Reactive Nitrogen Compounds at Spitsbergen in the Norwegian Arctic

Simultaneousindependent measurements of NO_y and NO_x(NO_x= NO + NO₂) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NO_xmixing ratio was 27 pptv and did not show any cyclethrough the period. The NO_y mixing ratio showeda maximum in late March, while the difference betweenNO_y and PAN decreased during spring. This is anindication of the dominance of PAN in the NO_ybudget in the Arctic, but possible changes in theefficiency of the NO_y converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h^-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1.     

Seismic facies and architecture of ice-contact submarine fans in high-relief fjords, Troms, Northern Norway

During the Late Weichselian, large marginal moraines were deposited in the Norwegian fjords. In Troms County these features are termed the Skarpnes and Tromsø-Lyngen moraines, respectively, and have been mapped from land into the marine environment where they were formed as ice-contact submarine fans. High-resolution seismic data from several fjords have been studied and reveal a typical sediment thickness of 150–320 m for these ice-contact systems. All of the ice-contact submarine fans were formed under similar climatic conditions, but display wide variation in geometry, architecture and seismic pattern. This variation is related to differences in sediment supply, the nature of the subsurface of the fan (e.g. position of thresholds), basin geometry and basin depth. Based on interpretation of the different seismic facies and the architecture of the fans, former ice-front positions have been suggested and a model has been presented for the formation of different types of ice-contact submarine fans dependent upon variation in local basin condition.     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

On the relation between cloud cover amount and sunshine duration

Summary The total cloud cover is deduced from measurements of monthly mean averages of the percent of possible sunshine duration at three locations in Egypt, Cairo, Bahtim and Sedi-Barrani stations during the period 1987–1995. This sunshine-derived total cloud cover (C_s) is compared to conventional ground-based observations of total cloud covers (C_g) made by meteorological observers. A linear relationship between the two estimates is calculated, and the difference between the two estimates as a function of C_s and C_g is fitted with a least-squares linear equation. It is found that on the average the sunshine-derived values of total cloud cover are about 7% lower than the corresponding ground-based estimated of total cloud cover. Both of these parameters are mainly used in solar radiation models and the error sources are mainly depending upon the way to describe sky cover.     

Microseismicity and active deformation of Messinia,SW Greece

By deploying a 30 3-component digital seismic array in the Messiniakos gulf and the surrounding region, we recorded for a period of 45 days the microseismic activity. With a minimum of six records per event, we located 1121 earthquakes corresponding to an average of 20 events per day. For the hypocenter location we used a local velocity model adopted to two controlled source seismic experiments. Within the array, traveltime residuals were within ± 0.2 s and the epicentral accuracy in the order of ± 2 km, while the hypocentral one is twice this value. Correlation of the seismicity with the tectonic elements indicated that most of the NW-SE oriented faults are active with strike-slip movement along this orientation and extension perpendicular to it. The neogene basins of Messini, Meligalas and Megalopolis are seismically very active and their eastern flanks are delineated by higher seismic activity than their western ones. This indicates that the basins are asymmetric with master faults defining their eastern-northeastern flanks. This hypothesis is supported by the asymmetric structure mapped at the offshore Messiniakos basin as densely spaced high resolution reflection seismic profiles have revealed. The western margins of the basins are less deformed and the seismic activity is dispersed over several minor NW-SE faults. Since the NW-SE striking faults onshore are truncated by major NE-SW oriented ones, their overall length is shortened, reducing their seismic potential and capacity to store large stresses that could produce events above Ms6.1. Offshore western Messinia, in the Ionian Sea, the size and activity of the faults is significantly larger and prone to develop events of larger magnitudes. Subcrustal seismicity indicates a deepening of the foci to the east-northeast.Part of this work was presented at the CIESM Conference, Monaco, 2001, and in the EGS General Assembly, Nice, 2001.     

The influence of climate on mechanistic pathways that affect lower food web production in Northern San Francisco Bay estuary

Significant coherence among time series of environmental and biological production variables suggested mechanistic pathways through which climate contributed to the downward shift in estuarine production (biomass) in northern San Francisco Bay estuary, 1975–1993. Climate directly and indirectly affected physical processes in the estuary through precipitation and its subsequent impact on streamflow and physical variables affected by streamflow. Climate also directly influenced air temperature and wind velocity. The influence if climate was evaluated through a climate index based on sea level pressure. A shift in this climate index in the early 1980s coincided with changes in many environmental variables including water transparency, water temperature, wind velocity, and rainfall. These physical changes were accompanied by a decrease in diatom, total zooplankton, andNeomysis mercedis carbon at the base of the food web throughout the estuary. Box-Jenkins time series coherence analysis was used to quantify associations among these physical, chemical, and biological time series for nine regions of the estuary. These associations were used to develop a conceptual model of mechanistic pathways that directly linked food web carbon production to climate. Strong coherence among diatom, zooplankton, andN. mercedis carbon time series suggested climate also had an indirect impact on food web production through trophic cascade. Differing mechanistic pathways among the nine regions of the estuary suggested climate was an important contributor to the spatial variability in total food web production and trophic structure.     

Spectral characteristics of components of a model radio-brightness distribution for the radio galaxy 3C 234

Physical processes that can, under cosmic conditions, give rise to emission whose spectrum peaks at some frequency are discussed in the context of the spectrum of the central extended component of a model brightness distribution for the radio galaxy 3C 234. This component is not detected at decameter wavelengths, probably due to the absorption of the radiation in the plasma in the source itself.