Geochemical mobility of arsenic in the surficial waters from Argentina

The presence of arsenic (As) in surface water constitutes an important environmental risk, where mobility and adsorption processes are responsible for its behavior in the sediment–water interface. Therefore, the assessment of adsorption, mobility and water availability of arsenic in freshwater sediments, with agricultural, livestock and urban soil uses was performed. Arsenic concentrations in sediments ranged from 5.4 to 15.9 mg kg^?1 (total) and 2.8 to 6.5 mg kg^?1 (labile), and those of iron and manganese were 11,563–23,500 and 140.6–662.1 mg kg^?1, respectively. The As levels in water were significantly lower than those of sediments. Results would suggest that As co-precipitation and adsorption on Fe oxides are probably the major route of immobilization, determining its low lability. Manganese did not present an outstanding contribution to the retention, and cation-exchange capacity, pH and organic matter of sediments did not show an influence on the mobility of As.     

Evaluating uncertainties in regional climate simulations over South America at the seasonal scale

This work focuses on the evaluation of different sources of uncertainty affecting regional climate simulations over South America at the seasonal scale, using the MM5 model. The simulations cover a 3-month period for the austral spring season. Several four-member ensembles were performed in order to quantify the uncertainty due to: the internal variability; the definition of the regional model domain; the choice of physical parameterizations and the selection of physical parameters within a particular cumulus scheme. The uncertainty was measured by means of the spread among individual members of each ensemble during the integration period. Results show that the internal variability, triggered by differences in the initial conditions, represents the lowest level of uncertainty for every variable analyzed. The geographic distribution of the spread among ensemble members depends on the variable: for precipitation and temperature the largest spread is found over tropical South America while for the mean sea level pressure the largest spread is located over the southeastern Atlantic Ocean, where large synoptic-scale activity occurs. Using nudging techniques to ingest the boundary conditions reduces dramatically the internal variability. The uncertainty due to the domain choice displays a similar spatial pattern compared with the internal variability, except for the mean sea level pressure field, though its magnitude is larger all over the model domain for every variable. The largest spread among ensemble members is found for the ensemble in which different combinations of physical parameterizations are selected. The perturbed physics ensemble produces a level of uncertainty slightly larger than the internal variability. This study suggests that no matter what the source of uncertainty is, the geographical distribution of the spread among members of the ensembles is invariant, particularly for precipitation and temperature.     

Linking soil water balance with flood spatial arrangement in an extremely flat landscape

In areas with very mild relief, water drains in a disordered way due to the lack of a developed drainage network, as it occurs in extremely flat sedimentary regions like the Argentine Pampas. The study analysed the flood spatial arrangements in 2014 by calculating landscape metrics and relating them to soil water balance. The study area is located at Del Azul creek lower basin (Pampa Ecoregion, Argentina). Daily soil water balances were obtained, and seven landscape metrics were calculated in 15 windows in five LandSat images, all along 2014, to explore the relationship between hydrological scenarios and spatial pattern summarized with principal component analysis. Water excess concentrated in winter (June and August); deficits were in late spring and summer (January and November), whereas the beginning of autumn (March) was an intermediate situation. Principal component 1 (44.7%) reflected area and shape metrics and correlated positively with water table level; principal component 2 (32.3%) summarized aggregation ones and was negatively associated with accumulated water excesses or deficits in previous 30 days and useful reserve. Both exhibited possible threshold-driven behaviour. Internal heterogeneity between NW and SE zones within the study area coincided with the existence of ancient alluvial fans. The results highlight the peculiarities of the flood spatial patterns in regions with very mild relief, where landforms usually determine water flows.     

Transgressive dunefield landforms and vegetation associations,Doña Juana,Veracruz, Mexico

Transgressive dune fields often comprise a multiplicity of landforms where vegetation processes largely affect landform dynamics, which in turn, also affect vegetation processes. These associations have seldom been studied in detail. This paper examines four separate landform types in a complex coastal transgressive dunefield located in the central Gulf of Mexico, in order to assess the relationships between dunefield habitat, local environmental factors, vegetation associations and landform evolution. Topographic surveys using tape and clinometer were conducted in conjunction with vegetation survey transects at four locations across the Doña Juana dunefield. Vegetation surveys allowed the estimation of relative plant cover of each plant species found along the transects. A large variety of landforms were found at the Doña Juana Dunefield: deflation plains, gegenwalle (counter) ridges, transverse dune trailing ridges, blowouts and parabolic dunes, aklé (fish‐scale shaped) dunefields and precipitation ridges, with plant species associations developing on these different landforms equally variable. Flood tolerant species were located in the lower parts (deflation plain and gegenwalle ridges) whereas the older and dryer parts were covered by coastal matorral shrubs. Burial‐tolerant species were dominant in the most mobile areas (blowouts and aklé dunefield and margin). The dune trailing ridge, with relatively milder conditions, showed the highest richness, with no dominant species. A dual interaction was found such that colonizing species both create and affect topography, and in turn, topography determines vegetation association and succession patterns. In coastal dunes, the vegetation and abiotic environment (namely the different landforms and the inherent micronevironmental variability) interact tightly and generate a complex and highly dynamic biogeomorphic system where substrate mobility and colonization processes reinforce one another in positive feedback. Copyright © 2010 John Wiley & Sons, Ltd.     

Paleomagnetic constraints on the paleogeography and oroclinal bending of the Devonian volcanic arc in Kazakhstan

Numerical modelling, incorporating coupling between surface processes and induced flow in the lower continental crust, is used to address the Quaternary evolution of the Gulf of Corinth region in central Greece. The post-Early Pleistocene marine depocentre beneath this Gulf overlies the northern margin of an older (Early Pleistocene and earlier) lacustrine basin, the Proto Gulf of Corinth Basin or PGCB. In the late Early Pleistocene, relief in this region was minimal but, subsequently, dramatic relief has developed, involving the creation of  900 m of bathymetry within the Gulf and the uplift by many hundreds of metres of the part of the PGCB, south of the modern Gulf, which forms the Gulf's main sediment supply. It is assumed that, as a result of climate change around 0.9 Ma, erosion of this sediment source region and re-deposition of this material within the Gulf began, both processes occurring at spatial average rates of  0.2 mm a^− 1. Modelling of the resulting isostatic response indicates that the local effective viscosity of the lower crust is  4 × 10¹⁹ Pa s, indicating a Moho temperature of  560 °C. It predicts that the  10 mm a^− 1 of extension across this  70 km wide model region, at an extensional strain rate of  0.15 Ma^− 1, is partitioned with  3 mm a^− 1 across the sediment source,  2 mm a^− 1 across the depocentre, and  5 mm a^− 1 across the ‘hinge zone’ in between, the latter value being an estimate of the extension rate on normal faults forming the major topographic escarpment at the southern margin of the Gulf. This modelling confirms the view, suggested previously, that coupling between this depocentre and sediment source by lower-crustal flow can explain the dramatic development in local relief since the late Early Pleistocene. The effective viscosity of the lower crust in this region is not particularly low; the strong coupling interpreted between the sediment source and depocentre results instead from their close proximity. In detail, the effective viscosity of the lower crust is expected to decrease northward across this model region, due to the northward increase in exposure of the base of the continental lithosphere to the asthenosphere; in the south the two are separated by the subducting Hellenic slab. The isostatic consequences of such a lateral variation in viscosity provide a natural explanation for why, since  0.9 Ma, the modern Gulf has developed asymmetrically over the northern part of the PGCB, leaving the rest of the PGCB to act as its sediment source.     

A hybrid deterministic and stochastic approach for tsunami hazard assessment in Iquique,Chile

Natural Hazards - This paper presents an investigation of the collapse of a 325-year-old multi-tiered heritage temple during the 2015 Gorkha earthquake in Kathmandu, Nepal. The research comprises a...     

Phylogenetic Diversity of Microorganisms from Chemocline of the Meromictic Soda Lake Doroninskoe(Zabaikalie,Russia)

正1 Introduction Many soda and salt lakes are characterized by the formation of the meromictic conditions under which a part of the water column is not involved in the annual process of mixing(Mac Intyre,Melack,1982).This creates an     

Observations and box model analysis of radon-222 in the atmospheric surface layer at L’Aquila,Italy: March 2009 case study

Two years of radon-222 observations collected at L’Aquila (Italy) in the atmospheric surface layer during 2004–2006 were analyzed in correlation with meteorological data and other atmospheric tracers. A box model was developed to better understand the mechanisms of diurnal and seasonal variability of the tracer and to indirectly assess the magnitude of the monthly averaged radon soil flux in the L’Aquila measurement site. The model was successfully validated with measurements, with a 0.8 average correlation coefficient between hourly values for the whole period of radon observations. Measurements taken during March 2009 were analyzed to find possible signs of perturbation due to the ongoing seismic activity that would have reached its peak on the 6 April 2009 destructive earthquake. Contrary to the professed (and unpublished) dramatic increases of radon activity unofficially announced to the inhabitants at that time, the study presented here shows that no radon activity increase took place in L’Aquila with respect to a previous ‘seismically unperturbed’ year (same month with similar meteorological conditions), but that an average 30 % decrease was experienced. This conclusion is reached from a direct comparison of observed data and also as a result of the previously validated radon box model constrained by actual meteorological data, from which an indirect estimate of a 17 % reduction of the radon soil flux is obtained.