Strontium in coral aragonite: 2. Sr coordination and the long-term stability of coral environmental records

We have used X-ray Diffraction (XRD) and Sr K-edge Extended X-ray Absorption Fine Structure (EXAFS) to determine the structural state of Sr in a suite of coral aragonite samples. Our samples encompassed a selection of coral species (Porites lobata, Porites lutea, Pocillopora eydouxi, Montastrea annularis, Pavona gigantea and Pavona clavus) including some commonly used for palaeoenvironmental reconstruction. Aragonite was the only carbonate observed by XRD. We refined the isolated EXAFS against structural models for Sr in aragonite and two-phase strontianite/aragonite mixes. Our data are indistinguishable from Sr ideally substituted in aragonite and strontianite was present below detection levels (estimated at <5% of Sr present). Comparisons of recent and ancient coral aragonite show no sign of exsolution, either by spinodal decomposition or by the direct nucleation of strontianite domains. Published diffusion rates of Sr in ionic solids support the view that exsolution would occur prohibitively slowly. Coral aragonites are metastable materials with slow diffusion kinetics that have the potential to encode environments over timescales of millions of years.     

Stability at high-pressure,elastic behaviour and pressure-induced structural evolution of CsAlSi<Subscript>5</Subscript>O<Subscript>12</Subscript>, a potential host for nuclear waste

The elastic and structural behaviour of the synthetic zeolite CsAlSi₅O₁₂ (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V ₀ = 1,155(4) ų, K _T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a ³, b ³, c ³) for the volume. The refined axial-EoS parameters are: a ₀ = 16.701(44) Å, K _T0a = 14(2) GPa (β_a = 0.024(3) GPa^?1), K′ _a = 6.2(8) for the a-axis; b ₀ = 13.778(20) Å, K _T0b = 21(3) GPa (β_b = 0.016(2) GPa^?1), K′ _b = 10(2) for the b-axis; c ₀ = 5.018(7) Å, K _T0c = 33(3) GPa (β_c = 0.010(1) GPa^?1), K′ _c = 3.2(8) for the c-axis (K _T0a:K _T0b:K _T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi₅O_12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi₅O₁₂ allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes.     

Structural evolution of a 2M 1 phengite mica up to 11 GPa: an in situ single-crystal X-ray diffraction study

The structural evolution at high pressure of a natural 2M ₁-phengite [(K_0.98Na_0.02)_Σ=1.00(Al_1.55Mg_0.24Fe_0.21Ti_0.02)_Σ=2.01(Si_3.38Al_0.62)O₁₀(OH)₂; a = 5.228(2), b = 9.057(3), c = 19.971(6)Å, β = 95.76(2)°; space group: C2/c] from the metamorphic complex of Cima Pal (Sesia Zone, Western Alps, Italy) was studied by single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions up to ~11 GPa. A series of 12 structure refinements were performed at selected pressures within the P range investigated. The compressional behaviour of the same phengite sample was previously studied up to ~25 GPa by synchrotron X-ray powder diffraction, showing an irreversible transformation with a drastic decrease of the crystallinity at P > 15–17 GPa. The elastic behaviour between 0.0001 and 17 GPa was modelled by a third-order Birch–Murnaghan Equation of State (BM-EoS), yielding to K _T0 = 57.3(10) GPa and K′ = ?K _T0/?P = 6.97(24). The single-crystal structure refinements showed that the significant elastic anisotropy of the 2M ₁-phengite (with β(a):β(b):β(c) = 1:1.17:4.60) is mainly controlled by the anisotropic compression of the K-polyhedra. The evolution of the volume of the inter-layer K-polyhedron as a function of P shows a negative slope, Fitting the P–V(K-polyhedron) data with a truncated second-order BM-EoS we obtain a bulk modulus value of K _T0(K-polyhedron) = 26(1) GPa. Tetrahedra and octahedra are significantly stiffer than the K-polyhedron. Tetrahedra behave as quasi-rigid units within the P range investigated. In contrast, a monotonic decrease is observed for the octahedron volume, with K _T0 = 120(10) GPa derived by a BM-EoS. The anisotropic response to pressure of the K-polyhedron affects the P-induced deformation mechanism on the tetrahedral sheet, consisting in a cooperative rotation of the tetrahedra and producing a significant ditrigonalization of the six-membered rings. The volume of the K-polyhedron and the value of the ditrigonal rotation parameter (α) show a high negative correlation (about 93%), though a slight discontinuity is observed at P >8 GPa. α increases linearly with P up to 7–8 GPa (with ?α/?P ≈ 0.7°/GPa), whereas at higher Ps a “saturation plateau” is visible. A comparison between the main deformation mechanisms as a function of pressure observed in 2M ₁- and 3T-phengite is discussed.     

Development and Pull-through of Climate Science to Services in China

正1.Introduction The impacts arising from climate change and climate variability pose major challenges to global and regional security and economic prosperity(UNFCCC,2015).Some regions are more at risk than others,through heightened exposure to climatic hazards,and high vulnerability and exposure to such hazards.China,with its rapid economic development,large     

Analysis of climatic trends in data from the agrometeorological station of Bologna-Cadriano, Italy (1952–2007)

Agriculture is highly exposed to climate change, as farming activities directly depend on climatic conditions. Knowledge of the extent of such change and of related phenomena will help to answer the questions posed by society about adaptation strategies. The global situation is well described by the Fourth IPCC assessment report (IPCC 2007), but local studies are important to understand the impact and the priorities to adopt in adaptation strategies. In this study a historical set of meteorological data, collected during the period 1952–2007 at the University of Bologna (Italy) agrometeorological station, was analysed. Several indexes, such as Frost Severity Index, number of hot days, number of rainy days, etc., were calculated, and their trends in time were analysed. The results show a scenario of increasing temperatures and evapotranspiration, a decrease in rainy days and a deepening of the watertable. The effect of these changes on agriculture will be a decrease in water availability, an increase in heat stress in plants and an increase in drought risk.     

Water‐bottom multiple attenuation by Kirchhoff extrapolation

Despite being less general than 3D surface‐related multiple elimination (3D‐SRME), multiple prediction based on wavefield extrapolation can still be of interest, because it is less CPU and I/O demanding than 3D‐SRME and moreover it does not require any prior data regularization. Here we propose a fast implementation of water‐bottom multiple prediction that uses the Kirchhoff formulation of wavefield extrapolation. With wavefield extrapolation multiple prediction is usually obtained through the cascade of two extrapolation steps. Actually by applying the Fermat’s principle (i.e., minimum reflection traveltime) we show that the cascade of two operators can be replaced by a single approximated extrapolation step. The approximation holds as long as the water bottom is not too complex. Indeed the proposed approach has proved to work well on synthetic and field data when the water bottom is such that wavefront triplications are negligible, as happens in many practical situations.     

Assessment of a monumental masonry bell-tower after 2016 Central Italy seismic sequence by long-term SHM

The response of the San Pietro monumental bell-tower located in Perugia, Italy, to the 2016 Central Italy seismic sequence is investigated, taking advantage of the availability of field data recorded by a vibration-based SHM system installed in December 2014 to detect earthquake-induced damages. The tower is located about 85 km in the NW direction from the epicenter of the first major shock of the sequence, the Accumoli Mw6.0 earthquake of August 24th, resulting in a small local PGA of about 30 cm/s², whereby near-field PGA was measured as 915.97 cm/s² (E–W component) and 445.59 cm/s² (N–S component). Similar PGA values also characterized the two other major shocks of the sequence (Ussita Mw5.9 and Norcia Mw6.5 earthquakes of October 26th and 30th, respectively). Despite the relatively low intensity of such earthquakes in Perugia, the analysis of long-term monitoring data clearly highlights that small permanent changes in the structural behavior of the bell-tower have occurred after the earthquakes, with decreases in all identified natural frequencies. Such natural frequency decays are fully consistent with what predicted by non-linear finite element simulations and, in particular, with the development of microcracks at the base of the columns of the belfry. Microcracks in these regions, and in the rest of tower, are however hardly distinguishable from pre-existing ones and from the physiological cracking of a masonry structure, what validates the effectiveness of the SHM system in detecting earthquake-induced damage at a stage where this is not yet detectable by visual inspections.     

Long-Term RST Analysis of Anomalous TIR Sequences in Relation with Earthquakes Occurred in Greece in the Period 2004–2013

Real-time integration of multi-parametric observations is expected to accelerate the process toward improved, and operationally more effective, systems for time-Dependent Assessment of Seismic Hazard (t-DASH) and earthquake short-term (from days to weeks) forecast. However, a very preliminary step in this direction is the identification of those parameters (chemical, physical, biological, etc.) whose anomalous variations can be, to some extent, associated with the complex process of preparation for major earthquakes. In this paper one of these parameters (the Earth’s emitted radiation in the Thermal InfraRed spectral region) is considered for its possible correlation with M ≥ 4 earthquakes occurred in Greece in between 2004 and 2013. The Robust Satellite Technique (RST) data analysis approach and Robust Estimator of TIR Anomalies (RETIRA) index were used to preliminarily define, and then to identify, significant sequences of TIR anomalies (SSTAs) in 10 years (2004–2013) of daily TIR images acquired by the Spinning Enhanced Visible and Infrared Imager on board the Meteosat Second Generation satellite. Taking into account the physical models proposed for justifying the existence of a correlation among TIR anomalies and earthquake occurrences, specific validation rules (in line with the ones used by the Collaboratory for the Study of Earthquake Predictability—CSEP—Project) have been defined to drive a retrospective correlation analysis process. The analysis shows that more than 93 % of all identified SSTAs occur in the prefixed space–time window around (M ≥ 4) earthquake's time and location of occurrence with a false positive rate smaller than 7 %. Molchan error diagram analysis shows that such a correlation is far to be achievable by chance notwithstanding the huge amount of missed events due to frequent space/time data gaps produced by the presence of clouds over the scene. Achieved results, and particularly the very low rate of false positives registered on a so long testing period, seems already sufficient (at least) to qualify TIR anomalies (identified by RST approach and RETIRA index) among the parameters to be considered in the framework of a multi-parametric approach to t-DASH.     

Chlorinated compounds and polybrominated diphenyl ethers (PBDEs) in mussels (Mytilus galloprovincialis) collected from Apulia Region coasts

This project was carried out to assess the levels and spatial distribution of organochlorine compounds in the coastal marine environment, using mussels as bioindicators to evaluate the coastal water quality. Levels of polychlorobiphenils (PCB), chlorinated pesticides (DDT isomers, HCH isomers, Aldrin, Dieldrin, alfa-Endosulfan, Hexachlorobenzene, Pentachlorobenzene) and polybrominated diphenyl ethers (PBDEs) were determined in tissues from mussels (Mytilus galloprovincialis) collected along the Apulia Region coasts (Mediterranean Sea). Results indicate that contamination by organochlorine compounds is higher in mussels sampled in the Ionian Sea than in those from the Adriatic Sea, with PCB levels up to seven times higher in mussels from Ionian than from the Adriatic Sea. Although PCB levels were above the maximum values indicated by both European Community (EC) and National regulation in several sample sites, the PCB concentrations were particularly high in some stations, suggesting that these locations require a much specific attention. Conversely, results on the mussel contamination by PBDEs highlight their ubiquitous environmental distribution, and underline the need to establish the maximum level for these compounds in foodstuff, according to European Regulations.     

Vegetation turnover in a braided river: frequency and effectiveness of floods of different magnitude

This work addresses the temporal dynamics of riparian vegetation in large braided rivers, exploring the relationship between vegetation erosion and flood magnitude. In particular, it investigates the existence of a threshold discharge, or a range of discharges, above which erosion of vegetated patches within the channel occurs. The research was conducted on a 14 km long reach of the Tagliamento River, a braided river in north‐eastern Italy. Ten sets of aerial photographs were used to investigate vegetation dynamics in the period 1954–2011. By using different geographic information system (GIS) procedures, three aspects of geomorphic‐vegetation dynamics and interactions were addressed: (i) long‐term (1954–2011) channel evolution and vegetation dynamics; (ii) the relationship between vegetation erosion/establishment and flow regime; (iii) vegetation turnover, in the period 1986–2011. Results show that vegetation turnover is remarkably rapid in the study reach with 50% of in‐channel vegetation persisting for less than 5–6 years and only 10% of vegetation persisting for more than 18–19 years. The analysis shows that significant vegetation erosion is determined by relatively frequent floods, i.e. floods with a recurrence interval of c. 1–2.5 years, although some differences exist between sub‐reaches with different densities of vegetation cover. These findings suggest that the erosion of riparian vegetation in braided rivers may not be controlled solely by very large floods, as is the case for lower energy gravel‐bed rivers. Besides flow regime, other factors seem to play a significant role for in‐channel vegetation cover over long time spans. In particular, erosion of marginal vegetation, which supplies large wood elements to the channel, increased notably over the study period and was an important factor for in‐channel vegetation trends. Copyright © 2014 John Wiley & Sons, Ltd.