Anomalous behaviour of specific electrical conductivity at a karst spring induced by variable catchment boundaries: the case of the Podstenjšek spring,Slovenia

Anomalous behaviour of specific electrical conductivity (SEC) was observed at a karst spring in Slovenia during 26 high‐flow events in an 18‐month monitoring period. A conceptual model explaining this anomalous SEC variability is presented and reproduced by numerical modelling, and the practical relevance for source protection zoning is discussed. After storm rainfall, discharge increases rapidly, which is typical for karst springs. SEC displays a first maximum during the rising limb of the spring hydrograph, followed by a minimum indicating the arrival of freshly infiltrated water, often confirmed by increased levels of total organic carbon (TOC). The anomalous behaviour starts after this SEC minimum, when SEC rises again and remains elevated during the entire high‐flow period, typically 20–40 µS/cm above the baseflow value. This is explained by variable catchment boundaries: When the water level in the aquifer rises, the catchment expands, incorporating zones of groundwater with higher SEC, caused by higher unsaturated zone thickness and subtle lithologic changes. This conceptual model has been checked by numerical investigations. A generalized finite‐difference model including high‐conductivity cells representing the conduit network (“discrete‐continuum approach”) was set up to simulate the observed behaviour of the karst system. The model reproduces the shifting groundwater divide and the nearly simultaneous increase of discharge and SEC during high‐flow periods. The observed behaviour is relevant for groundwater source protection zoning, which requires reliable delineation of catchment areas. Anomalous behaviour of SEC can point to variable catchment boundaries that can be checked by tracer tests during different hydrologic conditions. Copyright © 2011 John Wiley & Sons, Ltd.     

Global energy security under different climate policies,GDP growth rates and fossil resource availabilities

Energy security is one of the main drivers of energy policies. Understanding energy security implications of long-term scenarios is crucial for informed policy making, especially with respect to transformations of energy systems required to stabilize climate change. This paper evaluates energy security under several global energy scenarios, modeled in the REMIND and WITCH integrated assessment models. The paper examines the effects of long-term climate policies on energy security under different assumptions about GDP growth and fossil fuel availability. It uses a systematic energy security assessment framework and a set of global and regional indicators for risks associated with energy trade and resilience associated with diversity of energy options. The analysis shows that climate policies significantly reduce the risks and increase the resilience of energy systems in the first half of the century. Climate policies also make energy supply, energy mix, and energy trade less dependent upon assumptions of fossil resource availability and GDP growth, and thus more predictable than in the baseline scenarios.     

A new quantitative interpretation of the long-tail and plateau-like breakthrough curves from tracer tests in the artesian karst aquifer of Stuttgart, Germany

In 1998 and 1999, two multi-tracer experiments were conducted in the artesian karst aquifer of the mineral springs of Stuttgart, Germany. The breakthrough curves (BTCs) monitored at the springs showed very long tails or developed plateau-like concentration levels for more than 200 days. Initially, this observation was qualitatively explained by exchange between cavities with stagnant water and the active conduits. Since then, a new analytical solution for tracer transport in karst aquifers has become available, the “two-region non-equilibrium model” (2RNE), which assumes the presence of mobile and immobile fluid regions, and mass transfer between these two regions. The experiments were thus revisited, and it was possible to provide a more quantitative explanation of the observed behaviour. The new model simulated all BTCs very well, thus confirming the earlier qualitative explanation. The prolonged BTCs can be attributed to intermediate storage in cavities containing quasi-immobile groundwater, and slow release into active fractures and conduits. The results also demonstrate that karst aquifers are not always fast-flushing systems, but contaminants can sometimes remain in immobile fluid regions for long periods.     

Olivine or impact melt: Nature of the “Orange” material on Vesta from Dawn

NASA’s Dawn mission observed a great variety of colored terrains on asteroid (4) Vesta during its survey with the Framing Camera (FC). Here we present a detailed study of the orange material on Vesta, which was first observed in color ratio images obtained by the FC and presents a red spectral slope. The orange material deposits can be classified into three types: (a) diffuse ejecta deposited by recent medium-size impact craters (such as Oppia), (b) lobate patches with well-defined edges (nicknamed “pumpkin patches”), and (c) ejecta rays from fresh-looking impact craters. The location of the orange diffuse ejecta from Oppia corresponds to the olivine spot nicknamed “Leslie feature” first identified by Gaffey (Gaffey, M.J. [1997]. Icarus 127, 130–157) from ground-based spectral observations. The distribution of the orange material in the FC mosaic is concentrated on the equatorial region and almost exclusively outside the Rheasilvia basin. Our in-depth analysis of the composition of this material uses complementary observations from FC, the visible and infrared spectrometer (VIR), and the Gamma Ray and Neutron Detector (GRaND). Several possible options for the composition of the orange material are investigated including, cumulate eucrite layer exposed during impact, metal delivered by impactor, olivine–orthopyroxene mixture and impact melt. Based on our analysis, the orange material on Vesta is unlikely to be metal or olivine (originally proposed by Gaffey (Gaffey, M.J. [1997]. Icarus 127, 130–157)). Analysis of the elemental composition of Oppia ejecta blanket with GRaND suggests that its orange material has ∼25% cumulate eucrite component in a howarditic mixture, whereas two other craters with orange material in their ejecta, Octavia and Arruntia, show no sign of cumulate eucrites. Morphology and topography of the orange material in Oppia and Octavia ejecta and orange patches suggests an impact melt origin. A majority of the orange patches appear to be related to the formation of the Rheasilvia basin. Combining the interpretations from the topography, geomorphology, color and spectral parameters, and elemental abundances, the most probable analog for the orange material on Vesta is impact melt.     

Spatial and temporal dynamics of suspended particles and E. coli in a complex surface-water and karst groundwater system as a basis for an adapted water protection scheme,northern Vietnam

Karst aquifers in subtropical regions are characterized by high variability of water availability and quality due to changes associated with rainy and dry seasons. An additional challenge for water management is the combination of surface-water and karst groundwater systems since high spatiotemporal dynamics cause high variability of water quality. In these cases, adapted protection strategies are required. In this study, a protection approach for the catchment of a river-water diversion point in a rural area in northern Vietnam is developed. The variability of water quality was evaluated by rainy and dry season synoptic surveys of suspended particles and microbial contamination at 49 sites and time series at three sets of paired sites under constant hydraulic conditions. The anthropogenic land-use activities in the catchment were mapped to identify potential contamination sources and to highlight the challenging combination of surface-water and karst groundwater management. The analyzed data indicate differences in water quality between the dry and rainy seasons and a higher influence on water quality from land use than from hydrologic conditions. Furthermore, the results suggest a high risk of contamination resulting from residential areas, agriculture, and livestock farming, and reveal the necessity of implementation of appropriate measures such as restricted farming and the hook-up of buildings to municipal sewage disposal. Finally, the data show that water quality can be improved by adjusting water withdrawals by the time of day. The applied methods can be transferred to other surface-water and karst groundwater systems in similar subtropical environments.

     

Review: From multi-scale conceptualization to a classification system for inland groundwater-dependent ecosystems

Aquifers provide water, nutrients and energy with various patterns for many aquatic and terrestrial ecosystems. Groundwater-dependent ecosystems (GDEs) are increasingly recognized for their ecological and socio-economic values. The current knowledge of the processes governing the ecohydrological functioning of inland GDEs is reviewed, in order to assess the key drivers constraining their viability. These processes occur both at the watershed and emergence scale. Recharge patterns, geomorphology, internal geometry and geochemistry of aquifers control water availability and nutritive status of groundwater. The interface structure between the groundwater system and the biocenoses may modify the groundwater features by physicochemical or biological processes, for which biocenoses need to adapt. Four major types of aquifer-GDE interface have been described: springs, surface waters, peatlands and terrestrial ecosystems. The ecological roles of groundwater are conditioned by morphological characteristics for spring GDEs, by the hyporheic zone structure for surface waters, by the organic soil structure and volume for peatland GDEs, and by water-table fluctuation and surface floods in terrestrial GDEs. Based on these considerations, an ecohydrological classification system for GDEs is proposed and applied to Central and Western-Central Europe, as a basis for modeling approaches for GDEs and as a tool for groundwater and landscape management.