Emplacement ages and sources of kimberlites and related rocks in southern Africa: U–Pb ages and Sr–Nd isotopes of groundmass perovskite

Groundmass perovskite has been dated by LA-ICPMS in 135 kimberlites and related rocks from 110 localities across southern Africa. Sr and/or Nd isotopes have been analysed by LA-MC-ICPMS in a subset of these and integrated with published data. The age distribution shows peaks at 1,600–1,800, 1,000–1,200, 500–800 and 50–130 Ma. The major “bloom” of Group I kimberlites at ca 90 ± 10 Ma was preceded by a slow build-up in magmatic activity from ca 180 Ma. The main pulse of Group II kimberlites at 120–130 Ma was a distinct episode within this build-up. Comparison of the isotopic data with seismic tomography images suggests that metasomatized subcontinental lithospheric mantle (SCLM) with very low ε _Nd and high ⁸⁷Sr/⁸⁶Sr, (the isotopic signature of Group II kimberlites) was focused in low-Vs zones along translithospheric structures. Such metasomatized zones existed as early as 1,800 Ma, but were only sporadically tapped until the magmatic build-up began at ca 180 Ma, and contributed little to the kimberlitic magmas after ca 110 Ma. We suggest that these metasomatized volumes resided in the deep SCLM and that their low-melting point components were “burned off” by rising temperatures, presumably during an asthenospheric upwelling that led to SCLM thinning and a rise in the ambient geotherm between 120 and 90 Ma. The younger Group I kimberlites therefore rarely interacted with such SCLM, but had improved access to shallower volumes of differently metasomatized, ancient SCLM with low ⁸⁷Sr/⁸⁶Sr and intermediate ε _Nd (0–5). The kimberlite compositions therefore reflect the evolution of the SCLM of southern Africa, with metasomatic-enrichment events from as early as 1.8 Ga, through a major thermal and compositional change at ca 110 Ma, and the major kimberlite “bloom” around 90 Ma.     

Potential of marble dust to stabilise red tropical soils for road construction

The potential of marble dust as a stabilizing additive to red tropical soils was evaluated. The evaluation involved the determination of the geotechnical properties of three different red tropical soils in their natural state as well as when mixed with varying proportions of marble dust. The parameters tested included the particle size distribution, specific gravity, Atterberg limits, the standard compaction characteristics, the compressive strength and the California bearing ratio (CBR). The strength tests were repeated after normal 28 day curing of the treated samples and also after accelerated 24 h curing at temperatures of 40°C, 60°C and 80°C.

Results showed that the geotechnical parameters of red tropical soils are improved substantially by the addition of marble dust; plasticity was reduced by 20 to 33% and strength and CBR increased by 30 to 46% and 27 to 55% respectively. The highest strength and CBR values were achieved at 8% marble dust. Results also showed that normal 28 day curing improved the strength of the marble dust-treated soil with over 80% strength gain achieved after 7 to 10 days of normal curing. Higher strength development was realised following accelerated 24 h curing at 60°C.

Although these results imply marked improvement in the geotechnical parameters of red tropical soils, the higher strength developed is not enough for the improved soil to be used as a base material in the construction of heavily trafficked flexible pavements. The improved material may, however, be successfully used as base material for lightly trafficked roads and as a sub-base material for heavily trafficked roads.     

Geoscientific R&D for high level radioactive waste disposal in Sweden — current status and future plans

SKB (Svensk Kärnbränslehantering AB) is responsible for all handling, transport and storage of the nuclear wastes outside the Swedish nuclear power stations. According to Swedish law, SKB is responsible for an R&D-programme needed to take care of the radwastes. The programme comprises, among others, a general supportive geo-scientific R&D and the Äspö Hard Rock Laboratory (HRL) for more in-situ specific tasks.

Sweden is geologically located in the Fennoscandian shield which is dominated by gneisses and granitoids of Precambrian age. The Swedish reference repository concept thus considers an excavated vault at ca. 500 m depth in crystalline rocks. In this concept (KBS-3), copper canisters with high level waste will be emplaced in deposition holes from a system of tunnels. Blocks of highly compacted swelling bentonite clay are placed in the holes leaving ample space for the canisters. At the final closure of the repository, the galleries are backfilled with a mixture of sand and bentonite. This repository design aims to make the disposal system as redundant as possible. Although the KBS-3 concept is the reference concept, alternative concepts and/or repository lay-outs are also studied. The main alternative, currently under development at SKB, is disposal in boreholes with depths of 4–5 km. The geoscientific research will to a great extent be guided by the demands posed by the performance and safety assessments, as well as the constuctability issues. Some main functions of the geological barrier are fundamental for the long-term safety of a repository. These are: bedrock mechanical stability, a chemically stable environment as well as a slow and stable groundwater flux. The main time-table for the final disposal of long-lived radioactive waste in Sweden foresees the final selection of the disposal system and site during the beginning of next decade.     

Comparative petrology and metamorphic evolution of the Limpopo (South Africa) and Lapland (Fennoscandia) high-grade terrains

Summary ?Detailed studies of rocks from the Limpopo (South Africa) and Lapland (Kola-Fennoscandia) high-grade terrains were carried out in order to reveal similar geological and thermodynamic conditions in their formation. Both complexes (1) are situated between Archean greenstone belts, (2) are younger than the belts, (3) are bounded by crustal-scale shear zones, (4) have a similar intrusive-like (harpolith) geometry, and (5) show similar reaction textures that reflect both breakdown and growth of garnet in each high-grade terrain. Local mineral equilibria within the textures indicate their successive formation with cooling of the granulite facies rocks. Some of the textures in the metapelites must have resulted from the following reverse reactions: Grt + Qtz ⇌Opx + Crd and/or Grt + Sil + Qtz ⇌ Crd. Based on these data, both the decompression cooling P-T path and the near-isobaric cooling P-T path were deduced for each HGT. However the near-isobaric cooling P-T path is not a characteristic of the central zones of both complexes studied. Similar structural framework of the high-grade terrains, similar morphologies (shapes of granulitic bodies), similar reaction textures developed in metapelites, and similar shapes of P-T paths suggest similarity in geodynamic history of both complexes.

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Zusammenfassung ?Vergleichende Petrologie und metamorphe Entwicklung der hochgradig metamorphen Terrains von Limpopo (Südafrika) und Lappland (Fennoscandia) Eingehende Untersuchungen an Gesteinen aus den hochgradig metamorphen Terrains von Limpopo (Südafrika) und Lappland (Kola-Fennoscania) sollen m?gliche ?hnlichkeiten in den geologischen und thermodynamischen Bildungsbedingungen aufzeigen. Beide Komplexe sind Lokale Mineralgleichgewichte innerhalb der Texturen weisen auf ihre schrittweise Bildung w?hrend der Abkühlung der granulitfaziellen Gesteine hin. Einige der Texturen in den Metapeliten gehen auf folgende reversible Reaktionen zurück: Grt + Qtz ⇌Opx + Crd und/oder Grt + Sil + Qtz ⇌ Crd. Diese Daten erm?glichten es, sowohl den P-T Pfad der Abkühlung bei Druckentlastung sowie den fast-isobaren P-T Pfad der Abkühlung für jedes HGT zu ermitteln. Der fast-isobare P-T Pfad der Abkühlung ist jedoch kein Charakteristikum der Zentralzonen beider Komplexe. Ein ?hnlicher struktureller Rahmen der hochgradigen Terrains, ?hnliche Morphologien (Ausbildung der Granulitk?rper), ?hnliche Reaktionstexturen in Metapeliten und ?hnliche P-T Pfade weisen auf ?hnlichkeiten der geodynamischen Entwicklungsgeschichte beider Komplexe hin.

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Received March 8, 1999; revised version accepted September 17, 1999     

Geochemistry and lithology of accretionary wedge in the Pekul’nei range, central Chukotka

Based on the study of various facies of ancient and modern oceanic sediments, the Ce/La versus Zr/Y criterion is proposed to discriminate the principal genetic groups of sedimentary rocks in foldbelts and to determine their geodynamic formation conditions. The structure and composition of siliceous, clayey and fineclastic tuffaceous rocks from various complexes of paleoaccretionary wedge in the Pekul’nei Range (Chukotka) are discussed. Lithological and geochemical studies of sedimentary rocks in the Pekul’nei Range allowed us to trace the regular variations in rock sections depending on (1) propagation of oceanic plate from the spreading center toward the convergent boundary for paleooceanic rock complexes and (2) sedimentation regime and provenances for rocks deposited above the convergent plate boundary.     

Evolution of the distribution function and radiation spectrum for electrons in a magnetic field

The evolution of a system of electrons with a given initial distribution in an external magnetic field is considered. An equation describing the evolution of the electron distribution function in a uniform magnetic field is derived for the case of arbitrarily relativistic electrons, and an exact solution to this equation is found. Asymptotics of this solution corresponding to the cases of synchrotron radiation and relativistic dipole radiation are calculated, and the evolution of the radiation spectra for these limiting cases is analyzed. The curvature of the magnetic field lines is taken into account phenomenologically, which demonstrates the presence of an exponential dependence in the case of synchrotron radiation.     

Authigenic carbonates in methane seeps from the Norwegian sea: Mineralogy, geochemistry, and genesis

Authigenic carbonates in the caldera of an Arctic (72°N) submarine mud volcano with active CH₄bearing fluid discharge are formed at the bottom surface during anaerobic microbial methane oxidation. The microbial community consists of specific methane-producing bacteria, which act as methanetrophic ones in conditions of excess methane, and sulfate reducers developing on hydrogen, which is an intermediate product of microbial CH₄ oxidation. Isotopically light carbon (δ¹³C_av =−28.9%0) of carbon dioxide produced during CH₄ oxidation is the main carbonate carbon source. Heavy oxygen isotope ratio (δ¹⁸O_av = 5%0) in carbonates is inherited from seawater sulfate. A rapid sulfate reduction (up to 12 mg S dm⁻³ day⁻¹) results in total exhausting of sulfate ion in the upper sediment layer (10 cm). Because of this, carbonates can only be formed in surface sediments near the water-bottom interface. Authigenic carbonates occurring within sediments occur do notin situ. Salinity, as well as CO ₃ ²⁻ /Ca and Mg/Ca ratios, correspond to the field of nonmagnesian calcium carbonate precipitation. Calcite is the dominant carbonate mineral in the methane seep caldera, where it occurs in the paragenetic association with barite. The radiocarbon age of carbonates is about 10000 yr.