Investigation of ion beam techniques for the analysis and exposure of particles encapsulated by silica aerogel: Applicability for Stardust

Abstract— In 2006, the Stardust spacecraft will return to Earth with cometary and perhaps interstellar dust particles embedded in silica aerogel collectors for analysis in terrestrial laboratories. These particles will be the first sample return from a solid planetary body since the Apollo missions. In preparation for the return, analogue particles were implanted into a keystone of silica aerogel that had been extracted from bulk silica aerogel using the optical technique described in Westphal et al. (2004). These particles were subsequently analyzed using analytical techniques associated with the use of a nuclear microprobe. The particles have been analyzed using: a) scanning transmission ion microscopy (STIM) that enables quantitative density imaging; b) proton elastic scattering analysis (PESA) and proton backscattering (PBS) for the detection of light elements including hydrogen; and c) proton‐induced X‐ray emission (PIXE) for elements with Z > 11. These analytical techniques have enabled us to quantify the composition of the encapsulated particles. A significant observation from the study is the variable column density of the silica aerogel. We also observed organic contamination within the silica aerogel. The implanted particles were then subjected to focused ion beam (FIB) milling using a 30 keV gallium ion beam to ablate silica aerogel in site‐specific areas to expose embedded particles. An ion polished flat surface of one of the particles was also prepared using the FIB. Here, we show that ion beam techniques have great potential in assisting with the analysis and exposure of Stardust particles.     

Dynamical implications of Jupiter's tropospheric ammonia abundance

Groundbased radio observations indicate that Jupiter's ammonia is globally depleted from 0.6 bars to at least 4-6 bars relative to the deep abundance of ∼3 times solar, a fact that has so far defied explanation. The observations also indicate that (i) the depletion is greater in belts than zones, and (ii) the greatest depletion occurs within Jupiter's local 5-μm hot spots, which have recently been detected at radio wavelengths. Here, we first show that both the global depletion and its belt-zone variation can be explained by a simple model for the interaction of moist convection with Jupiter's cloud-layer circulation. If the global depletion is dynamical in origin, then important endmember models for the belt-zone circulation can be ruled out. Next, we show that the radio observations of Jupiter's 5-μm hot spots imply that the equatorial wave inferred to cause hot spots induces vertical parcel oscillation of a factor of ∼2 in pressure near the 2-bar level, which places important constraints on hot-spot dynamics. Finally, using spatially resolved radio maps, we demonstrate that low-latitude features exceeding ∼4000 km diameter, such as the equatorial plumes and large vortices, are also depleted in ammonia from 0.6 bars to at least 2 bars relative to the deep abundance of 3 times solar. If any low-latitude features exist that contain 3-times-solar ammonia up to the 0.6-bar ammonia condensation level, they must have diameters less than ∼4000 km.     

Ocean-floor hydrothermal metamorphism in the Limousin ophiolites (western French Massif Central): evidence of a rare preserved Variscan oceanic marker

The Limousin ophiolite is located at the suture zone between two major thrust sheets in the western French Massif Central. This ophiolitic section comprises mantle‐harzburgite, mantle‐dunite, wehrlites, troctolites and layered gabbros. It has recorded a static metamorphic event transforming the gabbros into undeformed amphibolites and the magmatic ultramafites into serpentinites and/or pargasite‐bearing chloritites. With various thermobarometric methods, it is possible to show that the different varieties of amphibole have registered low‐P (c. 0.2 GPa) conditions with temperature ranging from high‐T, late‐magmatic conditions to greenschist–zeolite metamorphic facies. The abundance of undeformed metamorphic rocks (which is typical of the lower oceanic crust), the occurrence of Ca–Al (–Mg) metasomatism illustrated by the growth of Ca–Al silicates in veins or replacing the primary magmatic minerals, the P–T conditions of the metamorphism and the numerous similarities with oceanic crustal rocks from Ocean Drilling Program and worldwide ophiolites are the main arguments for an ocean‐floor hydrothermal metamorphism in the vicinity of a palaeo‐ridge. Among the West‐European Variscan ophiolites, the Limousin ophiolites constitute an extremely rare occurrence that has not been involved in any HP (subduction‐related) or MP (orogenic) metamorphism as observed in other ophiolite occurrences (i.e. France, Spain and Germany).     

SORPTION AND DESORPTION CHARACTERISTICS OF CADMIUM BY FOUR DIFFERENT SOILS IN NORTHEAST CHINA

1IN TR O D U C TIO NA s a persistentand toxic pollutant, cadm ium (C d) canresultin m any adverse health effects in a variety oftis-suesand organssuch asthe lung,kidney,urinary,blad-der,pancreas,breast and prostate (SA TA R U G etal.,2003).C adm ium in so…     

Estimation of dispersion in estuaries by a self-consistent method

Longitudinal and transverse dispersion in estuaries may be determined in principle by measuring the change in time of the concentration field of a water soluble dye. In practice, measurements may take the form of several sampling runs crossing the dye patch. The coefficients of dispersion are usually estimated from the second moments of the concentration field; the use of second moments, in particular, introduces errors because measurements at long times or distance are unduly emphasized.A self-consistent method, free of the disadvantages inherent in the use of higher moments, is described in which the distribution of concentration in space is related to the zeroth spatial moment of concentration. In this formulation, based upon sampling runs across the dye patch, the concentration field in the estuary may be directly and simply related to the dispersion coefficients in both the intercept and gradient of a linear graph.The methods are illustrated by the characterization of a series of experiments in the Inner Estuary of Milford Haven.     

Robertson-Walker type model with conformally invariant scalar field with trace-free energy momentum tensor

A non-static exact solution of the Einstein equations corresponding to a conformally invariant scalar field with trace-free energy momentum tensor is obtained for the Robertson-Walker type metric. Some physical properties of the solution are discussed.     

A neural network approach to ship track-keeping control

This paper presents an on-line trained neural net work controller for ship track-keeping problems. Following a brief review of the ship track-keeping control development since the 1980's, an analysis of various existing backpropagation-based neural controllers is provided. We then propose a single-input multioutput (SIMO) neural control strategy for situations where the exact mathematical dynamics of the ship are not available. The aim of this study is to build an autonomous neural controller which uses rudder to regulate both the tracking error and heading error. During the whole control process, the proposed SIMO neural controller adapts itself on-line from a direct evaluation of the control accuracy, and hence the need for a “teacher” or an off-line training process can be removed. With a relatively modest amount of quantitative knowledge of the ship behavior, the design philosophy enables real time control of a nonlinear ship model under random wind disturbances and measurement noise. Three different track-keeping tasks have been simulated to demonstrate the effectiveness of the training method and the robust performance of the proposed neural control strategy     

Identification of physical processes inherent in artificial neural network rainfall runoff models

The emergence of artificial neural network (ANN) technology has provided many promising results in the field of hydrology and water resources simulation. However, one of the major criticisms of ANN hydrologic models is that they do not consider/explain the underlying physical processes in a watershed, resulting in them being labelled as black‐box models. This paper discusses a research study conducted in order to examine whether or not the physical processes in a watershed are inherent in a trained ANN rainfall‐runoff model. The investigation is based on analysing definite statistical measures of strength of relationship between the disintegrated hidden neuron responses of an ANN model and its input variables, as well as various deterministic components of a conceptual rainfall‐runoff model. The approach is illustrated by presenting a case study for the Kentucky River watershed. The results suggest that the distributed structure of the ANN is able to capture certain physical behaviour of the rainfall‐runoff process. The results demonstrate that the hidden neurons in the ANN rainfall‐runoff model approximate various components of the hydrologic system, such as infiltration, base flow, and delayed and quick surface flow, etc., and represent the rising limb and different portions of the falling limb of a flow hydrograph. Copyright © 2004 John Wiley & Sons, Ltd.     

The Dergaon (H5) chondrite: Fall,classification, petrological and chemical characteristics,cosmogenic effects,and noble gas records

Abstract— A multiple fall of a stony meteorite occurred near the town of Dergaon in Assam, India, on March 2, 2001. Several fragments weighing <2 kg and a single large fragment weighing ～10 kg were recovered from the strewn field, which extended over several tens of square kilometers. Chemical, petrographic, and oxygen isotopic studies indicate it to be, in most aspects, a typical H5 chondrite, except the unusually low K content of ～340 ppm. A cosmic ray exposure of 9.7 Ma is inferred from the cosmogenic noble gas records. Activities of eleven cosmogenic radionuclides were measured. ²⁶Al and ²²Na activities as well as the ²²Na/²⁶Al activity ratio are close to the values expected on the basis of solar modulation of galactic cosmic rays. The low ⁶⁰Co activity (<1 dpm/kg) is indicative of a small preatmospheric size of the meteorite. Cosmic ray heavy nuclei track densities in olivine grains range from ～106 cm^?2 in samples from the largest fragment to approximately (4–9) × 105 cm^?2 in one of the smaller fragments. The combined track, radionuclide, and noble gas data suggest a preatmospheric radius of ～20 cm for the Dergaon meteorite.