Application of electrical imaging to leachate plume evolution studies under in-situ and model conditions

Electrical imaging (resistivity tomography) is increasingly used as a geophysical exploration technique in contaminated land research. The present work demonstrates the efficiency of electrical imaging in monitoring pollution plume evolution under both in-situ and model conditions. The in-situ campaign was done at an unlined landfill site situated in the city of Patras, Hellas. A partially saturated zone of alluvial fan deposits underlies the site, which retards leachate percolation to the underlying water table. Electrical imaging provided details of the internal structure of the waste tip, and confirmed the presence of a leachate plume beneath the base of the landfill. This field data component provided the constraints for the design of a generic model of contaminant infiltration into partially saturated sand. The aim was to study leachate plume evolution in a laboratory environment. For this purpose, a miniaturised resistivity tomography technique, developed at Cardiff University, was used to image the resistivity distribution before during and after contaminant infiltration. Comparison of resulting two-dimensional tomography with observed plume geometry at the end of the test showed the miniaturised electrical imaging technique to be highly effective. Experiment showed that contaminant evolution taking place in the model was gravity-driven, with capillary water in the vadose zone being displaced by the denser contaminant solution.     

Topography-adjusted solar radiation indices and their importance in hydrology

Abstract

Solar radiation, direct and diffuse, is affected by surface characteristics, such as slope, aspect, altitude and shading. The paper examines the effects of topography on radiation, at multiple spatiotemporal scales, using suitable geometric methods for the direct and diffuse components. Two indices are introduced for comparing the direct radiation received by areas at the same and different latitudes. To investigate the profile of direct radiation across the whole of Greece, these are evaluated from an hourly to annual basis, via GIS techniques. Moreover, different approaches are examined for estimating the actual global radiation at operational spatial scales (sub-basin and terrain), according to the available meteorological data. The study indicates that the errors of typical hydrometeorological modelling formulas, which ignore the topographic effects and the seasonal allocation of direct and diffuse radiation, depend on the spatial scale and are non-uniformly distributed in time. In all cases, the estimations are improved by applying the proposed adjustment approaches. In particular, the adjustment of the measured global radiation ensures up to 10% increase of efficiency, while the modified Angström formula achieves slight (i.e. 2–4%) increase of efficiency and notable reduction of bias.

Editor Z.W. Kundzewicz

Citation Mamassis, N., Efstratiadis, A. and Apostolidou, I.-G., 2012. Topography-adjusted solar radiation indices and their importance in hydrology. Hydrological Sciences Journal, 57 (4), 756–775.     

Isotope Geochemistry of the Pb-Zn-Ba(-Ag-Au) Mineralization at Triades-Galana,Milos Island,Greece

The Pb-Zn-Ba(-Ag-Au) mineralization in the Triades and Galana mine areas is hosted in 2.5–1.4 Ma pyroclastic rocks, and structurally controlled mostly by NE-SW or N-S trending brittle faults. Proximal pervasive silica and distal pervasive sericite-illite alteration are the two main alteration types present at the surface. The distribution of mineralization-alteration in the district suggests at least two hydrothermal events or that hydrothermal activity lasted longer at Galana. The Sr isotope signature of sphalerite and barite (⁸⁷Sr/⁸⁶Sr = 0.709162 to 0.710214) and calculated oxygen isotope composition of a fluid in equilibrium with barite and associated quartz at temperatures of around 230°C are suggestive of a seawater hydrothermal system and fluid/rock interaction. Lead isotope ratios of galena and sphalerite (²⁰⁶Pb/²⁰⁴Pb from 18.8384 to 18.8711; ²⁰⁷Pb/²⁰⁴Pb from 15.6695 to 15.6976; ²⁰⁸Pb/²⁰⁴Pb from 38.9158 to 39.0161) are similar to those of South Aegean Arc volcanic and Aegean Miocene plutonic rocks, and compatible with Pb derived from an igneous source. Galena and sphalerite from Triades-Galana have δ³⁴S_VCDT values ranging from +1 to +3.6‰, whereas barite sulfate shows δ³⁴S_VCDT values from +22.8 to +24.4‰. The sulfur isotope signatures of these minerals are explained by seawater sulfate reduction processes. The new analytical data are consistent with a seawater-dominated hydrothermal system and interaction of the hydrothermal fluid with the country rocks, which are the source of the ore metals.     

Geology and Origin of Supergene Ore at the Lavrion Pb-Ag-Zn Deposit, Attica, Greece

The Lavrion carbonate-hosted Pb-Ag-Zn deposit in southeast Attica, Greece, consisted of significant non-sulfide ore bodies. The polymetallic sulfide mineralization was subjected to supergene oxidation, giving rise to gossan. The principal non-sulfide minerals of past economic importance were smithsonite, goethite and hematite. The supergene mineral assemblages occupy secondary open spaces and occur as replacement pods within marble. Calamine and iron ore mainly filled open fractures. X-ray diffraction and scanning electron microscopy of samples of oxidized ore indicate complex gossan mineralogy depending on the hypogene mineralogy, the degree of oxidation and leaching of elements, and the local hydrologic conditions. Bulk chemical analysis of the samples indicated high ore-grade variability of the supergene mineralization. On multivariate cluster analysis of geochemical data the elements were classified into groups providing evidence for their differential mobilization during dissolution, transport and re-precipitation. The mode of occurrence, textures, mineralogy and geochemistry of the non-sulfide mineralization confirm that it is undoubtedly of supergene origin: the product of influx into open fractures in the country rock of highly acidic, metal-rich water resulting from the oxidation of pyrite-rich sulfide protore. Dissolution of carbonates led to opening of the fractures. Mineral deposition in the supergene ore took place under near-neutral to mildly acidic conditions. The supergene dissolution and re-precipitation of Fe and Zn in the host marble increased metal grades and separated iron and zinc from lead, thereby producing economically attractive deposits; it further contributed to minimization of pollution impact on both soil and ground water.     

The West Spitsbergen Fold Belt: The result of Late Cretaceous-Palaeocene Greenland-Svalbard convergence?

The West Spitsbergen Fold Belt, together with the Eurekan structures of northern Greenland and Ellesmere Island, are suggested to be the result of Late Cretaceous-Palaeocene intracontinental compressional tectonics. The Late Palaeozoic –Mesozoic rocks of western Spitsbergen are characterized by near-foreland deformation with ramp-flat, top-to-the east thrust trajectories, whereas structurally higher nappes involving Caledonian complexes are typified by more listric thrusts and mylonite zones. A minimum of 40 km of shortening is estimated for the northern part of the West Spitsbergen Fold Belt. The axial trends in the West Spitsbergen and the North Greenland Eurekan fold belts parallel the principal fault zones which accommodated the separation of Greenland and Svalbard after Chron 25/24. In northern Greenland, north directed Eurekan thrusts associated with mylonites and cleavage formation represent at least 10 km of shortening. Between 50 and 100 km of shortening is estimated for the markedly arcuate Eurekan Fold Belt of Ellesmere Island, but the principal tectonic transport is eastwards. Kinematic reconstructions suggest that Svalbard was linked to North America before the opening of the Eurasian Basin and Norwegian — Greenland Sea. In the Late Cretaceous — Palaeocene interval, the relative motion between Greenland and North America was convergent across the Greenland — Svalbard margin, giving rise to the West Spitsbergen Fold Belt and the Eurekan structures of North Greenland.