Groundwater quality and rural drinking-water supplies in the Republic of Moldova

 This paper describes the results of a groundwater quality assessment conducted in two pilot areas, Balatina and Carpineni, in the Republic of Moldova. Shallow groundwater is the main source of drinking water in rural areas, but reliable data on its quality are currently insufficient for developing rural water-supply systems with standard designs. The main components of the study included a field sampling program (including pesticides), an evaluation of the reliability of existing drinking-water data, an analysis of land use and groundwater-pollution risks using GIS, and the formulation of recommendations to reduce risks for public health. Microbiological, nitrate, and selenium contamination are most serious in the villages. These contaminants should be given priority in addressing drinking-water aspects for rural water-supply development in the two pilot areas. Pollution occurs mainly due to poor sanitary conditions. In a few shallow wells, traces of selected pesticides were observed, but the effect of these levels of pesticides on public health is still unclear. Limited resources of shallow groundwater of good quality occur outside the villages. Additional pilot studies should be implemented to prove the technical and institutional feasibility of developing and protecting these resources. Received, September 1997 Revised, September 1998 Accepted, March 1999     

Calcareous algae bioclast contribution to sediment enrichment by arsenic on the Brazilian subtropical coast

Arsenic levels (up to 130 mg kg⁻¹) substantially exceeding the official threshold have recently been documented in beach and nearshore sediments along more than 50 km of coastline in the Brazilian state of Espírito Santo between 19°50′ and 20°12′S. In an attempt to assess the sources of this enrichment, we performed a study on arsenic distribution in the main mineral substances and living organisms in the beach environment. Laboratory tests on arsenic retention by beach carbonate debris have also been carried out. The data suggest that sedimentary arsenic occurs largely bound to particles of the calcareous red alga Corallina panizzoi, whereby live specimens contained much smaller amounts of this metalloid than was the case for nonliving material (2.4 and 20.3 mg kg⁻¹, respectively). Experimental tests confirmed the ability of C. panizzoi detritus to retain arsenic at pH intervals and ionic strength characteristic of seawater. There are two potential sources of that metalloid for calcareous debris in sediments: brown macroalgae, which were found to contain high levels of As (up to 66.3 mg kg⁻¹), and ferruginized sandstones (up to 23.0 mg kg⁻¹). We argue that any contribution of brown algae to beach sediment enrichment by As would be minor, and consider the ferrous sandstones from coastal sedimentary rocks of the Barreiras Group as the principal large-scale source of arsenic in the marine environment of Espírito Santo. The experimental data, together with field studies, corroborate the interpretation that arsenic anomalies in sediments with calcareous debris can form when weathered continental rocks even only slightly enriched in As are leached by marine waters, and the As is at least partially retained by biogenic calcareous detritus in nearshore sediments. Considering that rocks of the Barreiras Group are exposed to marine erosion far to the north of Espírito Santo, we estimate that marine sediments containing calcareous material are “anomalously” enriched in As along approximately 2,000 km of the Brazilian tropical coastline.     

On M-Theory

This contribution gives a personal view on recent attempts to find a unified framework for non-perturbative string theories, with special emphasis on the hidden symmetries of supergravity and their possible role in this endeavor. A reformulation ofd = 11 supergravity with enlarged tangent space symmetry SO(1, 2) × SO(16) is discussed from this perspective, as well as an ansatz to construct yet further versions with SO(1, 1) × SO(16)^∞ and possibly even SO(1, 1)₊ × ISO(16)^∞ tangent space symmetry. It is suggested that upon “third quantization”, dimensionally reduced maximal supergravity may have an equally important role to play in this unification as the dimensionally reduced maximally supersymmetricSU(∞) Yang Mills theory.     

Stability issues of the continuous welded rail track on the concrete sleepers on the curves with radius R ≤ 300 m

This paper describes the economic and technological benefits of installing continuous welded rail(CWR) track on sharp(radius ≤ 300 m) railway curves. A new form of prestressed concrete sleepers developed by the V. Lazaryan Dnipropetrovsk National University of Railway Transport is shown to improve the lateral shift resistance of CWR track in sharp curves and the use of anchor sleepers on tangents is shown to make it possible to lower the fastening temperature of the CWR track in order to increase the rail lifespan.     

Reconnaissance survey of the Duolun ring structure in Inner Mongolia: Not an impact structure

The Duolun basin, which is located in Inner Mongolia, China, has been proposed to be an impact structure with an apparent rim diameter of about 70, or even 170 km. The designation as an impact structure was based on its nearly circular topography, consisting of an annular moat that surrounds an inner hummocky region, and the widespread occurrences of various igneous rocks, polymict breccias, and deformed crustal rocks. Critical shock metamorphic evidence is not available to support the impact hypothesis. We conducted two independent reconnaissance field surveys to this area and studied the lithology both within and outside of the ring structure. We collected samples from all lithologies that might contain evidence of shock metamorphism as suggested by their locations, especially those sharing similar appearances with impact breccias, suevites, impact melt rocks, and shatter cones. Field investigation, together with thin‐section examination, discovered that the suspected impact melt rocks are actually Early Cretaceous and Late Jurassic lava flows and pyroclastic deposits of rhyolitic to trachytic compositions, and the interpreted impact glass is typical volcanic glass. Petrographic analyses of all the samples reveal no indications for shock metamorphic overprint. All these lines of evidence suggest that the Duolun basin was not formed through impact cratering. The structural deformation and spatial distribution pattern of the igneous rocks suggest that the Duolun basin is most likely a Jurassic–Cretaceous complex rhyolite caldera system that has been partly filled with sediments forming an annular basin, followed by resurgent doming of the central area.     

Effects of Bioirrigation and Salinity on Arsenic Distributions in Ferruginous Concretions from Salt Marsh Sediment Cores (Southern Brazil)

Arsenic (As), iron (Fe), and manganese (Mn) contents were measured in sediment nodules and associated pore waters obtained from sediment cores collected from a salt marsh on Pólvora Island (southern Brazil). Sediment cores were obtained when brackish water dominated the estuary, at two different environments: an unvegetated mudflat colonized by crabs (Neohelice granulata), and a low intertidal stand vegetated by Spartina alterniflora. We determined the percentage of nodules in each depth interval of the cores, along with redox potential, and As, Fe, and Mn contents of the nodules. The mineralogy of the nodules was investigated, and results showed they are mainly composed by quartz, phyllosilicates, and amorphous Fe–Mn oxides/oxyhydroxides. Pore water results showed that bioturbation by local crabs supports oxygen penetration to depths of ca. 25 cm below the salt marsh surface, with lower Fe contents in pore water associated with the brackish period. However, S. alterniflora growth appears to have a greater impact on sediment geochemistry of Fe, Mn, and possibly As due to sulfate reduction and the associated decrease in pore water pH. Higher Fe concentrations were observed in the pore waters during the period of brackish water dominance, which also corresponded to the S. alterniflora growth season. The study demonstrates that differences in geochemical conditions (e.g., Fe content) that can develop in salt marsh sediments owing to different types of bioirrigation processes (i.e., bioirrigation driven by crabs versus that related to the growth of S. alterniflora) play important roles in the biogeochemical cycling of As.

     

Evaluation of deep crustal earthquakes in northern Germany – Possible tectonic causes

We present new evidence for seven deep crustal, intraplate earthquakes in northern Germany, a region regarded as an area of low seismicity. From 2000 to 2018, seven earthquakes with magnitudes of M_L 1.3–3.1, were detected at depths of 17.0–31.4 km. By placing the earthquake hypocentres in a geological three‐dimensional model, we can correlate two of the earthquakes with the Thor Suture, a major fault zone in this area. Five of the earthquakes group in the lower crust near the Moho, which implies that parts of the lower crust and the crust/mantle boundary in northern Germany act as a structural discontinuity on which deformation localizes. Numerical simulation implies that stress changes due to glacial isostatic adjustment most likely triggered these deep crustal earthquakes.