Atmospheric chemistry of hydrogen fluoride

Although a large volume of monitoring and computer simulation data exist for global coverage of HF, study of HF in the troposphere is still limited to industry whose primary interest is the safety and risk assessment of HF release because it is a toxic gas. There is very limited information on atmospheric chemistry, emission sources, and the behavior of HF in the environment. We provide a comprehensive review on the atmospheric chemistry of HF, modeling the reactions and transport of HF in the atmosphere, the removal processes in the vertical layer immediately adjacent to the surface (up to approximately 500 m) and recommend research needed to improve our understanding of atmospheric chemistry of HF in the troposphere. The atmospheric chemistry, emissions, and surface boundary layer transport of hydrogen fluoride (HF) are summarized. Although HF is known to be chemically reactive and highly soluble, both factors affect transport and removal in the atmosphere, the chemistry can be ignored when the HF concentration is at a sufficiently low level (e.g., 10 ppmv). At a low concentration, the capability for HF to react in the atmosphere is diminished and therefore the species can be mathematically treated as inert during the transport. At a sufficiently high concentration of HF (e.g., kg/s release rate and thousands of ppm), however, HF can go through a series of rigorous chemical reactions including polymerization, depolymerization, and reaction with water to form molecular complex. As such, the HF species cannot be considered as inert because the reactions could intimately influence the plume’s thermodynamic properties affecting the changes in plume temperature and density. The atmospheric residence time of HF was found to be less than four (4) days, and deposition (i.e., atmosphere to surface transport) is the dominant mechanism that controls the removal of HF and its oligomers from the atmosphere. The literature data on HF dry deposition velocity was relatively high compared to many commonly found atmospheric species such as ozone, sulfur dioxide, nitrogen oxides, etc. The global average of wet deposition velocity of HF was found to be zero based on one literature source. Uptake of HF by rain drops is limited by the acidity of the rain drops, and atmospheric particulate matter contributes negligibly to HF uptake. Finally, given that the reactivity of HF at a high release rate and elevated mole concentration cannot be ignored, it is important to incorporate the reaction chemistry in the near-field dispersion close to the proximity of the release source, and to incorporate the deposition mechanism in the far-field dispersion away from the release source. In other words, a hybrid computational scheme may be needed to address transport and atmospheric chemistry of HF in a range of applications. The model uncertainty will be limited by the precision of boundary layer parameterization and ability to accurately model the atmospheric turbulence.     

长江上游流域秋季连阴雨时空变化特征

利用长江上游259个气象站逐日降水资料,采用线性趋势分析方法,分析了近1961—2012年来长江上游流域秋季连阴雨的时空变化特征。结果表明,长江上游流域秋季连阴雨过程平均出现1.54次/a,其中9月出现次数最多,10月次之,11月出现较少。秋季连阴雨日数、累积降水量分别以2.3 d/(10 a)、13.7 mm/(10 a)的速率显著减少,连阴雨开始和结束日期平均为9月9日和9月30日均表现出推迟趋势。进入21世纪后,5—9 d、10 d以上连阴雨过程的次数、80.0 mm以上连阴雨过程的次数均表现出减少趋势。金沙江下游和四川盆地东部为秋季连阴雨累计雨量及其变化速率的大值中心,四川盆地西南部为连阴雨日数及其变化速率的大值中心。9月的降水中心、雨日分布情况与秋季总体情况基本一致,10月降水中心、阴雨日数的中心出现了明显东撤,11月东撤更为明显。     

Spatially explicit modelling of the impact of climate changes on pasture production in the North Island,New Zealand

To assess the potential impact of climate changes on pasture production in the North Island, New Zealand, eight climate scenarios of increased temperature and increased (or decreased) rainfall were investigated by integrating a polynomial regression model for pasture production with a Geographic Information System (GIS). The results indicated that the climate change scenarios assuming an increase in temperature by 1–2°C and a rainfall change by −20 to +20% would have a very significant impact on pasture production with a predicted pasture production variation from −46.2 to +51.9% compared with the normal climate from 1961–1990. Increased temperature would generally have a positive effect on pasture production in the south and southeast of the North Island, and increased rainfall would have a positive effect in the central, south and southeast of the North Island and a negative effect in the north of the North Island. The interaction of decreased rainfall and increased temperature would have a negative impact for the whole North Island except some central areas with high rainfall. Relevant management practices for coping with potential climate change are discussed.     

1900年前后中国特大旱灾的旱情及其形成的自然因素

为了深入认识近代特大干旱事件的成因,利用中国1900年前后旱涝等级资料、近500年旱涝分布图集和西北地区近500年旱涝分布图集资料等,分析了1900年前后中国特大旱灾的旱情及其形成的自然因素。结果表明:(1)1900年前后的特大旱灾出现在100年来年代际变暖期,以北方干旱最严重,且多灾并发。(2)1900年前后是年代际夏季风最弱的时期,西太平洋副热带高压位置偏南和西伯利亚高压年代际增强期是特大旱灾发生的直接原因。(3)强厄尔尼诺事件与太阳黑子相对数的低值期,也是1900年前后特大旱灾发生的重要原因。     

基于通量距平的大气-海洋-海冰耦合模式

该文是对基于月平均通量距平（ＭＦＡ）的海气耦合方案及其在４个海气耦合的环流模式中应用情况的一个综合评述．这些模式的实施情况表明，由于采用精细化了的参考通量，修正的ＭＦＡ（ＭＭＦＡ）比它的原型具有更为稳定的控制气候漂移的能力．     

The Impact of Land-Surface Parameter Properties and Resolution on the Simulated Cloud-Topped Atmospheric Boundary Layer

A method to simulate characteristics of wind speed in the boundary layer of tropical cyclones in an idealized manner is developed and evaluated. The method can be used in a single-column modelling set-up with a planetary boundary-layer parametrization, or within large-eddy simulations (LES). The key step is to include terms in the horizontal velocity equations representing advection and centrifugal acceleration in tropical cyclones that occurs on scales larger than the domain size. Compared to other recently developed methods, which require two input parameters (a reference wind speed, and radius from the centre of a tropical cyclone) this new method also requires a third input parameter: the radial gradient of reference wind speed. With the new method, simulated wind profiles are similar to composite profiles from dropsonde observations; in contrast, a classic Ekman-type method tends to overpredict inflow-layer depth and magnitude, and two recently developed methods for tropical cyclone environments tend to overpredict near-surface wind speed. When used in LES, the new technique produces vertical profiles of total turbulent stress and estimated eddy viscosity that are similar to values determined from low-level aircraft flights in tropical cyclones. Temporal spectra from LES produce an inertial subrange for frequencies \(\gtrsim \)0.1 Hz, but only when the horizontal grid spacing \(\lesssim \)20 m.     

CoLM模式对青藏高原中部BJ站陆面过程的数值模拟

利用公共陆面模式Common Land Model(CoLM)及"全球协调加强观测计划之亚澳季风青藏高原试验"(CAMP/Tibet)中那曲地区Bujiao(BJ)站2002—2004年的观测资料对该地区进行了单点数值模拟试验。通过比较模拟与观测的地表能量通量,表明CoLM较成功地模拟了该地区的能量分配。模式对向上的短波辐射、向上的长波辐射、净辐射及土壤热通量模拟得较好,但冬季存在偏差。进一步比较了模拟和观测的土壤温度及土壤湿度,发现浅层60 cm土壤温度模拟较好,深层存在偏差,表现为土壤温度变化滞后于实际变化。土壤湿度总体偏小,尤其是冬季冻结期,土壤冻融过程中忽略了土壤液态水在温度0℃以下仍能存在,含冰量模拟偏高。     

A western North Pacific tropical cyclone intensity prediction scheme

A western North Pacific tropical cyclone (TC) intensity prediction scheme (WIPS) is developed based on TC samples from 1996 to 2002 using the stepwise regression technique, with the western North Pacific divided into three sub-regions: the region near the coast of East China (ECR), the South China Sea region (SCR), and the far oceanic region (FOR). Only the TCs with maximum sustained surface wind speed greater than 17.2 m s⁻¹ are used in the scheme. Potential predictors include the climatology and persistence factors, synoptic environmental conditions, potential intensity of a TC and proximity of a TC to land. Variances explained by the selected predictors suggest that the potential intensity of a TC and the proximity of a TC to land are significant in almost all the forecast equations. Other important predictors include vertical wind shear in ECR, 500-hPa geopotential height anomaly at the TC center, zonal component of TC translation speed in SCR, intensity change of TC 12 or 24 h prior to initial time, and the longitude of TC center in FOR.     

Influence of leaf water potential on diurnal changes in CO2 and water vapour fluxes

Mass and energy fluxes between the atmosphere and vegetation are driven by meteorological variables, and controlled by plant water status, which may change more markedly diurnally than soil water. We tested the hypothesis that integration of dynamic changes in leaf water potential may improve the simulation of CO₂ and water fluxes over a wheat canopy. Simulation of leaf water potential was integrated into a comprehensive model (the ChinaAgrosys) of heat, water and CO₂ fluxes and crop growth. Photosynthesis from individual leaves was integrated to the canopy by taking into consideration the attenuation of radiation when penetrating the canopy. Transpiration was calculated with the Shuttleworth-Wallace model in which canopy resistance was taken as a link between energy balance and physiological regulation. A revised version of the Ball-Woodrow-Berry stomatal model was applied to produce a new canopy resistance model, which was validated against measured CO₂ and water vapour fluxes over winter wheat fields in Yucheng (36°57′ N, 116°36′ E, 28 m above sea level) in the North China Plain during 1997, 2001 and 2004. Leaf water potential played an important role in causing stomatal conductance to fall at midday, which caused diurnal changes in photosynthesis and transpiration. Changes in soil water potential were less important. Inclusion of the dynamics of leaf water potential can improve the precision of the simulation of CO₂ and water vapour fluxes, especially in the afternoon under water stress conditions.     

气象电视会商会议系统的使用和维护

本文介绍省台———国家气象中心的电视会议系统的构成原理,总结省台与国家气象中心电视会商系统使用维护过程中的经验,对系统的使用和正在进行安装调试的“省—市—县”电视会商系统的使用提供借鉴。