Sequence of geologic events in the central and northeastern parts of the Lapland Granulite Belt: Isotopic geochemical zircon data and results of geological-petrological studies

Geological and petrological studies of rocks were conducted to reproduce the succession of endogenic processes in the central and northeastern parts of the Lapland Granulite Belt along the course of the Lotta River. Mineralogical-geochemical data on zircon from these rocks (the anatomy of zircon crystals seen in BSE and CL imagery; U, Th, Hf, and Y concentrations; and REE patterns) and their crystallization temperatures (calculated using the Ti concentration) make it possible to correlate the newly obtained geochronologic data with the sequence of metamorphic events inferred from petrological data. Three major episodes of enderbite-forming processes are distinguished: (i) early episode at 1.99 Ga, (ii) main episode at 1.940–1.925 Ga; and (iii) late episode at 1.89 Ga. The early medium-pressure metamorphic episode is dated at 1.97–1.96 Ga. The diatexis of the quartz-feldspar granulites with the derivation of garnet plagioclase leucogranites took place at 1.917–1.909 Ga.     

Evaluation of trace element availability from secondary metallurgical slag generated in steelmaking by sequential chemical extraction

During carbon steel manufacture, slag residues are generated to remove material impurities from liquid metal and thus control the quality of carbon steel. As the utilization of secondary metallurgical slags is not as efficient as those of primary slags, a comprehensive characterization of steel ladle slag was performed. Pseudo-total concentrations of a wide range of elements were determined during a 6-week sampling period with relevant physical and chemical properties, sequential extraction of trace elements, and parallel mineralogical characterization of extraction residues from a representative combined sample. According to the results, only Cr and V occurred in elevated concentrations with respective 6-week mean values of 198 and 310 mg kg^?1 (d.w.). The residual standard deviation of the weekly pseudo-total concentration values of the aforementioned elements (24 and 31 %, respectively) indicated that significant variation in the concentration of trace elements can occur due to fluctuation in process conditions and/or slag characteristics. The sequential extraction procedure suggested potential phytoavailability of V (123 mg kg^?1, d.w., amounting to 41 % of the respective pseudo-total concentration) through, e.g., changes in prevailing redox conditions. Although the analytical approach was validated by the analysis of a certified reference material and the calculation of extraction recoveries, the mineralogical characterization of parallel extraction residues indicated non-selectivity of the procedure coupled with potential redistribution phenomena during extraction with hydrogen peroxide and ammonium acetate.     

A Kinematic Model of the Formation of the Sim Trough of the Uralian Foredeep

The structural features and mechanism of the formation of the Sim trough within the Uralian Foredeep, as well as the development of the entire Karatau–Suleiman block, are considered. This wedge-shaped block was subject to lateral extrusion to the north along conjugated strike-slip fault zones under a general latitudinal compression. This factor determined the local meridional compression and latitudinal extension of the block. In the central part of the block, the latitudinal extension was compensated by gradual subsidence, which resulted in the formation of the Sim trough.     

Fabric evolution at basement–cover interfaces in a fold-and-thrust belt and implications for décollement tectonics (Autochthon, Lower Allochthon, central Scandinavian Caledonides)

Microstructural and magnetic investigations (anisotropy of magnetic susceptibility, AMS) on sections across basement–cover interfaces (BCI) revealed a complex evolution in the crystalline basement rocks beneath and in the basal units of the Caledonian fold-and-thrust belt: (1) Pre-Caledonian mylonitic fabrics in basement granite relate to steep shear zones. (2) Palaeoweathering formed smectite and illite at the expense of feldspar and mica. Secondary Fe-bearing clay minerals and the intensity of the chemical weathering control the bulk susceptibility. Changing susceptibility and AMS relate to a (time) sequence from primary magnetite to secondary paramagnetic clay to pyrite and ferrimagnetic pyrrhotite. (3) Burial compaction with BCI-parallel fabrics. (4) Caledonian cleavage, overprinted by décollement zones with S–C–C′ fabrics. Décollement cataclasis overprinted pre-existing magnetic fabrics and produced horizontal magnetic lineations and subhorizontal foliations defined by the S–C–C′ fabrics. Clay mineral enrichment, together with subsequent, BCI-parallel compaction fabrics, decreased the shear strength in the basement rocks beneath the BCI. Detachments initiated at such low-strength zones and produced allochthonous units with their footwall within crystalline basement rocks, an observation of general importance for orogenic fold-and-thrust belts.     

Application of petrographic and geochemical methods to sourcing felsitic archaeological materials in Southeastern New England

At least four volcanic complexes of different age and petrologic character occur in southeastern New England. Each complex contains a variety of fine-grained felsitic rocks, and three of these are known to have been quarried by prehistoric people for material used in the production of stone tools. These volcanics include a Late Proterozoic calcalkaline suite (Lynn-Mattapan) and several alkaline suites of Ordovician to Carboniferous age (Blue Hill, Spencer Hill, and Wamsutta suites). Each suite exhibits unique petrographic and geochemical features that help to constrain sources of felsitic archaeological materials. Distinctive petrographic features are: (1) Lynn/Mattapan: mostly pyroclastic rocks that typically contain broken crystals, volcanic clasts, and relict pumice and glass shards; phenocrysts of plagioclase, quartz, and perthite, commonly in glomeroporphyritic clusters; accessory sphene and prominent late-stage epidote; some varieties exhibit distinct flow-banding. (2) Blue Hill and Spencer Hill rocks: mainly lava flows; abundant perthite and quartz phenocrysts, with minor or no plagioclase; accessory minerals may include fluorite, aegerine, riebeckite, zircon, and allanite. (3) Wamsutta rhyolite: phenocrysts solely of anorthoclase; quartz restricted to late-stage filling of vesicles, and to planar, subparallel fractures in-filled as lithophysae; lava flows with devitrified glass matrix. Major element geochemistry is of limited use in distinguishing the volcanic groups, but trace element signatures are distinct and provide excellent criteria to discriminate rocks from each suite. Compared to the Lynn/Mattapan suite, the Blue Hill and Spencer Hill rocks exhibit higher concentrations of Rb, Y, Zr, Nb, La, Ce and Zn, and lower concentrations of Sr and Ba. Wamsutta rhyolite is intermediate in composition, but distinct. Examination of material from six prehistoric quarries, and debitage collected at seven archaeological sites, demonstrates that most samples can be assigned to one of the above volcanic suites based on combined petrographic and geochemical attributes. These geologic attributes add a significant element of quantification to archaeological sourcing problems that lead to improved identification of materials compared to hand sample characterization alone. The volcanics from source areas proximal to the Boston basin were important to Early and Middle Archaic period populations across most of southeastern Massachusetts. During the Late/Terminal Archaic period, these materials were being transported extensively throughout eastern and southeastern Massachusetts, the Narragansett Bay area, and parts of Rhode Island. Thus, routinely applied geological methods can provide useful approaches to constrain the sources of felsites from southeastern New England found in archaeological contexts. © 1997 John Wiley & Sons, Inc.     

Cyclic sedimentation and climatically caused sea-level changes in the Late Palaeozoic of Central Europe

Significant short-term fluctuations are characteristic of geological history since Precambrian times. Only the younger Quaternary climatic fluctuations are known in more detail as a result of a high grade time resolution. Climatic change can also be postulated with respect to older, cold periods during which polar inland ice sheets developed. From a discussion of endogene and exogene interpretations it is shown that global climatic changes, and the sea-level changes induced by them, as well as changes in the position and extent of climatic zones throughout the world provide a control mechanism for sedimentation which is consistent with cyclic sedimentation in Late Palaeozoic times, and also if the basin subsides non-cyclically. The model allows an explanation of the development of the Permo-Carboniferous sedimentary cycles without numerous short-term vertical oscillations of the earth's crust. In reality, exogene and endogene controls on sedimentation act together in great variety of combinations.     

Phenanthrene biomarkers in the organic matter of Precambrian and Phanerozoic deposits and in the oils of the Siberian Platform

The composition and distribution of phenanthrenes (polyaromatic compounds) have been studied in chloroform extracts from dispersed organic matter (OM) of clayey, siliceous, carbonate, and terrigenous rocks of different ages and facies and from some oils of the Siberian Platform. Phenanthrenes have been analyzed by gas chromatography-mass spectrometry. High contents of 1,7,8-trimethylphenanthrene and 1,1,7,8-tetramethyl-1,2,3,4-tetrahydrophenanthrene are present in the OM of Vendian and Cambrian carbonate-shale deposits and in ancient oils of the Nepa-Botuobiya and Anabar anteclises. The OM of Permian continental deposits and oils of the Vilyui syneclise is dominated by 1-methyl-7-isopropylphenanthrene (retene). A triangular diagram for identification of the types of original OM of rocks and classification of genetically related oils has been constructed based on the assessment of phenanthrene biomarker distribution. Putative pathways of the formation of phenanthrene biomarkers are discussed.     

Tectono-geomorphic development of intra-continental Cenozoic depressions within Cretaceous rocks of the Interior Homocline,Central Arabia

Intra-continental depressions occurred in Central Arabia, within the evaporite-bearing Sulaiy Formation, and extends for over 550 km along N-S arcuate belt, passing through eastern Ar Riyadh, Saudi Arabia. They mark Jurassic/Cretaceous contact within the Interior Homocline of Central Arabia, accommodating Neogene and Quaternary deposits. Two en echelon major depressional areas were discovered, the northern major depressional area and the southern major depressional area. The first depressional area occurs between Al Artawiyah and Ad Dilam towns, following the arcuate Jurassic/Cretaceous contact. It contains five depressions: N-S Al Artwaiyah depression; NW-SE Ath Thumamah depression, northeast of Riyadh; NW-SE Jinadriyah depression, east of Riyadh; E-W Al Kharj depression; and N-S Ad Dilam depression. All five depressions seems to be formed by tectonic and subsequent geomorphic events, except for Al Artawiyah and Jinadriyah depression, which developed mainly by tectonic events. Southern major depressional area steps over to southwest of Ad Dilam, and occurs from Hawtat bani tamim to Layla towns. This Hawtah-Layla major depression trends N-S, and Cretaceous units strike NNE, which is a slightly oblique relationship, suggesting expression of deep-seated structures. Tectonic features were part of the Alpine-Himalayan orogeny, developing during Eocene. They followed by a geomorphic event (karsts and subsequent collapse) that took place during Mid Pleistocene. Ad Dilam depression is a surface expression of three oil and gas fields, while the southern major depression between Hawtat Bani Tamim and Layla towns is a surface expression of four oil and gas fields. Yet, other several depressional areas are also accommodating Quaternary desert sediments, and they contain economic resources, which therefore, worth further detailed studies.