A numerical approach to the design parameters of permanent stoppings (seals and bulkheads) in Turkish underground coal mines

Observing permanent seals with different physical and mechanical characteristics under various conditions in the field is almost impossible. In conjunction with the development of high-speed computer algorithms, numerical simulation has become one of the major means to study the dynamics of such problems. Therefore, this study covers only the numerical approach to analyze the stability of underground seals. In this regard, the purpose of this study is to provide an insight to the design of underground seals by numerically analyzing their behaviors under different static and dynamic explosion overpressures using a geo-technical commercial software FLAC3D. For this purpose, a series of numerical models were constructed for a typical seal in an underground gallery with different properties such as seal thickness, seal dimensions, gallery geometry, and strength of the seal material to investigate the stability of seals exposed to various static and dynamic explosion overpressures. A total of 896 numerical analyses (512 static and 384 dynamic) were performed and evaluated. Regarding the gallery geometry, it was found that seals constructed in trapeze-shaped galleries are more stable than those constructed in horseshoe-shaped galleries having the same dimensions. Moreover, the results showed that the seal stability increases with the increasing seal thickness rather than the strength of the seal material. The statistical analyses suggest that there is a very strong exponential relationship between the seal thickness and the maximum displacement measured at the midpoints of the outer surfaces of the seals. The coefficients of determination values obtained are in the range of 0.92–0.93 and 0.92–0.95 for static and dynamic analyses, respectively. We proposed formulas which use the longer dimension of the seal (W _max ), maximum allowable displacement on the seal (D _max ), explosion overpressure applied onto the seal (P _exp ), and compressive strength of the seal material (σ _c and σ _cd for static and dynamic conditions, respectively) to predict the minimum required seal thickness (T _s ) for static and dynamic conditions. The proposed formulas enable calculating the necessary seal thickness easily if the explosion overpressure (or hydrostatic pressure) is known or approximated.     

Water quality and hydrogeochemical characteristics of the River Buyukmelen,Duzce, Turkey

The River Buyukmelen is located in the province of Duzce in northwest Turkey and its water basin is approximately 470 km². The Aksu, Kucukmelen and Ugursuyu streams flow into the River Buyukmelen. It flows into the Black Sea with an output of 44 m³ s⁻¹. The geological succession in the basin comprises limestone and dolomitic limestone of the Yılanlı formation, sandstone, clayey limestone and marls of the Akveren formation, clastics and volcano‐clastics of the Caycuma formation, and cover units comprised of river alluvium, lacutrine sediments and beach sands. The River Buyukmelen is expected to be a water source that can supply the drinking water needs of Istanbul until 2040; therefore, it is imperative that its water quality be preserved. The samples of rock, soil, stream water, suspended, bed and stream sediments and beach sand were collected from the Buyukmelen river basin. They were examined using mineralogical and geochemical methods. The chemical constituents most commonly found in the stream waters are Na⁺, Mg²⁺, SO²⁻₄, Cl⁻ and HCO₃⁻ in the Guz stream water, Ca²⁺ in the Abaza stream water, and K⁺ in the Kuplu stream water. The concentrations of Na⁺, K⁺, Ca²⁺, Mg²⁺, SO²⁻₄, HCO⁻₃, Cl⁻, As, Pb, Ni, Mn, Cr, Zn, Fe and U in the Kuplu and Guz stream waters were much higher than the world average values. The Dilaver, Gubi, Tepekoy, Maden, Celik and Abaza streams interact with sedimentary rocks, and the Kuplu and Guz streams interact with volcanic rocks. The amount of suspended sediment in the River Buyukmelen in December 2002 was 120 mg l⁻¹. The suspended and bed sediments in the muddy stream waters are formed of quartz, calcite, plagioclase, clay (kaolinite, illite and smectite), muscovite and amphibole minerals. As, Co, Cd, Cr, Pb, Ni, Zn and U have all accumulated in the Buyukmelen river‐bed sediments. The muddy feature of the waters is related to the petrographic features of the rocks in the basin and their mineralogical compositions, as most of the sandstones and volcanic rocks (basalt, tuffite and agglomerate) are decomposed to a clay‐rich composition at the surface. Thus, the suspended sediment in stream waters increases by physical weathering of the rocks and water–rock interaction. Owing to the growing population and industrialization, water demand is increasing. The plan is to bring water from the River Buyukmelen to Istanbul's drinking‐water reservoirs. According to the Water Pollution Regulations, the River Buyukmelen belongs to quality class 1 based on Hg, Cd, Pb, As, Cu, Cr, Zn, Mn, Se, Ba, Na⁺, Cl⁻, and SO²⁻₄; and to quality class 3 based on Fe concentration. The concentration of Fe in the River Buyukmelen exceeds the limit values permitted by the World Health Organization and the Turkish Standard. Because water from the River Buyukmelen will be used as drinking water, it will have an adverse effect on water quality and humans if not treated in advance. In addition, the inclusion of Mn and Zn in the Elmali drinking‐water reservoir of Istanbul and Fe in the River Buyukmelen water indicates natural inorganic contamination. Mn, Zn and Fe contents in the waters are related to geological origin. Moreover, the River Buyukmelen flow is very muddy in the rainy seasons and it is inevitable that this will pose problems during the purification process. Copyright © 2005 John Wiley & Sons, Ltd.     

Intermediate sulfidation epithermal gold-base metal deposits in Tertiary subaerial volcanic rocks,Sahinli/Tespih Dere (Lapseki/Western Turkey)

Gold in the Sahinli and Tespih Dere intermediate sulfidation gold-base metal deposits in Western Turkey occurs in relatively deep epithermal quartz veins along with base metal minerals which have epithermal textures, including plumose quartz, vug infills, comb and cockade textures and matrix-supported milled breccias. The total sulfide content of the veins in the area is variable ranging from < 1% to 60% and is dominated by pyrite, galena, sphalerite and chalcopyrite. Sphalerite is Fe-poor (0.6 to 1.4 mol% FeS). Minor amounts of Ag-rich tetrahedrite are present. Primary hydrothermal alteration minerals include illite/muscovite, mixed-layer illite/smectite (11.6 Å) and clinochlore towards the east and, alunite, dickite/nacrite and pyrophyllite towards the west at Sahinli; major illite/muscovite and dickite occur at Tespih Dere and Sarioluk, respectively.Fluid inclusions in main-stage quartz at Sahinli are only liquid-rich, with homogenization temperatures ranging from 220 to 322 °C and the majority of T_h values between 250 and 300 °C. Salinity ranges from 4.3 to 6.9 wt.% NaCl equiv. First ice-melting temperatures (T_mf) between ?24.5 and ?19.0 °C indicate that the fluids were dominated by NaCl – H₂O during mineralization. The relatively higher average T_h at the Tespih Dere deposit (295 °C) is attributed to a relatively deeper level of exposure.Calculated δ¹⁸O values indicate that ore-forming hydrothermal fluids in the study area had δ¹⁸O_H2O ranging from + 1.1 to + 9.7‰ (average = 3.8‰), strongly ¹⁸O-enriched compared with present-day hydrothermal meteoric water in the area (δ¹⁸O = ?8.5‰). δD values of fluid inclusions in quartz range from ?58 to ?93‰ and δD values of clay minerals and alunite from ?40 to ?119‰. δD values from intermediate argillic alteration (average = ?68‰) in the study area are very similar to δD values of the present-day local geothermal system (average δD = ?54‰) whereas δD values from advanced-argillic alteration (average δD = ?33‰) are very different from the present-day local geothermal system.The δ³⁴S values in samples from the Sahinli and Tespih Dere deposits average ?2.9‰ for pyrite; ?3.3‰ for chalcopyrite; ?5.4‰ for sphalerite and ?7.6‰ for galena. These data are consistent with derivation of the sulfur from either igneous rocks or possibly from local wallrock.     

Some exact solutions of string cosmology with heat flux in Bianchi type III space-time

In this paper, the Einstein field equations have been solved for a cloud of string with heat flux in Bianchi type III space-time. The physical and geometrical properties of the model have been examined.     

Dissolved Nutrient Distributions in Groundwater in the Mediterranean Coastal Plains – the Case of Silifke,Turkey

Total carbon, nitrogen, and phosphate parameters were studied for the first time in the groundwater in the Silifke coastal plain, which is a RAMSAR site in Turkey. Seasonal variations of these parameters in the plain were examined based on groundwater data collected from 21 wells during the winter, spring, summer, and fall seasons. Total dissolved organic carbon (DOC), inorganic carbon (DIC), inorganic phosphate (DIP), inorganic nitrogen (DIN), and total alkalinity (TAlk) average values in the groundwater were low in all seasons (<2.2 mg/L for DOC; <54 mg/L for DIC; <0.06 mg/L for DIP; <1.5 mg/L for DIN; <232 mg/L for TAlk). The results showed a strong relationship between DIC and as expected. The results indicate that the content of these parameters in the groundwater of Silifke coastal plain pose no or little risk at present. However, computed Langelier Saturation Index (LSI) values indicated that the groundwater has a tendency to form scale and CaCO₃ precipitation may occur.     

Earthquake fault rupture—shallow foundation interaction in undrained soils: a simplified analytical approach

The interaction between normal or reverse fault ruptures and shallow foundations resting on a homogeneous undrained soil layer is investigated. After performing a thorough set of non‐linear finite element simulations, three simple kinematic mechanisms are proposed to predict the conditions for the fault rupture to be diverted by the foundation. The results obtained by both numerical and analytical approaches are in good agreement, and support the adequacy of the proposed mechanisms. A relationship is established for assessing the minimum foundation bearing load needed for diversion of the fault rupture trace, either normal or reverse. This relationship is proved to be independent of the fault type and dip angle, so that it can be applied easily for engineering applications, even in the absence of specific tectonic information. Copyright © 2006 John Wiley & Sons, Ltd.     

Heat contamination in groundwater sourced from heat pump for heating in Bratislava (Slovakia)’s historic centre

The aim of the study is to evaluate the warming effect (thermal contamination) of city centres with high building density. This phenomenon has a number of scientific and practical implications. The case study was conducted in Bratislava (Slovakia), in the geological environment of alluvial gravels of the Danube River, where a permanent warming of the subsurface in the city centre is experienced, which is mainly affected by high building density and underground utilities. Thanks to this thermal contamination, the heat pumps efficiency is greater in winter, while in summer, their effectiveness is lower. Economically, this negative phenomenon in the case of heat pumps has a positive effect, since it increases energy efficiency during the heating period. This phenomenon is not universal and depends on the specific boundary conditions of the geological settings and hydrogeological conditions.     

Testing Simplified Beerkan Infiltration (SBI) Methods on Technosol to Estimate the Saturated Hydraulic Conductivity

Geotechnical and Geological Engineering - The development of infiltration techniques has facilitated the estimation of soils hydraulic properties. Among these, the simplified Beerkan infiltration...     

Single and binary adsorption of lead and cadmium ions from aqueous solution using the clay mineral beidellite

Beidellite, a low-cost, locally available and natural mineral was used as an adsorbent for the removal of lead and cadmium ions from aqueous solutions in batch experiments. The kinetics of adsorption process was tested for the pseudo first-order, pseudo second-order reaction and intra-particle diffusion models. The rate constants of adsorption for all these kinetic models were calculated. Comparison amongst the models showed that the sorption kinetics was best described by the pseudo second-order model. Langmuir and Freundlich isotherm models were applied to the experimental equilibrium data for different temperatures. The adsorption capacities (Q°) of beidellite for lead and cadmium ions were calculated from the Langmuir isotherm. It was found that adsorption capacity was in the range of 83.3–86.9 for lead and 42–45.6 mg/g for cadmium at different temperatures. Thermodynamic studies showed that the metal uptake reaction by beidellite was endothermic in nature. Binary metal adsorption studies were also conducted to investigate the interactions and competitive effects in binary adsorption process. Based on the optimum parameters found, beidellite can be used as adsorbent for metal removal processes.     

New evidence and solution to the Maden complex controversy of the Southeast Anatolian orogenic belt (Turkey)

The volcanosedimentary units of Late Mesozoic-Tertiary age that outcrop in the Southeast Anatolian orogenic belt are commonly referred to as the Maden complex. There is a long-lasting controversy over its definition, age, stratigraphic and structural position, and the origin, and thus, the orogenic evolution. To solve this problem, large strips across the Southeast Anatolian orogenic belt have been studied extensively, and different rock groups which were regarded previously as the Maden unit have been differentiated. Their major characteristics and differences have been identified. The Maden unit sensu stricto is here redefined as a volcanosedimentary succession of Middle Eocene age representing a short-lived back-arc basin which reached the stage of an embryonic ocean. Presently, the Maden group occurs mainly within the lower nappe stack of the nappe zone of the Southeast Anatolian orogen. It rests stratigraphically on an amalgamated nappe package consisting of the different metamorphic tectonic units and, in turn, is overlain tectonically by the upper nappe units.