Persistent organic pollutants and histological lesions in Mayan catfish Ariopsis assimilis from the Bay of Chetumal, Mexico

Livers of catfish (Ariopsis assimilis) from the Bay of Chetumal were analyzed for organochlorine compounds and hydrocarbons as part of a study to diagnose the environmental health of the Bay after a catfish mass mortality that occurred in 1996. The presence of histological lesions in several organs of the fish as result of chemical exposure was also evaluated. The concentrations of organic pollutants found in the Bay may be considered high if compared to the levels reported for sites affected by chemical pollution. High prevalences of cellular alteration histopathologies were found in liver, including hepatic tumors. The presence of some lesions may be related statistically to environmental pollution in the Bay, specially with chlorinated compounds.     

Distinct groundwater recharge sources and geochemical evolution of two adjacent sub-basins in the lower Shule River Basin,northwest China

Based on analysis of groundwater hydrogeochemical and isotopic data, this study aims to identify the recharge sources and understand geochemical evolution of groundwater along the downstream section of the Shule River, northwest China, including two sub-basins. Groundwater samples from the Tashi sub-basin show markedly depleted stable isotopes compared to those in the Guazhou sub-basin. This difference suggests that groundwater in the Tashi sub-basin mainly originates from meltwater in the Qilian Mountains, while the groundwater in the Guazhou sub-basin may be recharged by seepage of the Shule River water. During the groundwater flow process in the Tashi sub-basin, minerals within the aquifer material (e.g., halite, calcite, dolomite, gypsum) dissolve in groundwater. Mineral dissolution leads to strongly linear relationships between Na⁺ and Cl^? and between Mg²⁺+ Ca²⁺ and SO₄ ^2??+?HCO₃ ^?, with stoichiometry ratios of approximately 1:1 in both cases. The ion-exchange reaction plays a dominant role in hydrogeochemical evolution of groundwater in the Guazhou sub-basin and causes a good linear relationship between (Mg²⁺+ Ca²⁺)–(SO₄ ^2??+?HCO₃ ^?) and (Na⁺+ K⁺)–Cl^? with a slope of ?0.89 and also results in positive chloroalkaline indices CAI 1 and CAI 2. The scientific results have implications for groundwater management in the downstream section of Shule River. As an important irrigation district in Hexi Corridor, groundwater in the Guazhou sub-basin should be used sustainably and rationally because its recharge source is not as abundant as expected. It is recommended that the surface water should be used efficiently and routinely, while groundwater exploitation should be limited as much as possible.     

Preliminary study on assessment of nutrient transport in the Taihu Basin based on SWAT modeling

With the Taihu Basin as a study area, using the spatially distributed and mechanism-based SWAT model, preliminary simulations of nutrient transport in the Taihu Basin during the period of 1995:_2002 has been carried out. The topography, soil, meteorology and land use with industrial point pollution discharge, the loss of agricultural fertilizers, urban sewerage, and livestock drainages were all considered in the boundary conditions of the simulations. The model was calibrated and validated against water quality monitoring data from 2001 to 2002. The results show that the annual total productions of nitrogen (TN) and phosphorus (TP) into Lake Taihu are 40000t and 2000t respectively. Nutrient from the Huxi Region is a major resource for Lake Taihu. The non-point source (surface source) pollution is the main form of catchment sources of nutrients into Lake Taihu, occupied TN 53% and TP 56% respectively. TN and TP nutrients from industrial point pollution discharge are 30% and 16%, and sewerage in both forms of point source and non-point source are TN 31% and TP 47%. Both the loss of agricultural fertilizers and livestock drainages from the catchment should be paid more attention as an important nutrient source. The results also show that SWAT is an effective model for the simulation of temporally and spatially nutrient changes and for the assessment of the trends in a catchment scale.     

An Improved Approach for Parameterizing Surface-Layer Turbulent Transfer Coefficients in Numerical Models

Based on classic iterative computation results, new equations to calculate the surface turbulent transfer coefficients are proposed, which allow for large ratios of the momentum and heat roughness lengths. Compared to the Launiainen scheme, our proposed scheme generates results closer to classical iterative computations. Under unstable stratification, the relative error in the Launiainen scheme increases linearly with increasing instability, even exceeding 15%, while the relative error of the present scheme is always less than 8.5%. Under stable stratification, the Launiainen scheme uses two equations, one for 0 < Ri _B ≤ 0.08 and another for 0.08 < Ri _B ≤ 0.2, and does not consider the condition that Ri _B > 0.2, while its relative errors in the region 0 < Ri _B ≤ 0.2 exceed 31 and 24% for momentum and heat transfer coefficients, respectively. In contrast, the present scheme uses only one equation for 0 < Ri _B ≤ 0.2 and another equation for Ri _B > 0.2, and the relative error of the present scheme is always less than 14%.     

Impacts of the leading modes of tropical Indian Ocean sea surface temperature anomaly on sub-seasonal evolution of the circulation and rainfall over East Asia during boreal spring and summer

The two leading modes of the interannual variability of the tropical Indian Ocean (TIO) sea surface temperature (SST) anomaly are the Indian Ocean basin mode (IOBM) and the Indian Ocean dipole mode (IODM) from March to August. In this paper, the relationship between the TIO SST anomaly and the sub-seasonal evolution of the circulation and rainfall over East Asia during boreal spring and summer is investigated by using correlation analysis and composite analysis based on multi-source observation data from 1979 to 2013, together with numerical simulations from an atmospheric general circulation model. The results indicate that the impacts of the IOBM on the circulation and rainfall over East Asia vary remarkably from spring to summer. The anomalous anticyclone over the tropical Northwest Pacific induced by the warm IOBM is closely linked with the Pacific–Japan or East Asia–Pacific teleconnection pattern, which persists from March to August. In the upper troposphere over East Asia, the warm phase of the IOBM generates a significant anticyclonic response from March to May. In June and July, however, the circulation response is characterized by enhanced subtropical westerly flow. A distinct anomalous cyclone is found in August. Overall, the IOBM can exert significant influence on the western North Pacific subtropical high, the South Asian high, and the East Asian jet, which collectively modulate the precipitation anomaly over East Asia. In contrast, the effects of the IODM on the climate anomaly over East Asia are relatively weak in boreal spring and summer. Therefore, studying the impacts of the TIO SST anomaly on the climate anomaly in East Asia should take full account of the different sub-seasonal response during boreal spring and summer.     

Assessment of PPP integer ambiguity resolution using GPS,GLONASS and BeiDou (IGSO,MEO) constellations

Although integer ambiguity resolution (IAR) can improve positioning accuracy considerably and shorten the convergence time of precise point positioning (PPP), it requires an initialization time of over 30 min. With the full operation of GLONASS globally and BDS in the Asia–Pacific region, it is necessary to assess the PPP–IAR performance by simultaneous fixing of GPS, GLONASS, and BDS ambiguities. This study proposed a GPS + GLONASS + BDS combined PPP–IAR strategy and processed PPP–IAR kinematically and statically using one week of data collected at 20 static stations. The undifferenced wide- and narrow-lane fractional cycle biases for GPS, GLONASS, and BDS were estimated using a regional network, and undifferenced PPP ambiguity resolution was performed to assess the contribution of multi-GNSSs. Generally, over 99% of a posteriori residuals of wide-lane ambiguities were within ±0.25 cycles for both GPS and BDS, while the value was 91.5% for GLONASS. Over 96% of narrow-lane residuals were within ±0.15 cycles for GPS, GLONASS, and BDS. For kinematic PPP with a 10-min observation time, only 16.2% of all cases could be fixed with GPS alone. However, adding GLONASS improved the percentage considerably to 75.9%, and it reached 90.0% when using GPS + GLONASS + BDS. Not all epochs could be fixed with a correct set of ambiguities; therefore, we defined the ratio of the number of epochs with correctly fixed ambiguities to the number of all fixed epochs as the correct fixing rate (CFR). Because partial ambiguity fixing was used, when more than five ambiguities were fixed correctly, we considered the epoch correctly fixed. For the small ratio criteria of 2.0, the CFR improved considerably from 51.7% for GPS alone, to 98.3% when using GPS + GLONASS + BDS combined solutions.     

Infrasonic detection of a Leonid bolide: 1998 November 17

Abstract— During the early morning hours of the night of the peak of the annual Leonid meteor shower on 1998 November 17, a bright fireball (approximately ?12 to ?14 visual magnitude at 100 km in the zenith) was observed over northern New Mexico with visual sightings as far away from Los Alamos as Albuquerque (～150 km to the south of Los Alamos), including direct persistent trail observations at the U. S. A. F. Starfire Optical Range (SOR), which is also near Albuqerque. This event did not produce any sonic boom reports, presumably because of its high altitude. It was also detected locally by an infrared radiometer at Sandia National Laboratory and by an intensified charge-coupled device (CCD) camera located in Placitas, New Mexico. Subsequent investigations of the data from the six infrasound arrays used by Los Alamos National Laboratory (LANL) and operated for the Department of Energy as a part of the Comprehensive Test Ban Treaty (CTBT) Research and Development program for the International Monitoring System (IMS) showed the presence of an infrasonic signal from the proper direction at the correct time for this bolide from two of our six arrays (both located in Los Alamos). The infrasound recordings (i.e., the wave amplitude and period data) indicated that an explosion occurred in the atmosphere at a source height of ～93.5 km (with respect to sea level) or ～90 km with respect to the altitude of Los Alamos, having its origins slightly to the north and west of Los Alamos. Purely geometric solutions from the ground observers reports combined with direct measurements from the CCD camera at Placitas produced a source height of 91 ± 7 km. The signal characteristics analyzed from 0.5 to 3.0 Hz include a total duration of about 3–4 s for a source directed from Los Alamos toward 353.6 ± 0.4° measured from true north at a maximum elevation arrival angle of ～72.7°. The latter was deduced on the basis of the observed signal trace velocities (for the part of the recording with the highest cross-correlation) and ranged from a constant value of about 920–1150 m/s (depending on the window length used in the analysis) for a ray trajectory along a direct refractive path between the source and the Los Alamos arrays. The dominant signal frequency at maximum amplitude at Los Alamos was ～0.71 Hz. These highly correlated signals had a peak to peak, maximum amplitude of ～2.1 microbars (0.21 Pa). Using several methods that incorporate various observed signal characteristics, total distance traveled, etc., our analysis indicates that the bolide probably had a source energy of ～1.14 t (TNT equivalent) or 4.77 × 10⁹ J. This is ～14.1× smaller than the source energy estimate made using the infrasonic, empirical source energy relationship for low-altitude stationary point sources developed in the 1960s by the Air Force Technical Applications Center (AFTAC), Patrick Air Force Base, Florida. This relation was originally developed, however, for much larger source energies and at much longer ranges.     

On the accuracy of atmospheric forcing for extra-tropical storm surge prediction

The ability of the SMARA storm surge numerical prediction system to reproduce local effects in estuarine and coastal winds was recently improved by considering one-way coupling of the air–sea momentum exchange through the wave stress, and best forecasting practices for downscaling. The inclusion of long period atmospheric pressure forcing in tide and tide/surge calculations corrected a systematic error in the surge, produced by the South Atlantic Ocean quasi-stationary pressure patterns. The maximum forecast range for the storm surge at Buenos Aires provided by the real-time use of water level observations is approximately 12 h. The best available water level prediction is the 6-h forecast (nowcast) based on the closest water level observations. The 24-h forecast from the numerical models slightly improves this nowcast. Although the numerical forecast accuracy degrades after the first 48 h, the improvement to the full range observation-based prediction is maintained at the inner Río de la Plata area and extends to the first 3 days at the intermediate navigation channels.     

Late Quaternary clay minerals off Middle Vietnam in the western South China Sea: Implications for source analysis and East Asian monsoon evolution

High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 450 ka during late Quaternary from Core MD05-2901 off Middle Vietnam in the western South China Sea are re-ported to reconstruct a history of East Asian monsoon evolution. Variations in Illite, chlorite, and kaolinite contents indicate a strong glacial-interglacial cyclicity, while changes in smectite content present a higher frequency cyclicity. The provenance analysis indicates a mixture of individual clay minerals from various sources surrounding the South China Sea. Smectite derived mainly from the Sunda shelf and its major source area of the Indonesian islands. Illite and chlorite originated mainly from the Mekong and Red rivers. Kaolinite was provided mainly by the Pearl River. Spectral analysis of the kaolin-ite/(illite chlorite) ratio displays a strong eccentricity period of 100 ka, implying the ice sheet-forced win-ter monsoon evolution; whereas higher frequency changes in the smectite content show an ice sheet-forced obliquity period of 41 ka, and precession periods of 23 and 19 ka and a semi-precession period of 13 ka as well, implying the tropical-forced summer monsoon evolution. The winter monsoon evolution is generally in coherence with the glacial-interglacial cyclicity, with intensified winter monsoon winds during glacials and weakened winter monsoon winds during interglacials; whereas the summer monsoon evolution provides an almost linear response to the summer insolation of low latitude in the Northern Hemisphere, with strengthened summer monsoon during higher insolation and weakened summer monsoon during lower insolation. The result suggests that the high-latitude ice sheet and low-latitude tropical factor could drive the late Quaternary evolution of East Asian winter and summer monsoons, respectively, implying their diplex and self-contained forcing mechanism.