Wet-oxidation and automated colorimetry for simultaneous determination of organic carbon, nitrogen and phosphorus dissolved in seawater

We developed a simple and reliable method which allows simultaneous determination of organic forms of carbon (DOC), nitrogen (DON) and phosphorus (DOP) dissolved in seawater. Conversion of dissolved organic matter (DOM) to inorganic products (carbon dioxide, nitrate+nitrite and soluble reactive phosphate) is performed by a persulfate wet-oxidation in low alkaline condition. After oxidation, the concentration of the inorganic products dissolved in the sample was measured automatically by colorimetry using a 3-channel Technicon AutoAnalyzer system. A number of pure organic compounds were tested in the concentration range encountered in coastal and open ocean, indicating a high efficiency of the digestion procedure. The recovery range is similar to that obtained by other wet-oxidation procedures and by high-temperature catalytic oxidation techniques. Direct comparisons with usual methods used for separate determination of DOC, DON and DOP indicated a high efficiency of the procedure. Reproducibility tests demonstrated a very good precision (around 5%) for lagoonal and coastal waters, while precision was sometimes around 10–25% in oligotrophic oceanic waters, especially for DOP where values approached limits of detection for measuring phosphate. This method is highly suitable for routine analysis and especially appropriate for shipboard work.     

Hydrological resilience to forest fire in the subarctic Canadian shield

Understanding the role of forest fires on water budgets of subarctic Precambrian Shield catchments is important because of growing evidence that fire activity is increasing. Most research has focused on assessing impacts on individual landscape units, so it is unclear how changes manifest at the catchment scale enough to alter water budgets. The objective of this study was to determine the water budget impact of a forest fire that partially burned a ~450 km² subarctic Precambrian Shield basin. Water budget components were measured in a pair of catchments: one burnt and another unburnt. Burnt and unburnt areas had comparable net radiation, but thaw was deeper in burned areas. There were deeper snow packs in burns. Differences in streamflow between the catchments were within measurement uncertainty. Enhanced winter streamflow from the burned watershed was evident by icing growth at the streamflow gauge location, which was not observed in the unburned catchment. Wintertime water chemistry was also clearly elevated in dissolved organics, and organic-associated nutrients. Application of a framework to assess hydrological resilience of watersheds to wildfire reveal that watersheds with both high bedrock and open water fractions are more resilient to hydrological change after fire in the subarctic shield, and resilience decreases with increasingly climatically wet conditions. This suggests significant changes in runoff magnitude, timing and water chemistry of many Shield catchments following wildfire depend on pre-fire land cover distribution, the extent of the wildfire and climatic conditions that follow the fire.