern and central Scandinavia, consistent with conditions inferred for continental Europe. In contrast, the winter climate was dominated by blocking high-pressure circulation, giving rise to cold and dry conditions.     

First-Order Chemistry in the Surface-Flux Layer

We have discussed the behavior of a non-conserved scalar in the stationary, horizontally homogeneous, neutral surface-flux layer and, on the basis of conventional second-order closure, derived analytic expressions for flux and for mean concentration of a gas, subjected to a first-order removal process. The analytic flux solution showed a clear deviation from the constant flux, characterizing a conserved scalar in the surface-flux layer. It decreases with height and is reduced by an order of magnitude of the surface flux at a height equal to about the typical mean distance a molecule can travel before destruction. The predicted mean concentration profile, however, shows only a small deviation from the logarithmic behavior of a conserved scalar. The solution is consistent with assuming a flux-gradient relationship with a turbulent diffusivity corrected by the Damköhler ratio, the ratio of a characteristic turbulent time scale and the scalar mean lifetime. We show that if we use only first-order closure and neglect the effect of the Damköhler ratio on the turbulent diffusivity we obtain another analytic solution for the profiles of the flux and the mean concentration which, from an experimental point of view, is indistinguishable from the first analytic solution. We have discussed two cases where the model should apply, namely NO which, by night, is irreversibly destroyed by interaction with mainly O₃ and the radioactive ²²⁰Rn. Only in the last case was it possible to find data to shed light on the validity of our predictions. The agreement seemed such that a falsification of our model was impossible. It is shown how the model can be used to predict the surface flux of ²²⁰Rn from measured concentration profiles.     

Recent marginal changes of the Mittivakkat Glacier,Southeast Greenland and the discovery of remains of reindeer (Rangifer tarandus), polar bear (Ursus maritimus) and peaty material

Geografisk Tidsskrift, Danish Journal of Geography 108(1):137–142, 2008

During field observations in August 2005 antler remains of a reindeer were found at a recently deglaciated site at about 500 m asl., and bones from a polar bear were found at about 300 m asl. along the margin of Mittivakkat Glacier, Southeast Greenland. Radio carbon dating determined the age of the samples to 720 ¹⁴C years and 350 ¹⁴C years, respectively. In August 2006 old surface vegetation covering peaty material became exposed due to ice recession close to the site where the antler was found. The radio carbon age of small roots from the material was determined to 1530 ¹⁴C years, and is in agreement with dating of woody remains of Salix glauca found close by, at the top of a nearby nunatak in 1999. The antler indicates that reindeer lived in the area when the glacier began to advance from a position where it was close to or smaller than today. The vegetation surface and peaty material indicate that the climate was warmer before the onset of the Little Ice Age in Southeast Greenland than today.     

Derivation of Structure Parameters of Temperature and Humidity in the Convective Boundary Layer from Large-Eddy Simulations and Implications for the Interpretation of Scintillometer Observations

We derive the turbulent structure parameters of temperature $C_{T}^2$ and humidity $C_q^2$ from high-resolution large-eddy simulations (LES) of a homogeneously-heated convective boundary layer. Boundary conditions and model forcing were derived from measurements at Cabauw in The Netherlands. Three different methods to obtain the structure-parameters from LES are investigated. The shape of the vertical structure-parameter profiles from all three methods compare well with former experimental and LES results. Depending on the method, deviations in the magnitude up to a factor of two are found and traced back to the effects of discretization and numerical dissipation of the advection scheme. Furthermore, we validate the LES data with airborne and large-aperture scintillometer (LAS) measurements at Cabauw. Virtual path measurements are used to study the variability of $C_{T}^2$ in the mixed layer and surface layer and its implications for airborne and LAS measurements. A high variability of $C_{T}^2$ along a given horizontal path in the LES data is associated with plumes (high values) and downdrafts (low values). The path average of $C_{T}^2$ varies rapidly in time due to the limited path length. The LES results suggest that measured path averages require sufficient temporal averaging and an adequate ratio of path length to height above the ground for the LAS in order to approach the domain average of $C_{T}^2$ .     

On characterizing the temporal dominance patterns of model parameters and processes

Diagnostic analyses of hydrological models intend to improve the understanding of how processes and their dynamics are represented in models. Temporal patterns of parameter dominance could be precisely characterized with a temporally resolved parameter sensitivity analysis. In this way, the discharge conditions are characterized, that lead to a parameter dominance in the model. To achieve this, the analysis of temporal dynamics in parameter sensitivity is enhanced by including additional information in a three‐tiered framework on different aggregation levels. Firstly, temporal dynamics of parameter sensitivity provide daily time series of their sensitivities to detect variations in the dominance of model parameters. Secondly, the daily sensitivities are related to the flow duration curve (FDC) to emphasize high sensitivities of model parameters in relation to specific discharge magnitudes. Thirdly, parameter sensitivities are monthly averaged separately for five segments of the FDC to detect typical patterns of parameter dominances for different discharge magnitudes. The three methodical steps are applied on two contrasting catchments (upland and lowland catchment) to demonstrate how the temporal patterns of parameter dynamics represent different hydrological regimes. The discharge dynamic in the lowland catchment is controlled by groundwater parameters for all discharge magnitudes. In contrast, different processes are relevant in the upland catchment, because the dominances of parameters from fast and slow runoff components in the upland catchment are changing over the year for the different discharge magnitudes. The joined interpretation of these three diagnostic steps provides deeper insights of how model parameters represent hydrological dynamics in models for different discharge magnitudes. Thus, this diagnostic framework leads to a better characterization of model parameters and their temporal dynamics and helps to understand the process behaviour in hydrological models. Copyright © 2015 John Wiley & Sons, Ltd.