Correlation between electron paramagnetic resonance and thermoluminescence in natural sodalite

Samples of natural sodalite, Na₈Al₆Si₆O₂₄Cl₂, submitted to gamma irradiation and to thermal treatments, have been investigated using the thermoluminescence (TL) and electron paramagnetic resonance (EPR) techniques. Both, natural and heat-treated samples at 500°C in air for 30 min, present an EPR signal around g = 2.01132 attributed to oxygen hole centers. The EPR spectra of irradiated samples show an intense line at g = 2.0008 superimposed by a hyperfine multiplet of 11 lines due to an O⁻ ion in an intermediate position with respect to two adjacent Al nuclei. In the TL measurements, the samples were annealed at 500°C for 30 min and then irradiated with γ doses varying from 0.001 to 20 kGy. All the samples have shown TL peaks at 110, 230, 270, 365, and 445°C. A correlation between the EPR g = 2.01132 line and the 365°C TL peak was observed. A TL model is proposed in which a Na⁺ ion acts as a charge compensator when an Al³⁺ ion replaces a Si⁴⁺ lattice ion. The γ ray destruction of the Al–Na complex provides an electron trapped at the Na and a hole trapped at a non-bridging oxygen ion adjacent to the Al³⁺ ion.     

Hydrothermal Alteration Related to Silver Mineralization at the Iwami Silver Deposit,Shimane Prefecture,Japan

The Iwami epithermal silver deposit consists of Ag-Cu veins in a dacitic intrusive body at the deep portion of the Eikyu area, and veinlets with disseminated Ag mineralization in dacitic tuff breccia at a shallow portion of the Fukuishi area. Hydrothermal alteration associated with the silver mineralization is characterized by intense potassium metasomatism with oxidizing conditions. An illite zone occurs around the pathways of uprising fluids in both the Eikyu and Fukuishi areas. It grades laterally into the illite/smectite zone, which is surrounded by a broad smectite zone. Because of boiling, abundant adularia associated with silver mineralization overlaps on the altered tuff breccia in the Fukuishi area. The alteration zoning suggests that the western Eikyu area and the eastern Fukuishi area belong to a single hydrothermal system. The data of fluid inclusion microthermometry indicate that the temperatures range 220–270°C, and salinities range 5–7 wt percent NaCl equivalent for the silver mineralization at the upper portion in the Eikyu area and the lower portion in the Fukuishi area. Radiometric ages for volcanic rocks in the area range from 2.19 to 1.64 Ma, and the dacitic intrusion formed at approximately 1.6 Ma. The silver-dominant mineralizing hydrothermal fluids system was active around 1.44 to 1.07 Ma, which formed the Eikyu Ag-Cu veins at depth, and the Fukuishi Ag ores at the shallower portion.     

Holocene rockfalls in the southern Negev Desert,Israel and their relation to Dead Sea fault earthquakes

Rockfall ages in tectonically active regions provide information regarding frequency and magnitude of earthquakes. In the hyper-arid environment of the Dead Sea fault (DSF), southern Israel, rockfalls are most probably triggered by earthquakes. We dated rockfalls along the western margin of the DSF using terrestrial cosmogenic nuclides (TCN). At each rockfall site, samples were collected from simultaneously exposed conjugate boulders and cliff surfaces. Such conjugate samples initially had identical pre-fall (“inherited”) TCN concentrations. After boulder detachment, these surfaces were dosed by different production rates due to differences in post-fall shielding and geometry. However, in our study area, pre-rockfall inheritance and post-rockfall production rates of TCN cannot be evaluated. Therefore, we developed a numerical approach and demonstrated a way to overcome the above-mentioned problems. This approach can be applied in other settings where rockfalls cannot be dated by simple exposure dating. Results suggest rockfall ages between 3.6 ± 0.8 and 4.7 ± 0.7 ka. OSL ages of sediment accumulated behind the boulders range between 0.6 ± 0.1 and 3.4 ± 1.4 ka and support the TCN results. Our ages agree with dated earthquakes determined in paleoseismic studies along the entire length of the DSF and support the observation of intensive earthquake activity around 4–5 ka.     

VIDEO AND PHOTOGRAPHIC SPECTROSCOPY OF 1998 AND 2001 LEONID PERSISTENT TRAINS FROM 300 TO 930 nm

Spectra of persistent meteor trains were observed at wavelength between 300 and 930 nm. Two obtained train spectra during the 1998 and 2001 Leonid meteor showers are reported here. During the 1998 Leonids, one train was detected by a photographic camera with a spectrograph covering 370–640 nm region. On the other hand, during the 2001 Leonids, video observations were carried out using image intensified cameras in ultraviolet (UV), visible and near infrared (near-IR) wavelengths. Temperatures in persistent trains have been measured by atmospheric O₂ A(0,1) band at the wavelength near 864.5 nm. From a video spectrum obtained just 7 s after parent fireball’s flare, a rotational temperature of 250 K at altitude of 88.0±0.5 km was estimated. We can say that the cooling time scale of train strongly depends on the initial mass of its fireball at least for Leonids. Based on cooling constant calculated from our results, we estimated a temperature of ∼ ∼130 K as a final exothermic temperature at early stage of persistent trains.     

Simulation of groundwater dynamics in the North China Plain by coupled hydrology and agricultural models

We simulated the effects of irrigation on groundwater flow dynamics in the North China Plain by coupling the NIES Integrated Catchment‐based Ecohydrology (NICE) model with DSSAT‐wheat and DSSAT‐maize, two agricultural models. This combined model (NICE‐AGR) was applied to the Hai River catchment and the lower reach of the Yellow River (530 km wide by 840 km long) at a resolution of 5 km. It reproduced excellently the soil moisture, evapotranspiration and crop production of summer maize and winter wheat, correctly estimating crop water use. So, the spatial distribution of crop water use was reasonably estimated at daily steps in the simulation area. In particular, NICE‐AGR reproduced groundwater levels better than the use of statistical water use data. This indicates that NICE‐AGR does not need detailed statistical data on water use, making it very powerful for evaluating and estimating the water dynamics of catchments with little statistical data on seasonal water use. Furthermore, the simulation reproduced the spatial distribution of groundwater level in 1987 and 1988 in the Hebei Plain, showing a major reduction of groundwater level due mainly to overpumping for irrigation. Copyright © 2006 John Wiley & Sons, Ltd.     

Measurements of aerosol number concentrations and rainwater chemistry at Mt. Tateyama, near the coast of the Japan sea in central Japan: On the influence of high-elevation Asian dust particles in autumn

Measurements of size-separated aerosol number concentrations at Midagahara (altitude, 1,930 m), on the western slope of Mt. Tateyama near the coast of the Japan Sea, were performed each autumn from 2006 to 2011. High number concentrations of particles larger than 2 μm were frequently seen in 2006 and 2009 when the influence of Asian dust might have been significant. The pH and the ratio of Ca²⁺ to total ions were high in the rainwater bulk sampled when high number concentrations of coarse particles were observed. The mean pH of rainwater during the autumn in 2006 was significantly higher than that in 2007 and 2008. Acidic species might have been neutralized by the Asian dust particles. Dust particles may highly affect the natural environment, such as forest ecosystems, at high elevations during seasons without snow cover.     

Estimation of groundwater use by crop production simulated by DSSAT‐wheat and DSSAT‐maize models in the piedmont region of the North China Plain

Sustainable water use is in serious crisis in the piedmont region of the Taihang Mountains in the North China Plain, owing to rapid groundwater drawdown. Estimating the water requirement for agriculture, the biggest user of groundwater, will be helpful in understanding groundwater decline. Through the use of DSSAT‐3·5 wheat and maize models, we assessed water use in winter wheat and maize, two staple crops in the region, in 1987–2001. Trends between groundwater change and simulated agricultural water use were compared. The results showed that groundwater decline was sensitive to simulated crop water requirement and irrigation requirement. According to regression analysis, 100 mm of water requirement by cultivated land (mainly wheat and maize) resulted in about 0·64 m of groundwater decline. This relationship might be useful in understanding the regional water balance and to help decision‐makers control groundwater decline through controlling crop water use or through long‐distance water transfer. The study demonstrated the usefulness of using the DSSAT model for estimating crop water use and the effectiveness of clarifying the reason for groundwater decline using the simulation results of water use. Copyright © 2006 John Wiley & Sons, Ltd.     

Plasma dynamics at the very initial phases of flares

Solar Physics - Plasma motions at the initial phases of flares observed in the high resolution soft X-ray spectrometers are summarized. Blue-shifted components of highly ionized metal ions suggest...     

Perturbed physics ensemble using the MIROC5 coupled atmosphere–ocean GCM without flux corrections: experimental design and results

In this study, we constructed a perturbed physics ensemble (PPE) for the MIROC5 coupled atmosphere–ocean general circulation model (CGCM) to investigate the parametric uncertainty of climate sensitivity (CS). Previous studies of PPEs have mainly used the atmosphere-slab ocean models. A few PPE studies using a CGCM applied flux corrections, because perturbations in parameters can lead to large radiation imbalances at the top of the atmosphere and climate drifts. We developed a method to prevent climate drifts in PPE experiments using the MIROC5 CGCM without flux corrections. We simultaneously swept 10 parameters in atmosphere and surface schemes. The range of CS (estimated from our 35 ensemble members) was not wide (2.2–3.2?°C). The shortwave cloud feedback related to changes in middle-level cloud albedo dominated the variations in the total feedback. We found three performance metrics for the present climate simulations of middle-level cloud albedo, precipitation, and ENSO amplitude that systematically relate to the variations in shortwave cloud feedback in this PPE.