A tephrostratigraphic record for the last glacial–interglacial cycle from Lake Ohrid,Albania and Macedonia

Here we present a tephrostratigraphic record (core Co1202) recovered from the northeastern part of Lake Ohrid (Republics of Macedonia and Albania) reaching back to Marine Isotope Stage (MIS) 6. Overall ten horizons (OT0702‐1 to OT0702‐10) containing volcanic tephra have been recognised throughout the 14.94 m long sediment succession. Four tephra layers were visible at macroscopic inspection (OT0702‐4, OT0702‐6, OT0702‐8 and OT0702‐9), while the remaining six are cryptotephras (OT0702‐1, OT0702‐2, OT0702‐3, OT0702‐5, OT0702‐7 and OT0702‐10) identified from peaks in K, Zr and Sr intensities, magnetic susceptibility measurements, and washing and sieving of the sediments. Glass shards of tephra layers and cryptotephras were analysed with respect to their major element composition, and correlated to explosive eruptions of Italian volcanoes. The stratigraphy and the major element composition of tephra layers and cryptotephras allowed the correlation of OT0702‐1 to AD 472 or AD 512 eruptions of Somma‐Vesuvius, OT0702‐2 to the FL eruption of Mount Etna, OT0702‐3 to the Mercato from Somma‐Vesuvius, OT0702‐4 to SMP1‐e/Y‐3 eruption from the Campi Flegrei caldera, OT0702‐5 to the Codola eruption (Somma‐Vesuvius or Campi Flegrei), OT0702‐6 to the Campanian Ignimbrite/Y‐5 from the Campi Flegrei caldera, OT0702‐7 to the Green Tuff/Y‐6 eruption from Pantelleria Island, OT0702‐8 to the X‐5 eruption probably originating from the Campi Flegrei caldera, OT0702‐9 to the X‐6 eruption of generic Campanian origin, and OT0702‐10 to the P‐11 eruption from Pantelleria Island. The fairly well‐known ages of these tephra layers and parent eruptions provide new data on the dispersal and deposition of these tephras and, furthermore, allow the establishment of a chronological framework for core Co1202 for a first interpretation of major sedimentological changes. Copyright © 2009 John Wiley & Sons, Ltd.     

A multiproxy record of late Holocene natural and anthropogenic environmental change from the Sphagnum peat bog Dürres Maar,Germany: implications for quantitative climate reconstructions based on pollen

Pollen data are well established for quantitative climate reconstructions over long timescales, including the Holocene and older interglacials. However, anthropogenically induced environmental change in central Europe was strong during the last 4 ka, challenging quantitative reconstructions of this time period. Here we present quantitative climate reconstructions based on pollen analyses and evaluate them with the peat humification record and the stable carbon isotopes of Sphagnum plant material (δ¹³C_cellulose). All analyses were carried out on the same 7.5 m long, largely ombrotrophic peat bog section from Dürres Maar. Three different methods were used for the quantitative climate reconstructions on the basis of the pollen data: (1) a probabilistic indicator taxa approach (the ‘pdf method’); (2) a modern analogue technique based on pollen taxa from modern surface samples (cMAT); and (3) a modern analogue technique expanded by plant functional types (pMAT). At Dürres Maar the peat humification is only affected by peat cutting during the Roman period and the Middle Ages. The stable carbon isotopes are seemingly unaffected by human impact. Thus both proxies provide independent data to evaluate the reconstructions on the basis of pollen data. The quantitative climate reconstructions on the basis of the individual methods are in general relatively similar. Nevertheless, distinct differences between the individual approaches are also apparent, which could be attributed to taxa that reflect human impact on a local to regional scale. While the pdf method appears to be relatively robust to all observed anthropogenically induced vegetation changes, it potentially underestimates climate variability. This method is therefore expected to be independent of local site characteristics and to provide robust quantitative estimates of climatic trends rather than of climatic variability of small amplitude. This is of value for palaeoclimate reconstructions of older interglacials, for which neither multiple sites nor independent climate proxies are available for comparison. Copyright © 2009 John Wiley & Sons, Ltd.     

Fractures,hydrothermal alterations and permeability in the Soultz Enhanced Geothermal System

Borehole studies of the Soultz-sous-Forêts granite are dedicated to deep geothermics. The hydraulic properties of the reservoir are mainly controlled by the occurrence of some altered cataclastic shear zones showing a low natural permeability characterized by the occurrence of brines. Those zones show a fracture cluster organisation with sealed fractures of various types (post-filled joints, sheared fractures, veins). The main hydrothermal deposits observed within the permeable zones are geodic quartz, carbonates, illite and more locally sulphides. The fracture wall–rocks are intensely transformed: dissolution of igneous minerals, crystallization of new minerals, porosity and permeability increase. It is important to characterize the newly-formed minerals in order to choose the reagents used to improve the permeability of the exchanger by chemical stimulations. This article represents a synthesis of the studies completed by the authors between 1990 and 2008 on the fracture networks, hydrothermal alterations and mineral crystallizations they induced and data about the flow pathways in the exchanger.     

Fast numerical method for growth and retreat of subsurface ice on Mars

Subsurface water ice on Mars evolves due to exchange of vapor with the atmosphere, in the form of loss of ice to the atmosphere or in the form of the growth of interstitial ice. Described here is an accelerated numerical method for the long-term evolution of subsurface ice. This accelerated method is five orders of magnitude faster than explicit vapor transport calculations, enabling fundamentally new types of climate models. Its speed matches that of purely thermal models. The speedup is achieved primarily by solving time-averaged equations for vapor transport and ice volume change. Processes incorporated are growth of interstitial pore ice, retreat of pore ice, retreat of an ice sheet, and retreat of pore ice due to geothermal heating from below. Two example applications illustrate this numerical method’s capabilities. Near the permafrost margin at 55° latitude, ice is periodically depleted and slowly recharged, leading to a pore ice layer estimated to be currently no more than a few meters thick. At the Phoenix Landing Site, it shows the formation of a three layered structure, whereby the layer of pore ice can be very thin.     

Fractionation of rare-earth elements in plants during experimental growth in varied clay substrates

The distribution and content of rare-earth elements (REEs) were determined in two radish species, the cultivated Raphanus sativus and the wild Raphanus raphanistrum, that were grown under laboratory-controlled conditions, in three substrates consisting of illite for one and two smectite substrates for the others, with the two smectite substrates being characterised by different porosities. The plants were split into leaves and stems + roots for analysis. The results indicate that both species take up systematically higher amounts of REEs when grown in the illite substrate, even considering that the smectite equivalent contains about three times more REEs. The REE uptake is also more plant species than mineral composition dependent: R. raphanistrum takes up 3.5–6.7 times more REEs than R. sativus, depending on the substrate, its porosity and the considered plant segments. Increased substrate porosity favours the take up of the REEs, but no specific uptake is observed in leaves relative to that in the combined stems and roots. The transfer of the REEs from minerals to plant organs does not appear to induce systematically identical patterns: (1) in the case of R. sativus, a positive Eu anomaly is visible in all patterns from both segment groups grown in both substrates. When grown in illite, the heavy REEs are also enriched in the stems and roots, which has not been observed in any other organ or in the other substrate and (2) in the case of R. raphanistrum, a very significant positive Gd anomaly, which is not expected to fractionate relative to the other REEs as do Ce and Eu, is observed in all segments of the plants grown in both substrates. A slight negative Ce anomaly is also visible in some of the REE patterns, suggesting some changes in the oxidation–reduction conditions in the substrates near the roots during plant growth. The comparison of the REE patterns from leaves relative to those of the roots + stems shows that those of R. raphanistrum grown in illite provide a spectrum that is very specific with significant deficits in La, Ce, Gd, Tm, Yb and Lu in the leaves. In the other cases, the patterns do not outline significant differences except for R. sativus grown in illite, in which the leaves are enriched in light and medium REEs from La to Gd relative to the stems + roots.     

A heat flow and physical properties package for the surface of Mercury

European Space Agencies fifth cornerstone mission BepiColombo includes a ‘Surface Element’ to land a scientific payload on the surface of Mercury. The current strawman payload includes a heat flow and physical properties package (HP³), focussing on key thermal and mechanical properties of the near-surface material (down to a depth of 2–5 m) and the measurement of heat flow from Mercury's interior, an important constraining parameter for models of the planet's interior and evolution. We present here an overview of the HP³ experiment package and its possible accommodation in a self-inserting ‘mole’ device. A mole is considered to be the most appropriate deployment method for HP³, at least in the currently-assumed case of an airbag-assisted soft landing architecture for the Mercury Surface Element.