Arcanite from Fumarole Exhalations of the Tolbachik Volcano (Kamchatka,Russia) and Its Crystal Structure

The crystal structure (R = 0.0194) of arcanite β-K₂SO₄ was studied on a single crystal from exhalations of the Arsenatnaya fumarole, Tolbachik Volcano (Kamchatka, Russia). The mineral crystallizes at a temperature of ≥350–430°C and associates with langbeinite, aphthitalite, hematite, tenorite, johillerite, and others. Arcanite is orthorhombic, Pnma, a = 7.4763(2) Å, b = 5.77262(16) Å, c = 10.0630(3) Å, V = 434.30(2) ų, Z = 4. Its structure contains isolated SO₄ tetrahedra, whereas K cations center ten- and nine-fold polyhedra.     

Sources of Magmatic Rocks from the Deep-Sea Floor of the Arctic Ocean and the Central Atlantic: Evidence from Data on the U–Pb Age,Hf Isotopes,and REE Geochemistry of Zircons

The results of geochronological (U–Pb), isotope–geochemical (Lu–Hf), and geochemical (REEs) studies of young (MZ, KZ) and xenogenic (AR, PR) zircons from magmatic rocks of the Central Arctic rises of the Arctic Ocean (AO) and the crest zone of the Mid-Atlantic Ridge (MAR) are presented. The data obtained show that the depleted mantle could be a source of young (KZ) zircons of the MAR, whereas young (MZ) zircons of the MAR and all xenogenic (AR, PR) zircons of the AO and MAR are from crustal rocks of the continental lithosphere.     

Aerosols in the Near-Water Surface Layer of the Caspian Sea

The first data on the concentrations, fluxes, and mineral and chemical compositions of aerosols from the near-water surface layer of the Caspian Sea are presented. It is shown that the aerosol fluxes onto the sea surface are comparable to the fluxes of a lithogenic substance in a water column. The mineral and chemical compositions of aerosols depend on the carrying air masses that pass through different regions. The coefficients of enrichment of aerosols with chemical elements relative to the upper lithosphere and their correlation relationships are studied.

     

Geochemical Constraints for the Bulk Composition of the Moon

Doklady Earth Sciences - The bulk composition of the silicate Moon (crust + mantle, BSM) is determined on the basis of inversion of gravitational and seismic data. It is shown that the mantle...     

Numerical Simulations of Magnetized Astrophysical Jets and Comparison with Laboratory Laser Experiments

The results of MHD numerical simulations of the formation and development of magnetized jets are presented. Similarity criteria for comparisons of the results of laboratory laser experiments and numerical simulations of astrophysical jets are discussed. The results of laboratory simulations of jets generated in experiments at the Neodim laser installation are presented.     

Carbon Isotope Characteristics as Evidence of an External Source of High-Temperature Granitoids in Granulite Complexes

Doklady Earth Sciences - Data on the carbon isotope composition of graphite and CO2 from inclusions in quartz of granitoids of the Southern Marginal Zone (SMZ) of the Limpopo granulite belt, South...     

The Magmatic–Hydrothermal Transition and Origin of Brine in the Oceanic Core Complex of the Mid-Atlantic Ridge at 13° N

New data on local mineral associations and the microheterogeneity of minerals and fluid inclusions in gabbro were obtained for the gabbro–peridotite oceanic core complex with a long-lived detachment fault controlling the hydrothermal activity. It is assumed that the hydrothermal hydrogen-bearing fluid with a NaCl content of >30 wt % is formed in the seawater/harzburgite (~1/5) reaction of serpentinization. The brine residual after serpentinization interacted with gabbro at the final stages of crystallization of an intrusion and assimilated some components (K, REEs, and Ba) from the residual melt. The interaction was resulted in metamorphic transformations of gabbro at decreasing temperature below 500°C. The reaction of the decomposition of magmatic titanomagnetite with the transition of iron reduced to Fe²⁺ into newly formed chlorinebearing amphibole at 540–450°C and logf(O₂) from–20 to–24 is shown.

     

Magnetic measurements in electrical prospecting by resistivity methods

The electrical resistivity and induced polarization (IP) methods are widely used in geological mapping, prospecting and exploration of mineral deposits, engineering geology, hydrogeology, archaeology, and geotechnical and environmental applications. Historically, these methods have formed the basis of the electrical prospecting technique. In these methods, a DC or low-frequency AC electrical current is introduced into the earth through a grounded transmitter line. The measured quantity is the electric field. However, if the earth’s resistivity or chargeability changes horizontally, this change gives rise to an anomalous magnetic field, which is studied by the magnetometric resistivity (MMR) and magnetic induced polarization (MIP) methods, respectively. Along with advantages, some shortcomings are inherent in the MMR and MIP techniques. Apparently, the main drawback of these methods is that the magnetic fields of both the transmitter line wire and ground electrodes on the surface are several orders of magnitude greater than the anomalous magnetic field response. This introduces a significant “noise” to magnetic-resistivity data. We investigate the potential of using a circular electric dipole (CED) in magnetometric resistivity techniques. It has been found that the application of a CED, instead of a conventional transmitter line, dramatically enhances the signal-to-noise ratio.     

Fahlore and Sphalerite from the Darasun Gold Deposit in the Eastern Transbaikal Region,Russia: I. Mineral Assemblages and Intergrowths,Chemical Composition,and Its Evolution

The mineral assemblages, mode of occurrence, and chemical compositions of coexisting fahlore and sphalerite from the Darasun gold deposit have been described. Three generations of fahlore and three generations of sphalerite have been recognized. The FeS content in sphalerite coexisting with fahlore ranges from 0.8 to 9.4 mol %. The complete solid solution series Fe-tetrahedrite–Zn-tetrahedrite–Fe-tennantite–Zn-tennantite reflected in Sb/(Sb + As) and Fe/(Fe + Zn) ratios ranging from 0 to 0.97 and from 0.07 to 1.00, respectively, with a predominant negative relationship between these ratios has been identified for the first time at the deposit. Stepped, oscillatory, and combined stepped-oscillatory growth zonings within fahlore grains and heterogeneous aggregates of fahlore have been found. Fahlore is enriched in As with respect to Sb, and Zn-tetrahedrite is followed by Fe- and Zn-tennantite from early to late generation; Zn-tetrahedrite is followed by Fe-tennantite in zoned grains and overgrown rims; sphalerite crystallized at decreased temperature and sulfur fugacity. The evolution of the chemical composition of fahlores was caused by the evolving temperature, fluid salinity, and conditions of metal migration.     

Geodynamic setting,structure, and composition of continuous trachybasalt-trachyandesite-rhyolite series in the north of Altai-Sayan area: the role of crust-mantle interaction in continental magma formation

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (< 1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.