Experimental impact cratering: A summary of the major results of the MEMIN research unit

This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.     

Spectroscopic analysis (FTIR, Raman) of water in mafic and intermediate glasses and glass inclusions

Micro-Raman spectroscopy, even though a very promising technique, is not still routinely applied to analyse H₂O in silicate glasses. The accuracy of Raman water determinations critically depends on the capability to predict and take into account both the matrix effects (bulk glass composition) and the analytical conditions on band intensities. On the other hand, micro-Fourier transform infrared spectroscopy is commonly used to measure the hydrous absorbing species (e.g., hydroxyl OH⁻ and molecular H₂O) in natural glasses, but requires critical assumptions for the study of crystal-hosted glasses. Here, we quantify for the first time the matrix effect of Raman external calibration procedures for the quantification of the total H₂O content (H₂O_T = OH⁻ + H₂O_m) in natural silicate glasses. The procedures are based on the calibration of either the absolute (external calibration) or scaled (parameterisation) intensity of the 3550 cm⁻¹ band. A total of 67 mafic (basanite, basalt) and intermediate (andesite) glasses hosted in olivines, having between 0.2 and 4.8 wt% of H₂O, was analysed. Our new dataset demonstrates, for given water content, the height (intensity) of Raman H₂O_T band depends on glass density, reflectance and water environment. Hence this matrix effect must be considered in the quantification of H₂O by Raman spectroscopy irrespective of the procedure, whereas the parameterisation mainly helps to predict and verify the self-consistency of the Raman results. In addition, to validate the capability of the micro-Raman to accurately determine the H₂O content of multicomponent aluminosilicate glasses, a subset of 23 glasses was analysed by both micro-Raman and micro-FTIR spectroscopy using the band at 3550 cm⁻¹. We provide new FTIR absorptivity coefficients (ε₃₅₅₀) for basalt (62.80 ± 0.8 L mol⁻¹ cm⁻¹) and basanite (43.96 ± 0.6 L mol⁻¹ cm⁻¹). These values, together with an exhaustive review of literature data, confirm the non-linear decline of the FTIR absorptivity coefficient (ε₃₅₅₀) as the glass depolymerisation increases. We demonstrate the good agreement between micro-FTIR and micro-Raman determination of H₂O in silicate glasses when the matrix effects are properly considered.     

On the absence of critical levels in the solar atmosphere

We consider the propagation of linear oscillations in a stratified atmosphere permeated by an oblique but nearly horizontal uniform magnetic field. Our results do not show any of the strong characteristics associated with critical level singularities in the exactly horizontal field case. This suggests that critical levels may be of more mathematical interest than physical relevance in the solar atmosphere where the planar horizontal field approximation is seldom adequate.Currently a Nuffield Foundation Science Research Fellow.     

Modeling Nonprofit Resilience in Long-Term Recovery in Christchurch,New Zealand

Following the 2010–2011 earthquakes in Christchurch, New Zealand, many nonprofit organizations changed or expanded services to address emergent or compounded risks. This research is based on interviews with thirty local community nonprofit managers and discussions with five staff focus groups conducted in 2014. Preexisting nonprofits with flexible organizational structures and emergent nonprofits succeeded in providing services during the emergency response and early recovery phases; nonprofits contracted with the government were better suited for long-term recovery. Shared resources among nonprofit agency connections contributed to successful transitions from response to recovery. Similar organizational resilience factors might occur in other major cities following disasters.     

Effects of Recent Instability on Cultivated Area Along the Euphrates River in Iraq

We used MODIS NDVI data to determine whether there was a significant change in cultivated area along the Euphrates River in Iraq after the Iraq War compared to before and during the war. Results revealed that mean cultivated area was largest during the pre–Iraq War period (2000–2003) with 99,115 Mha, reduced some during the early Iraq War period (2003–2006) to 83,480 Mha, reduced even further during the late Iraq War period (2007–2011) to 53,813 Mha due to drought, and increased slightly during the post–Iraq War period (2012–2015) to 69,161 Mha, although not returning to previous highs of the pre–Iraq War or early Iraq War periods. Statistical analysis with the Kruskal–Wallis test revealed that the small cultivated area during the post–Iraq War period was more closely related to the late Iraq War and drought period than previous periods, indicating that recent instability, such as political turmoil following the departure of U.S. troops, violent militant extremism, lack of economic investment, and environmental degradation, has had a similar effect on cultivated area as a devastating drought.     

A simple derivation of capture probabilities for the J+1:J and J+2:J orbit-orbit resonance problems

We present a simplified analytic derivation of the capture probabilities for the j+1j and j+2j orbital resonances. We apply Henrard's method which is based on an extension of the theory of adiabatic invariants and recover the results originally obtained by Yoder.Contribution number 3874 from the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, U.S.A.     

Does martian soil release reactive halogens to the atmosphere?

Detailed statistical examination of Cl, Br, and S distributions, in martian soil profiles at Gusev Crater and Meridiani Planum, indicates decreasing Br abundance and weakening Br–S association towards the surface. All three elements decrease towards the surface in the order Cl < S < Br. Furthermore, Br variability decouples from potential cations such as Mg at the surface relative to the subsurface. These observations support a relative loss of surficial Br compared to S and Cl, all highly mobile elements in aqueous environments. We propose that Br may have converted preferentially to gas phases (e.g., BrO), driven either by UV photolysis or by chemical oxidants. Such volatilization pathways may in turn impart a global signature on Mars by acting as controls on oxidants such as ozone and perchlorates. S/Cl mass ratios vary with depth (∼4–5 in the subsurface; 1.8–3.6 on the surface) as well, with a strong correlation of S and Cl near the surface but more variable at depth, consistent with differential vertical mobility, but not volatilization of Cl. Elevated S/Cl in subsurface soil also suggests that the ratio may be higher in bulk soil – a key repository of martian geologic and climatic records – than previously thought.     

Hydrogeological and hydrochemical characterization of two karstic discharge areas in San Luis Potosí, Mexico

Two karstic discharge areas, Río Verde (RV) and Ciénega de Cabezas (CC), located in a distance of 80 km to each other are chosen to determine the influence of local variations in geology and climatic condition on water chemistry and to examine if the groundwater, supplying the discharge areas, undergoes the same evolution and has a common source. Both study areas are situated on the carbonate platform Valles-San Luis Potosí and comprise a similar geological setting, but despite of their spatial vicinity the climate is semiarid in RV and humid in CC presenting an important factor on the amount of discharge and the concentrations of ions in the discharge. The investigation encompasses discharge, hydrochemical and physico-chemical parameter evaluations as well as the determination of saturation indices, hydrochemical modelling and water type characterization of surface water samples to derive knowledge of the groundwater systems. Scatterplots and saturation indices were used to proof the influence of lithological variability. Both study areas represent normal alkaline water, marked by high concentrations of calcium and magnesium with varying concentrations of bicarbonate and sulphate. In RV, the water interacts with dolomite rocks and gypsum layers, whereas in CC the dolomite content is depleted and the influence of limestone rocks increases. The climatic impact on the groundwater in RV is noticeable by the increase in ionic concentrations due to higher evaporation. In CC the higher amount of precipitation dilutes the groundwater and causes decreasing ionic concentrations.     

A phytoplankton class-specific primary production model applied to the Kerguelen Islands region (Southern Ocean)

As part of the KErguelen: compared study of the Ocean and the Plateau in Surface water (KEOPS) project in late summer 2005, we examine the phytoplankton community composition and associated primary production in the waters surrounding the Kerguelen Archipelago, with the emphasis on two contrasted environments: (i) the Kerguelen Plateau, where a large bloom occurs annually, and (ii) the high-nutrient low-chlorophyll (HNLC) offshore waters. A biomarker pigment approach was used to assess the community composition in terms of chlorophyll biomass of three phytoplankton size classes, namely micro-, nano-, and picophytoplankton. The second objective was to evaluate a global class-specific approach for estimating the contribution of the three pigment-based size classes to the primary production in the study area. To do so, primary production rates associated with each phytoplankton class were computed from the class-specific chlorophyll biomass coupled to a class-specific primary production model, and compared with in situ measurements of size-fractionated ¹³C-based primary production. The iron-enriched bloom region was dominated by microphytoplankton (diatoms), which contributed 80–90% to the total primary production (of ≈1 g C m^?2 d^?1). In the HNLC area, the primary production was about 0.30 g C m^?2 d^?1, mainly (65%) achieved by small diatoms and nanoflagellates. The model results show a good overall agreement between predicted and measured total primary production rates. In terms of size classes, agreements were higher for the bloom region than for the HNLC waters. Discrepancies in this complex iron-limited area may be explained essentially by the smaller size of diatoms, or a different set of photophysiological properties.     

Imaging DOAS for volcanological applications

The simultaneous quantitative determination of two-dimensional bromine monoxide (BrO) and sulphur dioxide (SO₂) distributions in volcanic gas plumes is described. Measurements at the fumarolic field on the island Vulcano (autumn 2004) and in the plume of Mt. Etna volcano (spring 2005) were carried out with an Imaging DOAS instrument. The SO₂ fluxes of several fumaroles were estimated from two-dimensional distributions of SO₂. Additionally, the first two-dimensional distributions of BrO within a volcanic plume were successfully retrieved. Slant column densities of up to 2.6 × 10¹⁴ molecules per square centimetre were detected in the plume of Mt. Etna. The investigation of the BrO/SO₂ ratio, calculated from the two-dimensional distributions of SO₂ and BrO, shows an increase from the centre to the edge of the volcanic plume. These results have significance for the involvement of ozone during BrO formation processes in volcanic emissions.