Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Piping dynamics in mid‐altitude mountains under a temperate climate: Bieszczady Mountains,eastern Carpathians

Piping has been recognized as an important geomorphic, soil erosion and hydrologic process. It seems that it is far more widespread than it has often been supposed. However, our knowledge about piping dynamics and its quantification currently relies on a limited number of data for mainly loess‐derived areas and marl badlands. Therefore, this research aimed to recognize piping dynamics in mid‐altitude mountains under a temperate climate, where piping occurs in Cambisols, not previously considered as piping‐prone soils. It has been expressed by the estimation of erosion rates due to piping and elongation of pipes in the Bere?nica Wy?na catchment in the Bieszczady Mountains, eastern Carpathians (305 ha, 188 collapsed pipes). The research was based on the monitoring of selected piping systems (1971–1974, 2013–2016). Changes in soil loss vary significantly between different years (up to 27.36 t ha^?1 yr^?1), as well as between the mean short‐term erosion rate (up to 13.10 t ha^?1 yr^?1), and the long‐term (45 years) mean of 1.34 t ha^?1 yr^?1. The elongation of pipes also differs, from no changes to 36 m during one year. The mean total soil loss is 48.8 t ha^?1 in plots, whereas in the whole studied catchment it is 2.0 t ha^?1. Hence, piping is both spatially and temporally dependent. The magnitude of piping in the study area is at least three orders of magnitude higher than surface erosion rates (i.e. sheet and rill erosion) under similar land use (grasslands), and it is comparable to the magnitude of surface soil erosion on arable lands. It means that piping constitutes a significant environmental problem and, wherever it occurs, it is an important, or even the main, sediment source. Copyright © 2017 John Wiley & Sons, Ltd.     

Metal Ion Extraction with Bipyridine Derivatives as Chelating Ligands in Supercritical Carbon Dioxide

Three fluorinated bipyridine ligands have been designed and synthesized as chelating agents for the extraction of metal ions in supercritical CO₂ (sc‐CO₂). The ligand solubilities in sc‐CO₂ were investigated at different temperatures and pressures, and the measured data have been correlated using a semiempirical model. The calculated results showed satisfactory agreement with the experimental data. Based on these data, metal ion extraction with the three compounds as chelating agents in sc‐CO₂ was performed from spiked filter paper, whereby ligand 1 showed the highest extraction efficiency, especially for Ni²⁺ and Cu²⁺. The extraction constants, K_ex, of the three chelating ligands were seen to increase with increasing extraction efficiency for the same metal ion in the same extraction system.     

Normal fault growth influenced by basement fabrics: The importance of preferential nucleation from pre‐existing structures

Reactivation of pre‐existing intra‐basement structures can influence the evolution of rift basins, yet the detailed kinematic relationship between these structures and overlying rift‐related faults remains poorly understood. Understanding the kinematic as well as geometric relationship between intra‐basement structures and rift‐related fault networks is important, with the extension direction in many rifted provinces typically thought to lie normal to fault strike. We here investigate this problem using a borehole‐constrained, 3D seismic reflection dataset from the Taranaki Basin, offshore New Zealand. Excellent imaging of intra‐basement structures and a relatively weakly deformed, stratigraphically simple sedimentary cover allow us to: (a) identify a range of interaction styles between intra‐basement structures and overlying, Plio‐Pleistocene rift‐related normal faults; and (b) examine the cover fault kinematics associated with each interaction style. Some of the normal faults parallel and are physically connected to intra‐basement reflections, which are interpreted as mylonitic reverse faults formed during Mesozoic subduction and basement terrane accretion. These geometric relationships indicate pre‐existing intra‐basement structures locally controlled the position and attitude of Plio‐Pleistocene rift‐related normal faults. However, through detailed 3D kinematic analysis of selected normal faults, we show that: (a) normal faults only nucleated above intra‐basement structures that experienced late Miocene compressional reactivation, (b) despite playing an important role during subsequent rifting, intra‐basement structures have not been significantly extensionally reactivated, and (c) preferential nucleation and propagation of normal faults within late Miocene reverse faults and folds appears to be the key genetic relationship between contractionally reactivated intra‐basement structures and rift‐related normal faults. Our analysis shows that km‐scale, intra‐basement structures can control the nucleation and development of newly formed, rift‐related normal faults, most likely due to a local perturbation of the regional stress field. Because of this, simply inverting fault strike for causal extension direction may be incorrect, especially in provinces where pre‐existing, intra‐basement structures occur. We also show that a detailed kinematic analysis is key to deciphering the temporal as well as simply the spatial or geometric relationship between structures developed at multiple structural levels.     

Environmental factors influencing aggregation of manta rays (Manta birostris) off the northeastern coast of the Yucatan Peninsula

Manta rays inhabit tropical, subtropical and temperate waters. Aggregation sites of manta rays have been recognized worldwide, but the reasons for this behavior are still poorly understood. This study describes environmental factors influencing aggregation sites of the giant manta ray (Manta birostris) off the northeastern coast of the Yucatan Peninsula. Observations of manta rays were obtained from scientific surveys conducted during 2006–2011. Environmental data were obtained from satellite imagery. The maximum entropy (Maxent) method for habitat modeling was used to determine the effects of environmental conditions on the species and predict suitable habitat for manta rays in this region. Primary productivity and distance to the coast were the most influential variables, suggesting that aggregation occurs in highly productive coastal waters. The distribution of manta rays predicted by the Maxent model showed that the most suitable habitat within the study area is located off the northeastern coast of the Yucatán Peninsula, more precisely, northeast of Isla Holbox and northwest of Isla Contoy. Seasonal patterns of distribution suggest that the most suitable conditions are present from July through September.     

A comparison of growth patterns between non‐indigenous Halophila nipponica and the native sympatric Zostera marina on the southern coast of the Korean peninsula

The growth dynamics of two co‐occurring seagrass species, Zostera marina and Halophila nipponica, were examined on the southern coast of the Korean peninsula. Zostera marina is a native dominant seagrass species in Korean coastal waters, whereas H. nipponica is a non‐native tropical and subtropical species that has extended its distributional range to the temperate coastal areas of Korea. To examine the differences in the growth dynamics of H. nipponica and Z.  marina, their morphology, density, productivity and biomass, as well as local environmental conditions, were monitored monthly from January 2008 to July 2009. Underwater irradiance at the study site was the highest in April 2009 and the lowest in January 2008. Water temperature ranged from 10.4°C in January 2009 to 24.8°C in September 2008. Significant differences in growth dynamics were observed between the species, due to the effect of water temperature at the study site. Density and areal productivity were the highest in April 2008 and June 2008, respectively, for Z.  marina but the highest in July 2008 for H. nipponica. Leaf size, shoot height and shoot weight were the highest in July 2008 for Z.  marina but the highest in August 2008 or September 2008 for H. nipponica. The productivity of both species was strongly correlated with water temperature at the study site. However, the productivity of these species was not strongly correlated with underwater irradiance or the nutrient availability of either the water column or sediment pore water. Zostera marina exhibited the ecological characteristics of a temperate seagrass, whereas H. nipponica retained the features of a subtropical/tropical seagrass, even after adapting to the temperate coastal waters of Korea.     

Development of ST:REAM: a reach‐based stream power balance approach for predicting alluvial river channel adjustment

River channel sediment dynamics are important in integrated catchment management because changes in channel morphology resulting from sediment transfer have important implications for many river functions. However, application of existing approaches that account for catchment‐scale sediment dynamics has been limited, largely due to the difficulty in obtaining data necessary to support them. It is within this context that this study develops a new, reach‐based, stream power balance approach for predicting river channel adjustment. The new approach, named ST:REAM (sediment transport: reach equilibrium assessment method), is based upon calculations of unit bed area stream power (ω) derived from remotely sensed slope, width and discharge datasets. ST:REAM applies a zonation algorithm to values of ω that are spaced every 50 m along the catchment network in order to divide the branches of the network up into relatively homogenous reaches. ST:REAM then compares each reach's ω value with the ω of its upstream neighbour in order to predict whether or not the reach is likely to be either erosion dominated or deposition dominated. The paper describes the application of ST:REAM to the River Taff in South Wales, UK. This test study demonstrated that ST:REAM can be rapidly applied using remotely sensed data that are available across many river catchments and that ST:REAM correctly predicted the status of 87.5% of sites within the Taff catchment that field observations had defined as being either erosion or deposition dominated. However, there are currently a number of factors that limit the usefulness of ST:REAM, including inconsistent performance and the need for additional, resource intensive, data to be collected to both calibrate the model and aid interpretation of its results. Copyright © 2014 John Wiley & Sons, Ltd.     

Nonlinear earthquake analysis of high arch dam–water–foundation rock systems

A nonlinear finite element model for earthquake response analysis of arch dam–water–foundation rock systems is proposed in this paper. The model includes dynamic dam–water and dam–foundation rock interactions, the opening of contraction joints, the radiation damping of semi‐unbounded foundation rock, the compressibility of impounded water, and the upstream energy propagating along the semi‐unbounded reservoir. Meanwhile, a new equivalent force scheme is suggested to achieve free‐field input in the model. The effects of the earthquake input mechanism, joint opening, water compressibility, and radiation damping on the earthquake response of the Ertan arch dam (240 m high) in China are investigated using the proposed model. The results show that these factors significantly affect the earthquake response of the Ertan arch dam. Such factors should therefore be considered in the earthquake response analysis and earthquake safety evaluation of high arch dams. Copyright © 2011 John Wiley & Sons, Ltd.     

Glacial flood pulse effects on benthic fauna in equatorial high‐Andean streams

Equatorial glacier‐fed streams present unique hydraulic patterns when compared to glacier‐fed observed in temperate regions as the main variability in discharge occurs on a daily basis. To assess how benthic fauna respond to these specific hydraulic conditions, we investigated the relationships between flow regime, hydraulic conditions (boundary Reynolds number, Re*), and macroinvertebrate communities (taxon richness and abundance) in a tropical glacier‐fed stream located in the high Ecuadorian Andes (> 4000 m). Both physical and biotic variables were measured under four discharge conditions (base‐flow and glacial flood pulses of various intensities), at 30 random points, in two sites whose hydraulic conditions were representative to those found in other streams of the study catchment. While daily glacial flood pulses significantly increased hydraulic stress in the benthic habitats (appearance of Re* > 2000), low stress areas still persisted even during extreme flood events (Re* < 500). In contrast to previous research in temperate glacier‐fed streams, taxon richness and abundance were not significantly affected by changes in hydraulic conditions induced by daily glacial flood pulses. However, we found that a few rare taxa, in particular rare ones, preferentially occurred in highly stressed hydraulic habitats. Monte‐Carlo simulations of benthic communities under glacial flood reduction scenarios predicted that taxon richness would be significantly reduced by the loss of high hydraulic stress habitats following glacier shrinking. This pioneer study on the relationship between hydraulic conditions and benthic diversity in an equatorial glacial stream evidenced unknown effects of climate change on singular yet endangered aquatic systems. Copyright © 2013 John Wiley & Sons, Ltd.     

Vertical amplitude reduction of Rayleigh waves by a row of piles in a poroelastic half‐space

A row of rigid piles is addressed as the countermeasures for isolating Rayleigh waves in a poroelastic half‐space. The complex characteristic equations for Rayleigh waves are derived via Biot's theory and their existence conditions are given. The piles are modeled as Euler–Bernoulli beams with longitudinal displacements and the diffracted field by each pile is constructed only with Rayleigh waves. Six infinite linear systems of algebraic equations are obtained in terms of the equilibrium of forces and continuity of displacements at the pile–soil interfaces. The systems are subsequently solved in the complex least‐squares sense. The influence of certain pile and soil characteristics such as the permeability of poroelastic soil, spacing between the piles and length of the piles on the isolating performance of a pile barrier is investigated. Computed results show that the permeability of poroelastic soil displays a significant effect on the vertical amplitude reduction of Rayleigh waves. Copyright © 2009 John Wiley & Sons, Ltd.