Spatial dynamics of overbank sedimentation in floodplain systems

Floodplains provide valuable social and ecological functions, and understanding the rates and patterns of overbank sedimentation is critical for river basin management and rehabilitation. Channelization of alluvial systems throughout the world has altered hydrological and sedimentation processes within floodplain ecosystems. In the loess belt region of the Lower Mississippi Alluvial Valley of the United States, channelization, the geology of the region, and past land-use practices have resulted in the formation of dozens of valley plugs in stream channels and the formation of shoals at the confluence of stream systems. Valley plugs completely block stream channels with sediment and debris and can result in greater deposition rates on floodplain surfaces. Presently, however, information is lacking on the rates and variability of overbank sedimentation associated with valley plugs and shoals.We quantified deposition rates and textures in floodplains along channelized streams that contained valley plugs and shoals, in addition to floodplains occurring along an unchannelized stream, to improve our understanding of overbank sedimentation associated with channelized streams. Feldspar clay marker horizons and marker poles were used to measure floodplain deposition from 2002 to 2005 and data were analyzed with geospatial statistics to determine the spatial dynamics of sedimentation within the floodplains.Mean sediment deposition rates ranged from 0.09 to 0.67 cm/y at unchannelized sites, 0.16 to 2.27 cm/y at shoal sites, and 3.44 to 6.20 cm/y at valley plug sites. Valley plug sites had greater rates of deposition, and the deposited sediments contained more coarse sand material than either shoal or unchannelized sites. A total of 59 of 183 valley plug study plots had mean deposition rates > 5 cm/y. The geospatial analyses showed that the spatial dynamics of sedimentation can be influenced by the formation of valley plugs and shoals on channelized streams; however, responses can vary. Restoration efforts in the region need to have basinwide collaboration with landowners and address catchment-scale processes, including the geomorphic instability of the region, to be successful.     

Trace elements and polycyclic aromatic hydrocarbons (PAHs) concentrations in deep Gulf of Mexico sediments

The concentrations of polycyclic aromatic hydrocarbons (PAHs) and trace elements were determined for surface (top 2 cm) sediment samples collected during the deep Gulf of Mexico benthos (DGoMB) study .These elements and compounds are known to be toxic to organisms at high concentrations and may affect biological communities. There is no indication of major anthropogenic input of the elements Be, Co, Cr, Fe, Si, Tl, V, K, Mg, Ca, Sr and Zn, based on normalization to Al. The concentrations of these metals in the sediment are a function of the relative amounts of trace-metal-rich Mississippi River-derived silicate material and trace-metal-poor plankton-derived carbonate. This is not true for the elements Ba, Ni, Pb, Cd, As, Cu and Mn, whose concentrations show considerable scatter when normalized to Al and a general enrichment. On a normalized basis, Mn is enriched 5–10 fold, Cu and Ni 2–3 fold and Pb 2 fold over Mississippi River-derived material. These enrichments are likely the result of remobilization of metals from depths in the sediment column where reducing conditions exist. The Ba concentrations at selected sites are higher than those of average clay-rich sediments, but are typical of sediments from near oil well platforms in the northern Gulf of Mexico. In the case of Ba, it seems likely that the enrichments, as high as a factor of 10, are due to disposal of oil well drilling mud. The Ba-enriched samples are from the three shallowest water sites in the Mississippi Trough (sites MT1, 2 and 3) and from site C1 and WC5. All are in an area of intense petroleum exploration and development. PAH concentrations are also elevated at MT1, MT3 and C1. The total PAH concentration ranged from not detected (ND) to 1033 ng/g with a mean of 140 ng/g. Even at the sites most enriched in PAHs and trace elements, the concentrations are not at the levels expected to adversely affect the biota. However, these predicted non-effects are based on research using mostly near-shore estuarine species, not on the indigenous species at the sampling sites.     

Ozone production due to emissions from vegetation burning

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.     

The oxidation states of cobalt and selected metals in Pacific ferromanganese nodules

A study of the oxidation states of metals in selected Pacific ferromanganese nodules by x-ray photoelectron spectroscopy (XPS) indicates the presence of Co(III), Pb(II), Pb(IV), Fe(III) and Ti(IV). These findings are based on measurements of core electron binding energies and an evaluation of the core electron shake-up satellite features.     

Th sorption and export models in the water column: A review

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.     

Interannual variability and predictability of sea level along the Indian Coast

Summary The Indian coast stretching more than 7,500 km constitutes the major portion of the South Asian coastline in the North Indian Ocean region. The South Asian region is significantly influenced by meteorological/oceanographic phenomena like monsoons, El Ni?o/Southern Oscillation (ENSO) and tropical cyclones. Direct/indirect impacts of these phenomena, which exhibit large interannual variabilities, on sea level changes in this region are considerable. Our results show that the mean sea level along the eastern coast of India, which is highly vulnerable to the incidence of severe tropical cyclones, is considerably higher than normal during the intense cyclonic period of a year falling in the positive phase of the Southern Oscillation (La Ni?a epoch), thereby enhancing the hazardous potential of tropical cyclones. Further, in the closing phase of the La Ni?a southwest monsoon, higher sea level anomalies prevail along the Indian coast raising the flooding potential of such monsoons. Over the west coast of India significant simultaneous correlations have been found between the amount of southwest monsoon rainfall and the mean sea level during the period from June to September. Over the east coast of India at Visakhapatnam, mean sea level is predictable with a fair degree of confidence one month in advance, by using the Sea Surface Temperature (SST) and the Southern Oscillation Index (SOI) as predictors. These results will be useful in the annual preparedness programmes aimed at mitigating the impacts of natural disasters like tropical cyclones and floods in the South Asian region. Received November 9, 2001     

Record of Late Pleistocene Glaciation and Deglaciation in the Southern Cascade Range. I. Petrological Evidence from Lacustrine Sediment in Upper Klamath Lake, Southern Oregon

Petrological and textural properties of lacustrine sediments from Upper Klamath Lake, Oregon, reflect changing input volumes of glacial flour and thus reveal a detailed glacial history for the southern Cascade Range between about 37 and 15 ka. Magnetic properties vary as a result of mixing different amounts of the highly magnetic, glacially generated detritus with less magnetic, more weathered detritus derived from unglaciated parts of the large catchment. Evidence that the magnetic properties record glacial flour input is based mainly on the strong correlation between bulk sediment particle size and parameters that measure the magnetite content and magnetic mineral freshness. High magnetization corresponds to relatively fine particle size and lower magnetization to coarser particle size. This relation is not found in the Buck Lake core in a nearby, unglaciated catchment. Angular silt-sized volcanic rock fragments containing unaltered magnetite dominate the magnetic fraction in the late Pleistocene sediments but are absent in younger, low magnetization sediments. The finer grained, highly magnetic sediments contain high proportions of planktic diatoms indicative of cold, oligotrophic limnic conditions. Sediment with lower magnetite content contains populations of diatoms indicative of warmer, eutrophic limnic conditions. During the latter part of oxygen isotope stage 3 (about 37–25 ka), the magnetic properties record millennial-scale variations in glacial-flour content. The input of glacial flour was uniformly high during the Last Glacial Maximum, between about 21 and 16 ka. At about 16 ka, magnetite input, both absolute and relative to hematite, decreased abruptly, reflecting a rapid decline in glacially derived detritus. The decrease in magnetite transport into the lake preceded declines in pollen from both grass and sagebrush. A more gradual decrease in heavy mineral content over this interval records sediment starvation with the growth of marshes at the margins of the lake and dilution of detrital material by biogenic silica and other organic matter.     

Sedimentology and palynology of the Calafate Formation (Maastrichtian), Austral Basin, Southern Patagonia, Argentina

The Calafate Formation crops out in south-western Santa Cruz Province, Argentina, and displays a stacking of asymmetrical coarsening–fining-upward cycles. These cycles are interpreted as the product of short-lived transgressive-regressive events in which the coarsening upward part represents sedimentary aggradation with a stable or decreasing sea level. Sedimentological and palynological analyses indicate nearshore marine conditions. Even though the existence of an estuary or incised valley cannot be determined, this is the most probable palaeogeographic model. Based on dinoflagellate cysts, the base of the section is considered to be not older than Maastrichtian. The presence of the oyster Ambigostrea clarae (Ihering) occurring together with the dinoflagellate cyst species Manumiella druggii (Stover) Bujak and Davies and Eisenackia circumtabulata Drugg in the middle part of the section indicates an age no older than late Maastrichtian. According to sedimentological data, deposits representing the Cretaceous–Palaeogene transition would have been eroded, which is confirmed by the presence of Grapnelispora loncochensis Papú. This megaspore is a consistent component of the Maastrichtian assemblages from Patagonia.     

Estuarine modification of nutrient and sediment exports to the Great Barrier Reef Marine Park from the Daintree and Annan River catchments

Nutrient and suspended sediment concentrations were measured in the dry season and during the rising and falling stages of flood events in the Annan and Daintree rivers to estimate catchment exports. These flood events were also sampled along the salinity gradient in the estuary and nearshore shelf to quantify the modification of terrestrial sediment and nutrient loads as they pass through estuaries into the Great Barrier Reef lagoon. In the Daintree River TSS concentrations were found to increase between the catchment and the estuary plume. The source of TSS may have been scour of the estuarine channel or from land use in the catchment of the lower estuary. In the dry season nitrogen enters the Annan and Daintree estuaries predominantly in the form of PON and DON in roughly equal proportions. Nitrogen exports to the GBR are mostly in the form of DON. In the wet season the majority of nitrogen enters the estuaries as DON and leaves as PON. Nitrogen removal in the estuaries and plumes appears to be biologically mediated once suspended sediment concentrations decrease to a point where phytoplankton growth is not light limited. In the dry season phosphorus enters and leaves the estuaries primarily in organic form. PIP is the dominant form of phosphorus in river water, but leaves the estuary more evenly distributed between all forms. These estuarine processes result in less nitrogen and phosphorus being delivered to the GBR lagoon than is exported from the catchment. The differences between these estuaries highlights the need for further work to explore modifications in estuaries that drain into the Great Barrier Reef lagoon.