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201.
The distribution of several minor and trace elements mainly in fresh (dominating TDS 160–400 mg/l) groundwater of Latvia have
been investigated by the Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) technique. An evaluation of results of about
700 analyses leads to the conclusion that concentrations of these elements is influenced by: pH–Eh conditions, groundwater
residence time and diffuse contamination, whereas the role of water-bearing sediments is of secondary importance. Most trace
elements are characterised by low mobility under alkaline and reducing conditions; concentrations in confined aquifers are
much smaller than the Maximum Permissible Values for drinking water. The strongest anomalies of REE, Al and P were found in
shallow groundwater around the former agrochemical storehouses. 相似文献
202.
Paul F. Hudak 《Environmental Geology》2008,55(6):1311-1317
This modeling study evaluated the capability of alternative funnel-and-gate structures with three gates for capturing contaminated
groundwater in a hypothetical unconfined aquifer. Simulated interceptor structures were linear and 45 m wide, consisting of
three gates and two funnels (walls). One gate occupied the center and two gates occupied the ends of the interceptor structures.
The structures, positioned perpendicular to regional groundwater flow, traversed the entire thickness of the aquifer. A total
of four structures were evaluated (numbers designate widths of end, center, and end gates, respectively, in meters): 3-3-3,
2-5-2, 1-7-1, and 4-1-4. Particle tracking and zonal water budgets identified shapes of capture zones and discharge patterns
for each interceptor structure. A mass transport model, accounting for advection and hydrodynamic dispersion, tested the capability
of each structure for capturing a contaminant plume. Results suggest that: time-dependent capture zones underestimate the
amount of time to capture a contaminant plume, wide center gates facilitate plume capture, and wide end gates facilitate lateral
containment of contaminants. Of the structures simulated, the 2-5-2 configuration was relatively efficient at processing and
containing the simulated contaminant plume. 相似文献
203.
A Triassic carbonate unit has been intensively drained by zinc and lead ore mines and numerous borehole fields since the nineteenth
century. Its groundwater recharge has increased due to: pumping of water from boreholes, mining activity, and urbanization.
An approach to determine the amounts of the recharge at a variety of spatial scales is presented in the paper. Different methods
were used to identify and quantify recharge components on a regional and local scale: mathematical modelling was performed
for four aquifers included in an aquifer system, an analytical estimation based on the assumption that an average recharge
is equal to the average discharge of the hydrogeological system—for six man-made drainage centres, and the method of water
level fluctuation (WLF) was applied in one observation borehole. Results of modelling have been supplemented by observation
of environmental tracers (δ18O, δ2H, 3H), noble gases temperatures, and 4Heexc in groundwater. The regional aquifer’s current recharge according to estimations performed by means of modelling varies from
39 to 101 mm/year on average. Depending on the aquifer site the average precipitation ranges from 779 to 864 mm/year. In the
confined part of the aquifer average recharge ranges from 26 to 61 mm/year. Within outcrops average recharge varies from 96
to 370 mm/year. Current recharge estimated by the analytical method for man-made drainage centres varies from 158 up to 440 mm/year.
High values are caused by different recharge sources like precipitation, induced leakage from shallow aquifers, and water
losses from streams, water mains and sewer systems. Pumping of water, mining and municipal activities constitute additional
factors accounting for the intensified recharge. 相似文献
204.
Mapping susceptibility of rainfall-triggered shallow landslides using a probabilistic approach 总被引:2,自引:0,他引:2
To prepare a landslide susceptibility map is essential to identify hazardous regions, construct appropriate mitigation facilities,
and plan emergency measures for a region prone to landslides triggered by rainfall. The conventional mapping methods require
much information about past landslides records and contributing terrace and rainfall. They also rely heavily on the quantity
and quality of accessible information and subjectively of the map builder. This paper contributes to a systematic and quantitative
assessment of mapping landslide hazards over a region. Geographical Information System is implemented to retrieve relevant
parameters from data layers, including the spatial distribution of transient fluid pressures, which is estimated using the
TRIGRS program. The factor of safety of each pixel in the study region is calculated analytically. Monte Carlo simulation
of random variables is conducted to process the estimation of fluid pressure and factor of safety for multiple times. The
failure probability of each pixel is thus estimated. These procedures of mapping landslide potential are demonstrated in a
case history. The analysis results reveal a positive correlation between landslide probability and accumulated rainfall. This
approach gives simulation results compared to field records. The location and size of actual landslide are well predicted.
An explanation for some of the inconsistencies is also provided to emphasize the importance of site information on the accuracy
of mapping results. 相似文献
205.
This study presents a laboratory study of the following two aspects: (1) the influence of sea laver treatment acid on the
geoenvironmental properties of Ariake Sea tidal mud, and (2) the natural remediation effect on the sea laver treatment acid
contaminated Ariake Sea tidal mud caused by the upward seepage of pore water liquid in the mud. Firstly, the mechanisms of
the transport of sea laver treatment acid in the Ariake Sea tidal mud and the generation mechanisms of the upward seepage
flow in the Ariake Sea tidal mud are discussed. Secondly, a series of one-dimensional laboratory infiltration tests were carried
out to investigate the deterioration of the Ariake Sea tidal mud caused by the sea laver acid treatment practice. Test results
reveal that the acid treatment practice caused considerable change in the geochemical properties of the mud in terms of increase
in sulfide content and decrease in pH value. After the treatment by the sea laver treatment acid, the sulfide content of the
mud even exceeded the safe limit value for the benthos, which represents undesirable living condition for benthos. Thirdly,
series of laboratory fresh seawater infiltration tests for the deteriorated Iida site mud were conducted to illustrate this
natural remediation efficiency. It is found that with the infiltration of the fresh seawater, the sulfide content of the Iida
site mud was considerably reduced and pH value increased to an acceptable range for benthos living in the tidal flat mud.
With the increase in the infiltration time and the hydraulic gradient, the remediation efficiency could be increased. 相似文献
206.
Huijun Jin Zhi Wei Shaoling Wang Qihao Yu Lanzhi Lü Qingbai Wu Yanjun Ji 《Engineering Geology》2008,101(3-4):96-109
The Qinghai–Tibet Highway and Railway (the Corridor) across the Qinghai–Tibet Plateau traverses 670 km of permafrost and seasonally frozen-ground in the interior of the Plateau, which is sensitive to climatic and anthropogenic environmental changes. The frozen-ground conditions for engineering geology along the Corridor is complicated by the variability in the near-surface lithology, and the mosaic presence of warm permafrost and talik in a periglacial environment. Differential settlement is the major frost-effect problem encountered over permafrost areas. The traditional classification of frozen ground based on the areal distribution of permafrost is too generalized for engineering purposes and a more refined classification is necessary for engineering design and construction. A proposed classification of 51 zones, sub-zones, and sections of frozen ground has been widely adopted for the design and construction of foundations in the portion of the Corridor studied. The mean annual ground temperature (MAGT), near-surface soil types and moisture content, and active faults and topography are most commonly the primary controlling factors in this classification. However, other factors, such as local microreliefs, drainage conditions, and snow and vegetation covers also exert important influences on the features of frozen ground. About 60% of the total length of the Corridor studied possesses reasonably good frozen-ground conditions, which do not need special mitigative measures for frost hazards. However, other sections, such as warm and ice-rich or -saturated permafrost, particularly in the sections in wetlands, ground improvement measures such as elevated land bridges and passive or proactive cooling techniques need to be applied to ensure the long-term stability of thermally unstable, thick permafrost subsoils, and/or refill with non-frost-susceptible soils. Due to the long-history of the construction and management of the Corridor by various government departments, adverse impacts of construction and operation on the permafrost environment have been resulted. It is recommended that an integrated, executable plan for the routing of major construction projects within this transportation corridor be established and long-term monitoring networks installed for evaluating and mitigating the impact from anthropogenic and climatic changes in frozen-ground conditions. 相似文献
207.
Experiments at 6.0–7.1 GPa and 1500–1700°C were carried out to explore the boundary conditions of diamond nucleation and growth in pyrrhotite-carbon melt-solutions. Pyrrhotite is one of the main sulfide minerals of the pyrrhotite-pentlandite-chalcopyrite assemblage of mantle rocks and primary inclusions in diamond. Solutions of carbon in sulfide melts oversaturated with respect to diamond at the expense of the dissolution of starting graphite (thermodynamically unstable phase) are formed owing to the difference between the solubilities of graphite and diamond, which increases under the influence of temperature gradients in experimental samples. We determined the fields of carbon solutions in pyrrhotite melt showing labile and metastable oversaturation with respect to diamond, which correspond to the spontaneous nucleation of the diamond phase and diamond growth on seeds, respectively. The linear growth rate of diamond in sulfide-carbon melts is rather high (on average, 10 μ/min during the first 1–2 min from the onset of spontaneous crystallization). The nucleation density is estimated as 180 grains per cubic centimeter. Diamonds crystallized from sulfide melts show octahedral and spinel twin shapes. Diamond polycrystals were synthesized for the first time from a sulfide medium as intergrowths of skeletal (edge) or “cryptocrystalline” microdiamonds, from 1 to 100 μm in size, their spinel twins and, occasionally, polysynthetic (star-shaped) twins. During diamond growth from sulfidecarbon melts on smooth faces of cuboctahedral diamond seeds synthesized in metal systems, smooth-faced layer-by-layer step-like growth was observed on their octahedral (111) faces, whereas growth on the (100) cubic faces produced rough-surfaced layers of intergrown micropyramids, whose axes were oriented normal to the (100) face. The obtained experimental results were applied to the problem of diamond genesis under the conditions of the Earth’s mantle in the framework of the model of carbonate-silicate parental melts with blebs of immiscible sulfide melts. 相似文献
208.
A. A. Krylov O. M. Khlystov T. I. Zemskaya H. Minami A. Hachikubo H. Shoji M. Kida T. P. Pogodaeva L. Naudts J. Poort 《Geochemistry International》2008,46(10):985-995
This paper presents data on authigenic siderite first found in surface sediments from mud volcanoes in the Central (K-2) and Southern (Malen’kii) basins of Lake Baikal. Ca is the predominant cation, which substitutes Fe in the crystalline lattice of siderite. The enrichment of the carbonates in the 13C isotope (from +3.3 to +6.8‰ for the Malen’kii volcano and from +17.7 to +21.9‰ for K-2) results from the crystallization of the carbonates during methane generation via the bacterial destruction of organic matter (acetate). The overall depletion of the carbonates in 18O is mainly inherited from the isotopic composition of Baikal water. 相似文献
209.
This paper reports the results of a study of the composition of mica (biotite) crystallizing in the system of phonolite melt-Cl- and F-bearing aqueous fluid at T ~ 850°C, P = 200 MPa, and \(f_{O_2 } \) = Ni-NiO, as well as data on F and Cl partitioning between coexisting phases. It was established that Cl content in mica is significantly lower than in phonolite melt and, especially, in fluid. Fluorine shows a different behavior in this system: its content in mica is always higher than in phonolite melt but lower than in fluid. The mica-melt partition coefficients of Cl and F also behave differently. The Cl partition coefficient gradually increases from 0.17 to 0.33 with increasing Cl content in the system, whereas the partition coefficient of F sharply decreases from 3.0 to 1.0 with increasing total F content. The apparent partition coefficients of F between biotite and groundmass (melt) in various magmatic rocks are usually significantly higher than the experimental values. It was supposed that the higher Bt/glassDF values in natural samples could be related to the influence of later oxidation reactions, reequilibration of biotite at continuously decreasing \(f_{H_2 O} \)/f HF ratio, and an increase in this coefficients with decreasing total F content in the system. 相似文献
210.
Calculations of the saturation of groundwaters with respect to minerals of the rocks hosting these waters indicate that most of the analyzed groundwaters were saturates with respect to calcite, dolomite, and quartz. Brines of chloride-calcic composition were determined to be saturated with respect to calcite, whereas brines of chloride-sodic composition are saturated with respect to dolomite and quartz. The solution was simultaneously saturated with respect to six minerals for the association ankerite-calcite-dolomite-pyrite-quartz-strontianite. An increase in the number of minerals with respect to which solution is saturated is correlated with an increase in the diversity of types of groundwaters and an increase in the runoff rate. The paper proposes possible avenues for searches for relations between hydrogeological and geochemical parameters that make it possible to adapt the thermodynamic models to real geological-hydrogeological conditions. The research was centered on the testing of groundwaters for their saturation with respect to minerals of the rocks hosting these waters. This parameter plays a significant part in forming the geochemical type of natural waters because it reflects the crystallization of a mineral from a solution and, consequently, the removal of an element from the aqueous solution. 相似文献