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81.
The distribution and geochemical composition of suspended-particulate matter (SPM) in the East China Sea (ECS) were investigated
during the summer period of high continental runoff to elucidate SPM sources, distribution and cross-shelf transport. The
spatial variability of SPM distribution (0.3–6.5 mg l−1) and geochemical composition (POC, Al, Si, Fe, Mn, Ca, Mg and K) in the ECS was pronounced during summer when the continental
fluxes of freshwater and terrestrial materials were highest during the year. Under the influences of Changjiang runoff, Kuroshio
intrusion, surface production and bottom resuspension, the distribution generally showed strong gradients decreasing seaward
for both biogenic and lithogenic materials. Particulate organic carbon was enriched in surface water (mean ∼18%) due to the
influence of biological productivity, and was diluted by resuspended and/or laterally-transported materials in bottom water
(mean 9.4%). The abundance of lithogenic elements (Al, Si, Fe, Mn) increased toward the bottom, and the distribution correlations
were highly significant. Particulate CaCO3 distribution provided evidence that the SPM of the bottom water in the northern part of the study area was likely mixed with
sediments originally derived from Huanghe. A distinct benthic nepheloid layer (BNL) was present in all seaward transects of
the ECS shelf. Sediment resuspension may be caused by tidal fluctuation and other forcing and be regarded as the principal
agent in the formation of BNL. This BNL was likely responsible for the transport of biogenic and lithogenic particles across
or along the ECS shelf. Total inventories of SPM, POC and PN are 46, 2.8 and 0.4 Tg, respectively, measured over the total
area of 0.45 × 106 km2 of the ECS shelf. Their mean residence times are about 27, 13 and 11 days, respectively. The inventory of SPM in the water
column was higher in the northernmost and southernmost transects and lower in the middle transects, reflecting the influences
of terrestrial inputs from Changjiang and/or resuspended materials from Huanghe deposits in the north and perhaps from Minjiang
and/or Taiwan’s rivers in the south. The distribution and transport patterns of SPM and geochemical elements strongly indicate
that continental sources and cross-shelf transport modulate ECS particulate matter in summer. 相似文献
82.
The Magellan seamounts began forming as large submarine shield volcanoes south of the equator during the Cretaceous. These
volcanoes formed as a cluster on the small Pacific plate in a period when tectonic stress was absent. Thermal subsidence of
the seafloor led to sinking of these volcanoes and the formation of guyots as the seamounts crossed the equatorial South Pacific
(10–0°S) sequentially and ocean surface temperatures became too high for calcareous organisms to survive. Guyot formation
was completed between about 59 and 45 Ma and the guyots became phosphatized at about 39–34 and 27–21 Ma. Ferromanganese crusts
began formation as proto-crusts on the seamounts and guyots of the Magellan Seamount cluster towards the end of the Cretaceous
up to 55 Ma after the formation of the seamounts themselves. The chemical composition of these crusts evolved over time in
a series of steps in response to changes in global climate and ocean circulation. The great thickness of these crusts (up
to 15–20 cm) reflects their very long period of growth. The high Co contents of the outer parts of the crusts are a consequence
of the increasing deep circulation of the ocean and the resulting deepening of the oxygen minimum zone with time. Growth of
the Co-rich Mn crusts in the Magellan Seamount cluster can be considered to be the culmination of a long journey through time. 相似文献
83.
Ryoko Tokeshi Kaoru Ichikawa Satoshi Fujii Kenji Sato Shoichiro Kojima 《Journal of Oceanography》2007,63(4):711-720
A method to extract geostrophic current in the daily mean HF radar data in the Kuroshio upstream region is established by
comparison with geostrophic velocity determined from the along-track altimetry data. The estimated Ekman current in the HF
velocity is 1.2% (1.5%) and 48° (38°)-clockwise rotated with respect to the daily mean wind in (outside) the Kuroshio. Furthermore,
additional temporal smoothing is found necessary to remove residual ageostrophic currents such as the inertial oscillation.
After removal of the ageostrophic components, the HF geostrophic velocity agrees well with that from the altimetry data with
rms difference 0.14 (0.12) m/s in (outside) the Kuroshio. 相似文献
84.
The origin and biogeochemistry of organic matter in surface sediments of Lake Shihwa and Lake Hwaong
To understand the origin and biogeochemistry of the organic matter in surface sediments of Lake Shihwa and Lake Hwaong, organic
nitrogen, inorganic nitrogen, labile organic carbon, and residual organic carbon contents as well as stable isotope ratios
for carbon and nitrogen were determined by KOBr-KOH treatment. Ratios of organic carbon to organic nitrogen (Corg/Norg) (mean = 24) were much higher than ratios of organic carbon to total nitrogen (Corg/Ntot) (mean=12), indicating the presence of significant amounts of inorganic nitrogen in the surface sediments of both lakes.
Stable isotope ratios for organic nitrogen were, on average, 5.2‰ heavier than ratios of inorganic nitrogen in Lake Shihwa,
but those same ratios were comparable in Lake Hwaong. This might be due to differences in the origin or the degree of degradation
of sedimentary organic matter between the two lakes. In addition, stable isotope ratios for labile organic carbon were, on
average, 1.4‰ heavier than those for residual organic carbon, reflecting the preferential oxidation of13C-enriched organic matter. The present study demonstrates that KOBr-KOH treatment of sedimentary organic matter can provide
valuable information for understanding the origin and degradation state of organic matter in marine and brackish sediments.
This also suggests that the ratio of Corg/Norg and stable isotope ratios for organic nitrogen can be used as indexes of the degree of degradation of organic matter. 相似文献
85.
Fractal-like adsorption kinetics of Pb^2+ in rocks 总被引:1,自引:0,他引:1
The adsorption kinetics of Pb^2+ in rocks has been studied using ion selective electrodes and atomic absorption spectrophotometer. The results showed that the adsorption process is a fractal-like reaction. The adsorption rate was relatively high before 30 minutes, and then dropped. The saturated adsorption capacity (a) of Pb^2+ and kinetic parameters (b, a, D and k) increased with increasing initial concentrations of Pb^2+. These parameters (except a) decreased while Na^+ was present in the solution. Furthermore, the smaller the rocks were in grain size, the bigger these kinetic parameters would be, though the parameter a was almost constant. 相似文献
86.
FANG Tao LI Daoji YU Lihua LI Yun 《中国地球化学学报》2008,27(2):161-170
We conducted ship-board incubation experiments to investigate changes in nutrient uptake of phytoplankton under different phosphate concentrations and irradiances in the Changjiang River Estuary and its adjacent waters in China. Under 100% natural irradiance the uptake rates of phosphate, silicate, and nitrate were accelerated at high phosphate levels (1.84 μM), while under low irradiance (about 50% natural irradiance) their uptake rates were restrained at the high but stimulated greatly at the intermediate phosphate concentrations (1.26 μM), as the growth of phytoplankton, changes in nitrite and ammonium uptake didn't follow an obvious pattern. Our results also showed that there were linear relationships between nitrate, silicate and phosphate uptake at different phosphate concentrations under low and high irradiances, and the growth period of phytoplankton was prolonged both at the high phosphate concentrations under high irradiance and at the intermediate concentrations under low irradiance, suggesting that the limitation of phytoplankton growth mainly reflected changes in its growth period, and because no such environment (low irradiance and low phosphate concentrations) actually existed in a high turbidity zone, phytoplankton blooms hardly occurred there. In the absence of irradiance, denitrification occurred readily and phytoplankton was kept decreasing, which resulted in phosphate regeneration. 相似文献
87.
Xin Li Dongliang Wang Baoquan Liu Chunling Ren Jianying Guo Xuefeng Su Jian Wang 《中国地球化学学报》2008,27(4):412-419
The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation. 相似文献
88.
K. S. Rao Y. S. Rao H. K. Al Jassar 《Journal of the Indian Society of Remote Sensing》2008,36(2):123-136
Spaceborne Imaging Radar (SIR-C) data acquired over Gujarat, India in 1994 were processed and analysed using differnet techniques
applicable to polarimetric SAR data such as polarization signatures, polarization index, decomposition of the signal and polarization
phase difference and limited groundtruth data. It has been observed that multi-frequency polarimetric data enhances the potential
of retrieving geo-physical parameters. The polarization signatures are found to vary with the nature of the target. Target
decomposition of the returned signal will be useful for the classification of various features. Polarization Phase Difference
(PPD) gives good information about the vegetation parameters. 相似文献
89.
The Bayesian detection of discontinuities in a polynomial regression and its application to the cycle-slip problem 总被引:4,自引:1,他引:3
Maria Clara de Lacy Mirko Reguzzoni Fernando Sansò Giovanna Venuti 《Journal of Geodesy》2008,82(9):527-542
This paper deals with the problem of detecting and correcting cycle-slips in Global Navigation Satellite System (GNSS) phase
data by exploiting the Bayesian theory. The method is here applied to undifferenced observations, because repairing cycle-slips
already at this stage could be a useful pre-processing tool, especially for a network of permanent GNSS stations. If a dual
frequency receiver is available, the cycle-slips can be easily detected by combining two phase observations or phase and range
observations from a single satellite to a single receiver. These combinations, expressed in a distance unit form, are completely
free from the geometry and depend only on the ionospheric effect, on the electronic biases and on the initial integer ambiguities;
since these terms are expected to be smooth in time, at least in a short period, a cycle-slip in one or both the two carriers
can be modelled as a discontinuity in a polynomial regression. The proposed method consists in applying the Bayesian theory
to compute the marginal posterior distribution of the discontinuity epoch and to detect it as a maximum a posteriori (MAP)
in a very accurate way. Concerning the cycle-slip correction, a couple of simultaneous integer slips in the two carriers is
chosen by maximazing the conditional posterior distribution of the discontinuity amplitude given the detected epoch. Numerical
experiments on simulated and real data show that the discontinuities with an amplitude 2 or 3 times larger than the noise
standard deviation are successfully identified. This means that the Bayesian approach is able to detect and correct cycle-slips
using undifferenced GNSS observations even if the slip occurs by one cycle. A comparison with the scientific software BERNESE
5.0 confirms the good performance of the proposed method, especially when data sampled at high frequency (e.g. every 1 s or
every 5 s) are available. 相似文献
90.