Paragenetic relations in gedrite — cordierite — staurolite — biotite sillimanite — kyanite gneisses at Ajitpura,Rajasthan, India

Aluminous parageneses containing gedrite, cordierite, garnet, staurolite, biotite, sillimanite, kyanite, quartz or spinel plus corundum are found as dark colored lenses in the polymetamorphic, multideformed Archean complex at Ajitpura in northwest peninsular India. Staurolite, like kyanite, is a relict phase of earlier metamorphism and is excluded as a paragenetic mineral in view of its incompatibility with quartz and gedrite and its lower X _Mg values than for garnet of the assemblage. Its stability here is attributed to zinc content of up to 3 wt%. The XMg in other ferromagnesian minerals decreases in the order: cordierite, biotite, gedrite, garnet, as found elsewhere in high grade rocks.The textural criteria and systematic partitioning of Fe and Mg in the ferromagnesian phases, excluding staurolite, indicate attainment of equilibrium during the second metamorphism. From tie line configurations in the phase diagrams, X _Mg ratios in the constituent minerals, and other petrographic criteria, it is suggested that gedrite — cordierite-garnet — sillimanite — biotite assemblage has been produced by the reactions: Biotite+Sillimanite+Quartz = Cordierite+Garnet+K-feldspar+Vapor (1) and Biotite+Sillimanite+Quartz = Cordierite +Gedrite+K-feldspar+Vapor (2) which occurred during partial melting of the rocks at fixed P and T conditions.By isothermal P-X(Fe-Mg) sections it has been demonstrated that release of FeO, SiO₂ and other components modified the composition of the reactant biotite presumably by the substitution FeSi2 Al, whereby reaction 1 was replaced by reaction 2. Cordierite with higher X _Mg was produced with gedrite instead of with garnet, whose X _Mg is less than X _Mg of gedrite. Reaction 2 has been tentatively located in T-P space from the intersection of some continuous loops in the P-X(Fe-Mg) diagram at 700°C and also by other constraints. The discontinuous reaction 2 is located about 1–2 kilobars higher than reaction 1, which implies that it is difficult to distinguish between effects of pressure and those of melting on the X _Mg ratios of the reaction phases.The P-T calibrations of garnet — cordierite, garnet — biotite and garnet — plagioclase equilibria and the calibrations from other dehydration curves give temperatures near 700°C and pressure (assuming ) about 6 kilobars.     

Magnetic polarity stratigraphy of the Upper Siwalik deposits,Pabbi Hills,Pakistan

Over 1000 m of fluvial molasse, exhibiting a stable detrital remanent magnetization, is exposed in a mammal-bearing sequence in the Upper Siwalik Group of the Pabbi Hills, Pakistan. The magnetic polarity chronology reveals that the sequence records a time period of 2.6 m.y., extending from the early Gauss Normal Epoch into the Brunhes Normal Epoch. During this period, sedimentation rates increased upward in time from 0.25 m/1000 yr to 0.45 m/1000 yr. The sudden disappearance of red beds and a change in the lithoclastic composition of basal channel sands suggests that about 800,000 years ago the primary source area began shifting from the metamorphic terrane of the Himalayan Orogen to a more local sedimentary terrane on the folded margins of the Himalayan foredeep. About 500,000 years ago the anticlinal Pabbi Hills attained surface expression. Uplift continued at a minimum rate of 1 m/1000 yr.A local Pliocene/Pleistocene boundary based on the Olduvai Normal Event is clearly recognized. Local fossil finds reveal thatEquus, diagnostic element of the Pinjor faunal zone, appeared locally about 1.8 m.y. ago and thatHipparion, a faunal element of the Tatrot and earlier faunal zones, persisted locally until at least 3.0 m.y. ago.     

40Ar/39Ar age and thermal history of the Kirin chondrite

The Kirin meteorite, a large (2800kg) H5 chondrite, fell in Kirin Province, China in 1976. A sample from each of the two largest fragments (K-1, K-2) yield⁴⁰Ar/³⁹Ar total fusion ages of 3.63 ± 0.02b.y. and 2.78 ± 0.02b.y. respectively.⁴⁰Ar/³⁹Ar age spectra show typical diffusional argon loss profiles. Maximum apparent ages of 4.36 b.y. (K-1) and ～4.0 b.y. (K-2) are interpreted as possible minimum estimates for the age of crystallization of the parent body.The⁴⁰Ar/³⁹Ar ages found for gas released at low temperature are about 2.2 b.y. for K-1 and about 0.5 b.y. for K-2, suggesting that this meteorite may have suffered two discrete collisional events that caused degassing of radiogenic argon. Modelling of possible thermal events in the parent body indicates that samples K-1 and K-2 were at a depth of less than 3 m from the base of an impact melt of a thickness less than 7 m and separated by no more than ～2 m from one another at the time of the heating event about 0.5 b.y. ago. Further, the duration of heating was probably less than a few years.Calculations from³⁸Ar data yield exposure ages for samples K-1 and K-2 of about 5 m.y., similar to that found for many other H chondrites.     

The Early Carboniferous paleomagnetic field of North America and its bearing on tectonics of the Northern Appalachians

We have obtained additional evidence for the Early Carboniferous paleomagnetic field for cratonic North America from study of the Barnett Formation of central Texas. A characteristic magnetization of this unit was isolated after thermal demagnetization at four sites (36 samples) out of eight sites (65 samples) collected. The mean direction of declination = 156.3°, inclination = 5.8° (N = 4 ,k = 905 , α₉₅ = 3.0°), corresponds to a paleomagnetic pole position at lat. = 49.1°N,long. = 119.3°E (dp = 1.5° , dm = 3.0°). Field evidence suggests that characteristic magnetization was acquired very early in the history of the rock unit whereas the rejected sites are comprised of weakly magnetized limestones dominated by secondary components near the present-day field direction. Comparison of the Barnett pole with other Early Carboniferous (Mississippian) paleopoles from North America shows that it lies close to the apparent polar wander path for stable North America and that the divergence of paleopoles from the Northern Appalachians noted previously for the Devonian persisted into the Early Carboniferous. We interpret this difference in paleopoles as further evidence for the Northern Appalachian displaced terrain which we refer to here as Acadia, and the apparent coherence of Late Carboniferous paleopoles as indicating a large (～1500 km) motion of Acadia with respect to stable North America over a rather short time interval in the Carboniferous.     

Rare-gas-rich separates from carbonaceous chondrites

Samples studied were residual, carbonaceous /Alates—a coined word to designate colloids prepared sometimes before and sometimes after acid demineralization—from Murray, Murchison, Cold Bokkeveld (type C2s) and Allende (type CV3) meteorites. Characterization: C2 /Alates, comprising 0.5% of the bulk meteorite are fine-grained (< 100 Å), amorphous, sulfide-free, oxidizable, 95% carbonaceous materials which pyrolyze bimodally at 200–700 and 800–1200°C. Allende /Alates are similar but with traces of inferred spinel and chromite and of sulfur, Rare gas results: Elemental: Release from stepwise heated Murray is bimodal with maximum release and upper temperature peak at 1000°C, probably accompanying chemical reaction. All /Alates studied had very nearly the same elemental concentrations, distinctly planetary in pattern. Isotopic: Trapped neon compositions are unprecedentedly close to Pepin's neon-A corner but nevertheless show signs of complexity, as if accompanied by neon-E. The trapped ³He/⁴He ratio is essentially constant at (1.42 ± 0.2 × 10^?4. The isotopically anomalous heavy noble gases, easily detected in the residues of oxidized /Alates, were not conspicuous in this particular study. Comparison and Chicago results: Concentrations of heavy rare gases in our /Alates agree with concentrations measured directly (as opposed to inferred by difference) in acid resistant residues at Chicago. Alone, our results support the idea of a carbonaceous gas-carrier uniformly present in meteorites of various types, but Chicago characterizations of the samples can apply to both their samples and ours provided that the right amount of gas was lost in the Berkeley procedures to make the uniform gas contents in various samples a coincidence.     

Environmental changes in an alpine lake (Gossenköllesee, austria) over the last two centuries – the influence of air temperature on biological parameters

Changes in microfossils (diatoms, chrysophytes, chironomids and cladocera remains), geochemistry and deposition of atmospheric pollutants have been investigated in the sediment records of the alpine lake Gossenköllesee (Tyrol, Austria) spanning the last two centuries. The sediment records were compared with seasonal and annual air temperature trends calculated for the elevation (2417 m a.s.l.) and the geographical position (47° 1346N, 11° 0051E) of the lake, and with precipitation records available since 1866 from Innsbruck. Temperature trends followed a 20–30 year oscillation between cold and warm periods. Regarding long-term changes, temperature trends showed a U-shaped trend between 1780 and 1950, followed by a steep increase since 1975.Physical, geochemical, and organic parameters were not controlled by air temperature. Among the biological records only diatoms and chrysophytes reacted to air temperature changes: the relative abundance of planktonic diatoms increased during warm periods and changes in mean annual alpine air temperature explained 36.5% of their variation. The relation between abundance of seasonal stomatocyst types and air temperature varied on two different time scales: while summer stomatocysts were influenced by short term temperature fluctuations, the autumn stomatocysts were affected only by the long term changes. Other biological parameters exhibited a constant species composition (chironomids, pigments) or changes were small and independent of temperature (cladocera). Spheroidal carbonaceous fly-ash particles, and trends in Pb and Cr indicated increasing deposition of atmospheric pollutants but had no detectable effects on the biological parameters either. In respect to temperature variations over the last 200 years, this alpine lake is much less sensitive than expected and has thus to be regarded as a well buffered site. However, temperature alone is not sufficient to understand changes in species composition and other biogeochemical processes with unknown historical patterns might have affected species composition more strongly.     

CO2 Mitigation by Agriculture: An Overview

Agriculture currently contributes significantly to the increase of CO2 in the atmosphere, primarily through the conversion of native ecosystems to agricultural uses in the tropics. Yet there are major opportunities for mitigation of CO2 and other greenhouse gas emissions through changes in the use and management of agricultural lands. Agricultural mitigation options can be broadly divided into two categories: (I) strategies to maintain and increase stocks of organic C in soils (and biomass), and (ii) reductions in fossil C consumption, including reduced emissions by the agricultural sector itself and through agricultural production of biofuels to substitute for fossil fuels.Reducing the conversion of new land to agriculture in the tropics could substantially reduce CO2 emissions, but this option faces several difficult issues including population increase, land tenure and other socio-political factors in developing countries. The most significant opportunities for reducing tropical land conversions are in the humid tropics and in tropical wetlands. An important linkage is to improve the productivity and sustainability of existing agricultural lands in these regions.Globally, we estimate potential agricultural CO2 mitigation through soil C sequestration to be 0.4-0.9 Pg C y-1, through better management of existing agricultural soils, restoration of degraded lands, permanent "set-asides" of surplus agricultural lands in temperate developed countries and restoration of 10-20% of former wetlands now being used for agriculture. However, soils have a finite capacity to store additional C and therefore any increases in C stocks following changes in management would be largely realized within 50-100 years.Mitigation potential through reducing direct agricultural emissions is modest, 0.01-0.05 Pg C y-1. However, the potential to offset fossil C consumption through the use of biofuels produced by agriculture is substantial, 0.5-1.6 Pg C y-1, mainly through the production of dedicated biofuel crops with a smaller contribution (0.2-0.3 Pg C y-1) from crop residues.Many agricultural mitigation options represent "win-win" situations, in that there are important side benefits, in addition to CO2 mitigation, that could be achieved, e.g. improved soil fertility with higher soil organic matter, protection of lands poorly suited for permanent agriculture, cost saving for fossil fuel inputs and diversification of agricultural production (e.g. biofuels). However, the needs for global food production and farmer/societal acceptability suggest that mitigation technologies should conform to: (I) the enhancement of agricultural production levels in parts of the world where food production and population demand are in delicate balance and (ii) the accrual of additional benefits to the farmer (e.g., reduced labor, reduced or more efficient use of inputs) and society at large.     

Yandal greenstone belt, Western Australia: 12 million ounces of gold in the 1990s

After a century of virtual neglect, exploration in the Yandal greenstone belt of the Yilgarn Craton of Western Australia has yielded resources of 12 Moz Au during the 1990s. Success has come from a combination of conceptual geological models, surface prospecting, understanding the weathering environment, and systematic drilling. The Archaean Yandal greenstone belt comprises a lowermost banded iron formation, extensive basalt and dolerite sills, ultramafic rocks, intermediate to felsic volcanic rocks, and variable clastic sedimentary rocks. Early shear zones trend NNW and form the greenstone belt margins, or trend N–S within the belt. Later brittle cross-faults are critical in gold localization. Gold resources and past production at major deposits include Bronzewing (4 Moz Au), Jundee (5 Moz) Mt.␣McClure (1 Moz) and Darlot (3␣Moz, some of which was produced before 1990). All major deposits are hosted by Fe-rich mafic rocks, and mineralization displays a combination of different orientations and morphologies. Quartz veins are surrounded by broad carbonate alteration with proximal K-mica and Fe-sulphides. The recognition of a critical role for the late brittle structures in localizing gold implicates mid-crustal processes within the greenstone belt for fluid generation, and with the host rock control, supports the model in which fluid was derived by metamorphic devolatilization. Received: 19 September 1997 / Accepted: 7 January 1998