Phosphorus and metals bound to organic matter in coastal sediments - An investigation of complexes of P,Cu, Zn,Fe, Mn,Ni, Co and Ti by inductively coupled plasma-atomic emission spectrometry with sephadex gel chromatography

Phosphorus and metals bound to organic matter were separated from coastal sediments of Harima Sound in Seto Inland Sea, Japan by extraction with NaOH and fractionated by Sephadex G-25 chromatography. Phosphorus and metals were determined in the eluates by a multi-channel, inductively coupled plasma-atomic emission spectrometer. Phosphorus and Cu, Zn, Fe, Mn, Ni, Cr, Co and Ti bound to organic matter with high molecular weights (OMHMW) (MW ? 5000) were found to be present in the sediments, but no Mo or V were found. The technique provides minimum estimates of the amounts of P and metals bound to organic matter. These organic complexes show surface enrichment in a sediment core (0–20 cm) and their contents decrease with depth. Also, the amounts of eighteen elements, namely: P, Fe, Mn, Zn, Cu, Si, Al, Ti, Pb, Co, Ni, Cr, Mo, V, Na, K, Ca and Mg, in H₂O, ammonium acetate at pH 7 and 5, hydrogen peroxide, hydroxylamine hydrochloride and hydrogen fluoric acid soluble fractions have been determined with a selective chemical leaching technique for the ²¹⁰Pb-dated sediment core sample. Considerable amounts of P (6–19%) and Cu (5–21%) were associated with organic matter, in contrast to other metals such as Fe, Mn, Zn, Ni, Cr, Co and Ti which were associated with sulfide and silicate.     

EXAMINATION OF THE RELIABILITY OF THE JMA SEISMIC OBSERVATION NETWORK AROUND THE SOUTHERN OKINAWA TROUGH

After the establishment of the seismic observation network of southern Okinawa in August,1988 by the JMA(Japan Meteorological Agency),many hypocenters of earthquakes have been located.However,due to the small number of observation stations and narrow configuration of the array,the hypocenters lo-cated contain some systematic errors.Numerical experiments on the extent of the errors and the reliabilityof the JMA seismic observation network showed that the obtained hypocenters deeper than 100 km werereliable,but that for the obtained hypocenters shallower than 100 km,only the epicenters were reliable.     

Molecular weight and trace metal distributions in fulvic and humic acid fractions of coastal marine sediments

Molecular weight and trace metal distributions of fulvic and humic acid fractions of marine sediments from the Seto Inland Sea were investigated by using a gel filtration technique in combination with atomic absorption and emission spectrometries. A binary molecular weight distribution was found both in the fulvic acid fraction and in the humic acid fraction. The fulvic acid fractions with molecular weights of less than 1.5×10³ and of 5×10³?10⁴ accounted for 38–57 % and 25–41 % of the total fulvic acids, respectively, and the humic acid fractions with molecular weights of 10²?10⁴ and of over 2×10⁵ accounted for 58–73 % and 16–27 % of the total humic acids, respectively. The components with molecular weights of over 1.5×10³ contained 54 %, on average, of the Fe, Zn and Cu in the fulvic acid fraction, and the components with molecular weights of over 10⁴ contained 58 %, on average, of these metals in the humic acid fraction.     

Evolution of the composition of seawater through geologic time, and its influence on the evolution of life

The redox state of the surface environment of the early Earth is still controversial, and a detailed and quantitative estimate is still lacking. We carried out in-situ analyses of major, trace, and rare-earth elements of carbonate minerals in rocks with primary sedimentary structures in shallow and deep sea-deposits, in order to eliminate secondary carbonate and contamination of detrital materials, and to estimate the redox condition of seawater through time. Based on the Ce content and anomalies of the carbonate minerals at given parameters of atmospheric CO₂ content (pCO₂) and Ca content of seawater, we calculated the oxygen contents of shallow and deep seawater, respectively. The results show that the oxygen content of the deep sea was low and constant until at least 1.9 Ga. The oxygen content of shallow seawater increased after 2.7 Ga, but fluctuated. It became quite high at 2.5 and 2.3 Ga, but eventually increased after the Phanerozoic. In addition, the calculation of a high pCO₂ condition shows that seawater was more oxic even in the Archean than at present, suggesting a relatively low pCO₂ through geologic time.Our detailed calculations from compositions of carbonate minerals in Three Gorge area, south China show a low oxygen content of seawater after the Snowball Earth until the late Ediacaran, an increase in the late Ediacaran, and a significant decrease around the Precambrian–Cambrian and Nemakit/Daldynian–Tommotian boundaries. These variations were possibly caused by global regression and dissolution of methane hydrates.     

The emplacement of in situ greenstones in the northern Hidaka belt: The tectonic relationship between subduction of the Izanagi–Pacific ridge and Hidaka magmatic activity

Greenstone bodies emplaced upon or into clastic sediments crop out ubiquitously in the Hidaka belt (early Paleogene accretionary and collisional complexes exposed in the central part of northern Hokkaido, NE Japan), but the timing and setting of their emplacement has remained poorly constrained. Here, we report new zircon U–Pb ages for the sedimentary complexes surrounding these greenstones. The Hidaka Supergroup in the northern Hidaka belt is divided into four zones from west to east: zones S, U, and R, which contain in situ greenstones; and zone Y, which does not. Detrital zircons in zones S, U, and R have early Eocene U–Pb ages (55–47 Ma) and these strata are intruded by early Eocene granites (46–45 Ma), indicating that they were deposited between 55 and 46 Ma. Therefore, in situ greenstones in the northern Hidaka belt can only be explained by the subduction of the Izanagi–Pacific Ridge during 55–47 Ma. In contrast, the deposition of zone Y (the Yubetsu Group, younging to the west) began by 73–71 Ma, indicating that the accretionary prism in front of the paleo-Kuril arc formed at the same time as that in the Idonnappu zone and grew continuously until 48 Ma. The plutonic rocks that intruded the Hidaka belt are roughly divided into three stages: (1) early Eocene granites intruded the northern Hidaka belt at 46–45 Ma, during subduction of the Izanagi–Pacific Ridge; (2) the upper sequence of the Hidaka metamorphic zone was metamorphosed by magmatism at 40–37 Ma associated with the collision of the paleo-Kuril arc and NE Asia; and (3) younger granites intruded the entire Hidaka belt at 20–17 Ma in association with asthenospheric upwelling caused by back-arc expansion.     

A Paleogene magmatic overprint on Cretaceous seamounts of the western Pacific

The West Pacific Seamount Province (WPSP) represents a series of short-lived Cretaceous hotspot tracks. However, no intraplate volcanoes in advance of petit-spot volcanism erupted near a trench have been identified after the formation of the WPSP on the western Pacific Plate. This study reports new ages for Paleogene volcanic edifices within the northern WPSP, specifically the Ogasawara Plateau and related ridges, and Minamitorishima Island. These Paleogene ages are the first reported for basaltic rocks on western Pacific seamounts, in an area that has previously only yielded Cretaceous ages. The newly found Paleogene volcanisms overprint the Early–middle Cretaceous volcanic edifices, because the seamount or paleo-island material-covered reefal limestone caps on these edifices are uniformly older than the Paleogene volcanism identified in this study. This study outlines several possible causative factors for the Paleogene volcanism overprinting onto existing Cretaceous seamounts, including volcanism related to lithospheric stress, or a younger hotspot track within the northern part of the WPSP that records magmatism from ~60 Ma.     

Non-metamorphosed autochthonous Kuncha-Naudanda-Heklang Formations and their differences from those of the Kuncha nappe: A multichronological approach

Non-metamorphosed, autochthonous Lesser Himalayan sediments (LHS), which are correlated to the Kuncha and Naudanda Formations, were found in a narrow belt between the Main Boundary Thrust and the Lesser Himalayan Thrust at the base of the Kuncha nappe in southeastern Nepal. The autochthonous Naudanda Formation is comprised of cross-bedded and rippled orthoquartzite and yielded a maximum depositional age of 1795.1 Ma ±5.1 Ma using detrital zircons. Low-grade metamorphosed quartzite in the Kuncha nappe yielded a maximum depositional age of 1867.4 Ma ±3.4 Ma, although it is totally recrystallized. These ages and age distribution patterns of detrital zircon grains indicate that the meta-quartzite of the nappe is originally Naudanda Formation. A zircon fission-track age of the autochthonous Naudanda Formation shows partially annealed age of 864 Ma ±56 Ma, in contrast, that of the Kuncha nappe shows a totally annealed age of 11.9 Ma ±1.6 Ma. These results suggest that the autochthonous LHS have never undergone metamorphism during the Himalayan orogeny. We also discovered a non-metamorphosed Heklang Formation that rests on the Naudanda Formation, and designated it as a sub-type section on the basis of detailed lithostratigraphic study. It is characterized by black and light green slate with dolerite sills and ill-sorted quartzose sandstone, and correlated to the metamorphosed Dandagaon Phyllites in the Kathmandu area. Non-metamorphosed autochthonous formations distributed to the south of the nappe front suggest that they escaped from thermal metamorphism by hot nappe.     

Zircon U–Pb ages of Miocene granitic rocks in the Koshikijima Islands: Implications for Neogene tectonics in the Kyushu region,southwest Japan

The opening of the Japan Sea separated southwest Japan from the Eurasian continent during the Early to Middle Miocene. Since then, diverse igneous activities have occurred in relation to the subduction of the Philippine Sea Plate beneath southwest Japan. The Okinawa Trough formed in the back-arc region of the Ryukyu Arc since the Late Miocene. In the Koshikijima Islands, off the west coast of Kyushu and near the northern end of the Okinawa Trough, felsic to intermediate igneous rocks with Middle to Late Miocene radiometric ages occur as granitic intrusions and dikes. We obtained zircon U–Pb ages and whole-rock major- and trace-element compositions of Koshikijima granitic rocks to elucidate their magmagenesis. The U–Pb ages of granitic rocks in Kamikoshikijima and Shimokoshikijima and a dacite dike are about 10 Ma, suggesting that most magmatism on the Koshikijima Islands was coeval with early rifting in the Okinawa Trough. We infer that magmagenesis occurred via melting of lower crustal mafic rocks related to rifting in the Okinawa Trough based on the arc-like trace-element compositions of these I-type granites. Andesitic dikes preceded felsic igneous activity on the Koshikijima Islands, and their ages and petrochemistry will help elucidate the magmatism and tectonics in this area throughout the Miocene.