U–Pb zircon ages of the Nakanogawa Group in the Hidaka Belt,northern Japan: Implications for its provenance and the protolith of the Hidaka metamorphic rocks

Zircon U–Pb ages of two acidic tuff and two turbidite sandstone samples from the Nakanogawa Group, Hidaka Belt, were measured to estimate its depositional age and the development of the Hokkaido Central Belt, northeast Japan. In the northern unit, homogeneous zircons from pelagic acidic tuff from a basal horizon dated to 58–57 Ma, zircons from sandstone from the upper part of the unit dated to 56–54 Ma, and zircons from acidic tuff from the uppermost part dated to 60–56 Ma and 69–63 Ma. Both of the tuff U–Pb ages are significantly older than the youngest radiolarian fossil age (66–48 Ma). Therefore, the maximum depositional age of the turbidite facies in the northern unit is 58 Ma and the younger age limit, estimated from the fossil age, is 48 Ma. In the southern unit, homogeneous zircons from turbidite sandstone dated to 58–57 Ma. Thus the depositional age of this turbidite facies was interpreted to be 66–56 Ma from the fossil age, probably close to 57 Ma. Most of the zircon U–Pb ages from the Nakanogawa Group are younger than 80 Ma, with a major peak at 60 Ma. This result implies that around Hokkaido volcanic activity occurred mainly after 80 Ma. Older zircon ages (120–80 Ma, 180–140 Ma, 340–220 Ma, 1.9 Ga, 2.2 Ga, and 2.7 Ga) give information about the provenance of other rocks in the Hidaka Belt. It is inferred that the Nakanogawa Group comprises protoliths of the upper sequence of the Hidaka Metamorphic Zone, which therefore has the same depositional age as the Nakanogawa Group (66–48 Ma). The depositional ages of the lower sequence of the Hidaka Metamorphic Zone and the Nakanogawa Group are probably the same.     

Zircon fission‐track and U–Pb double dating using femtosecond laser ablation–inductively coupled plasma–mass spectrometry: A technical note

We present a new LA–ICP–MS system for zircon fission‐track (FT) and U–Pb double dating, whereby a femtosecond laser combined with galvanometric optics simultaneously ablates multiple spots to measure average surface U contents. The U contents of zircon measured by LA–ICP–MS and standardized with the NIST SRM610 glass are comparable to those measured by the induced FT method, and have smaller analytical errors. LA–ICP–MS FT dating of seven zircon samples including three IUGS age standards is as accurate as the external detector method, but can give a higher‐precision age depending on the counting statistics of the U content measurement. Double dating of the IUGS age standards gives FT and U–Pb ages that are in agreement. A chip of the Nancy 91500 zircon has a homogeneous U content of 84 ppm, suggesting the possibility of using this zircon as a matrix‐matched U‐standard for FT dating. When using the Nancy 91500 zircon as a U‐standard, a zeta calibration value of 42–43 year cm² for LA–ICP–MS FT dating is obtained. While this value is strictly valid only for the particular session, it can serve as a reference for other studies.     

Identification of Lower Pleistocene widespread tephras associated with large caldera-forming eruptions in the Tohoku area,north-east Japan

Tephra fingerprinting techniques contributing to volcanology and palaeoenvironmental studies have been developed using a combination of laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). In particular, femtosecond LA-ICP-MS can determine major- and trace element abundances in individual glass shards. On the basis of the major oxide and trace element composition of the glass shards, using those methods, we re-examined the identification of four lower Pleistocene tephras originating from north-east Japan. All trace element abundances exhibited the typical pattern of tephras from the Hokkaido–Tohoku area, and major element concentrations were distinct. As a result, we re-examined the correlation of the widespread Tmg-R4 tephra (2.0 Ma), and newly defined the widespread Kd44-Naka tephra (1.968–1.781 Ma), both originating from the Sengan geothermal region. Furthermore, we re-examined identifications of Sr-Asn-Kd8 (1.219 Ma) and Sr-Kc-U8 (0.922–0.910 Ma) in central Japan, both derived from the Aizu volcanic region. The extensive distributions of the former two tephras suggest the occurrence of two large caldera-forming eruptions (Volcanic Explosivity Index 7) during a short period. Also, the distributions and volumes of the latter two tephras are broader and larger than those previously assumed. The results provide insight into large volcanic eruption history and terrestrial and marine palaeoenvironmental history.     

A refined model for spinning dust radiation

We present a comprehensive treatment of the spectrum of electric dipole emission from spinning dust grains, updating the commonly used model of Draine & Lazarian. Grain angular velocity distributions are computed using the Fokker–Planck equation; we revisit the drift and diffusion coefficients for the major torques on the grain, including collisions, grain-plasma interactions and infrared emission. We use updated grain optical properties and size distributions. The theoretical formalism is implemented in the companion code, spdust , which is publicly available. The effect of some environmental and grain parameters on the emissivity is shown and analysed.     

Seismological monitoring on the 2003 Tokachi-oki earthquake, derived from off Kushiro permanent cabled OBSs and land-based observations

Japan Marine Science and Technology Center installed a cabled geophysical observatory system off Kushiro, Hokkaido Island in July 1999. This observatory system comprises three ocean bottom seismographs (OBSs), two tsunami gauges, and a geophysical/geochemical monitoring system. 4 years and 2 months after the installation, a megathrust earthquake (the 2003 Tokachi-Oki earthquake, 26th September in Japan Standard Time (JST), M_JMA 8.0) occurred along a plate boundary underneath a forearc basin where the system is located. The system recorded clear unsaturated seismograms just at 28.6 km from the epicenter. This paper demonstrates advantages brought by the cabled observatory to record the megathrust earthquake showing how earthquake detectability is improved dramatically combining permanent OBS and land-based observations around the region, and importance of the in situ monitoring on the seismogenic zone. In the present study, processing OBSs and land-based network together, and comparing magnitudes of common observed earthquakes with national authorized network, event detection level improved down to M 1.5, which is much lower than the previously designed as down to M  2. Comparing detection level before and after installing OBSs, we found dramatic improvement of the earthquake detection level in the interesting region. Real-time continuous observations of microearthquakes since 1999 have brought us tremendous findings. First, a seismic quiescence started about 10 days before the 2003 Tokachi-Oki earthquake. Second, aftershock distribution is not uniform over the focal area and can be divided into several sub-regions, which might indicate an existence of several asperities. We think that the geophysical observations helped to understand the initiation process of the rupture of the 2003 Tokachi-Oki earthquake and that observations including seismological, geodynamic, hydrogeological, and the other multidisciplinary observations would provide a clue to future understanding of seismogenic processes at subduction zones.     

Grain-scale iron isotopic distribution of pyrite from Precambrian shallow marine carbonate revealed by a femtosecond laser ablation multicollector ICP-MS technique: Possible proxy for the redox state of ancient seawater

The redox state of Precambrian shallow seas has been linked with material cycle and evolution of the photosynthesis-based ecosystem. Iron is a redox-sensitive element and exists as a soluble Fe(II) species or insoluble Fe(III) species on Earth’s surface. Previous studies have shown that the iron isotopic ratio of marine sedimentary minerals is useful for understanding the ocean redox state, although the redox state of the Archean shallow sea is poorly known. This is partly because the conventional bulk isotope analytical technique has often been used, wherein the iron isotopic record may be dampened by the presence of isotopically different iron-bearing minerals within the same sample. Here we report a microscale iron isotopic ratio of individual pyrite grains in shallow marine stromatolitic carbonates over geological time using a newly developed, near-infrared femtosecond laser ablation multicollector ICP-MS technique (NIR-fs-LA-MC-ICP-MS).We have determined that the grain-scale iron isotopic distribution of pyrite from coeval samples shows a bimodal (2.7 and 2.3 Ga) or unimodal pattern (2.9, 2.6, and 0.7 Ga). In particular, pyrite from the 2.7 Ga Fortescue Group shows a unique bimodal distribution with highly positive (+1.0‰ defined as Type 1) and negative δ⁵⁶Fe values (−1.8‰ defined as Type 2). Type 1 and 2 pyrites occasionally occur within different siliceous layers in the same rock specimen. Layer-scale iron isotopic heterogeneity indicates that the iron isotopic ratios of the two types of pyrite are not homogenized by diagenesis after deposition. Some cubic pyrites have a core with a positive δ⁵⁶Fe value (1‰) and a rim with a crustal δ⁵⁶Fe value (0‰). The observed isotopic zoning suggests that the positive δ⁵⁶Fe value is a primary signature at the time of stromatolite formation, while secondary pyrite precipitated during diagenesis.The positive δ⁵⁶Fe value of Type 1 and the large iron isotopic difference between Type 1 and 2 (2.8‰.) suggest partial Fe(II) oxidation in the 2.7-Ga shallow sea, i.e., pyritization of ⁵⁶Fe-enriched ferric oxyhydroxide (Type 1) and ⁵⁶Fe depleted Fe²⁺aq in seawater (Type 2). Type 2 pyrite was probably not produced by microbial iron redox cycling during diagenesis because this scenario requires a higher abundance of pyrite with δ⁵⁶Fe of 0‰ than of −1.8‰. Consequently, the degree of Fe(II) oxidation in the 2.7-Ga shallow sea can be estimated by a Fe²⁺aq steady-state model. The model calculation shows that half the Fe²⁺aq influx was oxidized in the seawater. This implies that O₂ produced by photosynthesis would have been completely consumed by oxidation of the Fe²⁺aq influx. Grain-scale iron isotopic distribution of pyrite could be a useful index for reconstructing the redox state of the Archean shallow sea.     

Provenance diversification within an arc‐trench system induced by batholith development: the Cretaceous Japan case

By comparing detrital zircon U–Pb age spectra of coeval fore‐arc and back‐/intra‐arc basin sandstones, we identified the overall distributary pattern of terrigenous clastic material within the Cretaceous arc system of SW Japan. Abundant Proterozoic (c. 1500–2500 Ma) detrital grains from the interior of East Asia are present in the Cretaceous intra‐arc basin. However, after a barrier mountain range formed during batholith emplacement, Proterozoic clastics were rarely transported into the fore‐arc domain. Episodic batholith formation in Pacific‐type orogens likely played a major role in controlling terrigenous supply routes between coeval back‐arc and fore‐arc domains. The Cretaceous orogen in Japan thus provides a good template for analysing the tectono‐sedimentary development of other arc‐related basins.     

Anomalous content of chromium in a Cretaceous sandstone aquifer of the Bauru Basin,state of São Paulo,Brazil

Anomalous and natural concentrations of Cr⁶⁺, occasionally exceeding the permitted limit for human consumption (0.05 mg/L), have been detected in groundwater in the northwestern region of the state of São Paulo. As part of a water-rock interaction investigation, this article describes the chemical and mineralogical characterization of rock samples taken from boreholes in the municipality of Urânia, with the objective of identifying Cr-bearing minerals and determining how chromium is associated with these minerals. Rock sample analysis were performed using X-ray Fluorescence, X-ray Diffraction, Scanning Electron Microscopy, electron microprobe and sequential extraction techniques. Chemical analyses indicated that the quartzose sandstones show a geochemical anomaly of chromium, with an average content of 221 ppm, which is higher than the reported chromium content of generic sandstones (35 ppm). Diopside was identified as the primary Cr-bearing mineral potentially subject to weathering processes, with a chromium content of up to 1.2% as Cr₂O₃. Many of the diopside grains showed dissolution features, confirming the occurrence of weathering. Sequential extraction experiments indicated that 99.3% of the chromium in samples is tightly bonded to minerals, whereas 0.24% is weakly bonded via adsorption. Assuming hypothetically that all adsorbed chromium is released via desorption, the theoretical Cr concentration in water would be one order of magnitude higher than the concentrations of Cr⁶⁺ detected in groundwater.     

Relation between sedimentary framework and hydrogeology in the Guarani Aquifer System in São Paulo state,Brazil

This paper presents the results of a new investigation of the Guarani Aquifer System (SAG) in São Paulo state. New data were acquired about sedimentary framework, flow pattern, and hydrogeochemistry. The flow direction in the north of the state is towards the southwest and not towards the west as expected previously. This is linked to the absence of SAG outcrop in the northeast of São Paulo state. Both the underlying Pirambóia Formation and the overlying Botucatu Formation possess high porosity (18.9% and 19.5%, respectively), which was not modified significantly by diagenetic changes. Investigation of sediments confirmed a zone of chalcedony cement close to the SAG outcrop and a zone of calcite cement in the deep confined zone. The main events in the SAG post-sedimentary history were: (1) adhesion of ferrugineous coatings on grains, (2) infiltration of clays in eodiagenetic stage, (3) regeneration of coatings with formation of smectites, (4) authigenic overgrowth of quartz and K-feldspar in advanced eodiagenetic stage, (5) bitumen cementation of Pirambóia Formation in mesodiagenetic stage, (6) cementation by calcite in mesodiagenetic and telodiagenetic stages in Pirambóia Formation, (7) formation of secondary porosity by dissolution of unstable minerals after appearance of hydraulic gradient and penetration of the meteoric water caused by the uplift of the Serra do Mar coastal range in the Late Cretaceous, (8) authigenesis of kaolinite and amorphous silica in unconfined zone of the SAG and cation exchange coupled with the dissolution of calcite at the transition between unconfined and confined zone, and (9) authigenesis of analcime in the confined SAG zone. The last two processes are still under operation. The deep zone of the SAG comprises an alkaline pH, Na–HCO₃ groundwater type with old water and enriched δ¹³C values (<?3.9), which evolved from a neutral pH, Ca–HCO₃ groundwater type with young water and depleted δ¹³C values (>?18.8) close to the SAG outcrop. This is consistent with a conceptual geochemical model of the SAG, suggesting dissolution of calcite driven by cation exchange, which occurs at a relatively narrow front recently moving downgradient at much slower rate compared to groundwater flow. More depleted values of δ¹⁸O in the deep confined zone close to the Paraná River compared to values of relative recent recharged water indicate recharge occur during a period of cold climate. The SAG is a “storage-dominated” type of aquifer which has to be managed properly to avoid its overexploitation.     

Options for monitoring and estimating historical carbon emissions from forest degradation in the context of REDD+

Measuring forest degradation and related forest carbon stock changes is more challenging than measuring deforestation since degradation implies changes in the structure of the forest and does not entail a change in land use, making it less easily detectable through remote sensing. Although we anticipate the use of the IPCC guidance under the United Framework Convention on Climate Change (UNFCCC), there is no one single method for monitoring forest degradation for the case of REDD+ policy. In this review paper we highlight that the choice depends upon a number of factors including the type of degradation, available historical data, capacities and resources, and the potentials and limitations of various measurement and monitoring approaches. Current degradation rates can be measured through field data (i.e. multi-date national forest inventories and permanent sample plot data, commercial forestry data sets, proxy data from domestic markets) and/or remote sensing data (i.e. direct mapping of canopy and forest structural changes or indirect mapping through modelling approaches), with the combination of techniques providing the best options. Developing countries frequently lack consistent historical field data for assessing past forest degradation, and so must rely more on remote sensing approaches mixed with current field assessments of carbon stock changes. Historical degradation estimates will have larger uncertainties as it will be difficult to determine their accuracy. However improving monitoring capacities for systematic forest degradation estimates today will help reduce uncertainties even for historical estimates.