Prediction of episodic acidification in North‐eastern USA: an empirical/mechanistic approach

Observations from the US Environmental Protection Agency's Episodic Response Project (ERP) in the North‐eastern United States are used to develop an empirical/mechanistic scheme for prediction of the minimum values of acid neutralizing capacity (ANC) during episodes. An acidification episode is defined as a hydrological event during which ANC decreases. The pre‐episode ANC is used to index the antecedent condition, and the stream flow increase reflects how much the relative contributions of sources of waters change during the episode. As much as 92% of the total variation in the minimum ANC in individual catchments can be explained (with levels of explanation >70% for nine of the 13 streams) by a multiple linear regression model that includes pre‐episode ANC and change in discharge as independent variables. The predictive scheme is demonstrated to be regionally robust, with the regional variance explained ranging from 77 to 83%. The scheme is not successful for each ERP stream, and reasons are suggested for the individual failures. The potential for applying the predictive scheme to other watersheds is demonstrated by testing the model with data from the Panola Mountain Research Watershed in the South‐eastern United States, where the variance explained by the model was 74%. The model can also be utilized to assess ‘chemically new’ and ‘chemically old’ water sources during acidification episodes. Copyright © 1999 John Wiley & Sons, Ltd.     

Numerical Analysis of Thermal Remediation in 3D Field‐Scale Fractured Geologic Media

Thermal methods are promising for remediating fractured geologic media contaminated with volatile organic compounds, and the success of this process depends on the coupled heat transfer, multiphase flow, and thermodynamics. This study analyzed field‐scale removal of trichloroethylene (TCE) and heat transfer behavior in boiling fractured geologic media using the multiple interacting continua method. This method can resolve local gradients in the matrix and is less computationally demanding than alternative methods like discrete fracture‐matrix models. A 2D axisymmetric model was used to simulate a single element of symmetry in a repeated pattern of extraction wells inside a large heated zone and evaluate effects of parameter sensitivity on contaminant recovery. The results showed that the removal of TCE increased with matrix permeability, and the removal rate was more sensitive to matrix permeability than any other parameter. Increasing fracture density promoted TCE removal, especially when the matrix permeability was low (e.g., <10^?17 m²). A 3D model was used to simulate an entire treatment zone and the surrounding groundwater in fractured material, with the interaction between them being considered. Boiling was initiated in the center of the upper part of the heated region and expanded toward the boundaries. This boiling process resulted in a large increase in the TCE removal rate and spread of TCE to the vadose zone and the peripheries of the heated zone. The incorporation of extraction wells helped control the contaminant from migrating to far regions. After 22 d, more than 99.3% of TCE mass was recovered in the simulation.     

Sediment yield of the lower Tana River,Kenya, is insensitive to dam construction: sediment mobilization processes in a semi‐arid tropical river system

Dam construction in the 1960s to 1980s significantly modified sediment supply from the Kenyan uplands to the lower Tana River. To assess the effect on suspended sediment fluxes of the Tana River, we monitored the sediment load at high temporal resolution for 1 year and complemented our data with historical information. The relationship between sediment concentration and water discharge was complex: at the onset of the wet season, discharge peaks resulted in high sediment concentrations and counterclockwise hysteresis, while towards the end of the wet season, a sediment exhaustion effect led to low concentrations despite the high discharge. The total sediment flux at Garissa (c. 250 km downstream of the lowermost dam) between June 2012 and June 2013 was 8.8 Mt yr^‐1. Comparison of current with historical fluxes indicated that dam construction had not greatly affected the annual sediment flux. We suggest that autogenic processes, namely river bed dynamics and bank erosion, mobilized large quantities of sediments stored in the alluvial plain downstream of the dams. Observations supporting the importance of autogenic processes included the absence of measurable activities of the fall‐out radionuclides ⁷Be and ¹³⁷Cs in the suspended sediment, the rapid lateral migration of the river course, and the seasonal changes in river cross‐section. Given the large stock of sediment in the alluvial valley of the Tana River, it may take centuries before the effect of damming shows up as a quantitative reduction in the sediment flux at Garissa. Many models relate the sediment load of rivers to catchment characteristics, thereby implicitly assuming that alterations in the catchment induce changes in the sediment load. Our research confirms that the response of an alluvial river to external disturbances such as land use or climate change is often indirect or non‐existent as autogenic processes overwhelm the changes in the input signal. Copyright © 2015 John Wiley & Sons, Ltd.     

A new species of Plaxiphora (Mollusca: Polyplacophora) from southern New Zealand

Plaxiphora boydeni n.sp. from wave‐exposed rocky shores of southern New Zealand is described and illustrated. This is the first published record of the genus from the New Zealand mainland. P. boydeni is readily distinguished from the 2 other New Zealand species of the genus, which occur in the subantarctic region, by the absence of bristle‐tufts on the girdle.     

Short-term and seasonal variation in metabolic balance in Liverpool Bay

Regions of freshwater influence (ROFIs) are dynamic areas within the coastal seas that experience cycles of stability driven by density gradients and the spring-neap tidal cycle. As a result, pulses of biological production may occur on a more frequent timescale than the classic seasonal cycle. Net community production (NCP) rates and chlorophyll a concentration are presented from a site within the ROFI of Liverpool Bay and compared to similar measurements made at a site outside the ROFI during 2009. The influence of water column stability on biological production in the ROFI was also investigated using high-frequency observations from a Cefas Smartbuoy. Both sites were autotrophic from spring to autumn before becoming heterotrophic over winter. NCP at the inshore site was estimated to range from 30.8 to 50.4 gC m⁻² year⁻¹. A linear relationship detected between chlorophyll a and NCP from both sites was used to estimate metabolic balance over 1 year at the ROFI site using high-resolution chlorophyll a concentrations from the Smartbuoy but was found to poorly replicate NCP rates compared to those derived from dissolved oxygen fluxes. There was no clear biological response to periods of stratification within the ROFI, and it is proposed that changes in light attenuation in the Liverpool Bay ROFI, driven not only by stratification but also by fluctuations in riverine sediment load, most likely play an important role in controlling phytoplankton growth in this region.     

Late Holocene upper bounds of flood magnitudes and twentieth century large floods in the ungauged, hyperarid alluvial Nahal Arava, Israel

The impact of large twentieth century floods on the riparian vegetation and channel morphology of the relatively wide anabranching and braided Nahal Arava, southern Israel, was documented as part of developing tools to (a) identify recent large floods, (b) determine these flood's respective magnitudes in alluvial ungauged streams, and (c) determine long-term upper bounds to flood stages and magnitudes. Along most of its course Nahal Paran, a major tributary that impacts the morphology, floods and sediments of Nahal Arava at the study reach, is a coarse-gravel, braided ephemeral stream. Downstream of the Arava–Paran confluence, aeolian and fluvial sand delivered from eastern Arava valley alters the channel morphology. The sand has accreted up to 2.5 m above the distinct current channels, facilitating the recording of large floods. This sand enhances the establishment of denser riparian vegetation (mainly Tamarix nilotica and Haloxylon persicum) that interacts with floods and affects stream morphology. A temporal association was found between specific floods recorded upstream and tree-ring ages of re-growth of flood-damaged tamarix trees (‘Sigafoos trees’) in the past 30 years. This association can be utilized for developing a twentieth century flood chronology in hyperarid ungauged basins in the region. The minimum magnitude of the largest flood that covered the entire channel width, estimated from flood deposits, is approximately 1700–1800 m³s^− 1. This is a larger magnitude than the largest gauged flood of 1150 m³s^− 1 that occurred in 1970 about 30 km upstream in Nahal Paran. Our estimation agrees with flood magnitude estimated from the regional envelope curve of the largest floods. Based on Holocene alluvial stratigraphy and OSL dating in the study reach we also conclude that flood stages did not reach the late Holocene ( 2.2 ka) surface and therefore we estimate a non-exceedance upper bound of  2000 m³s^− 1 flood magnitudes for Nahal Arava during that interval. This study indicates that in unfavorable areas the combination of hydrology, fluvial morphology and botanic evidence can increase our understanding of ungauged basins and give information crucial for hydrology planning.     

Reconstruction of MODIS total suspended matter time series maps by DINEOF and validation with autonomous platform data

In situ measurements of total suspended matter (TSM) over the period 2003–2006, collected with two autonomous platforms from the Centre for Environment, Fisheries and Aquatic Sciences (Cefas) measuring the optical backscatter (OBS) in the southern North Sea, are used to assess the accuracy of TSM time series extracted from satellite data. Since there are gaps in the remote sensing (RS) data, due mainly to cloud cover, the Data Interpolating Empirical Orthogonal Functions (DINEOF) is used to fill in the TSM time series and build a continuous daily “recoloured” dataset. The RS datasets consist of TSM maps derived from MODIS imagery using the bio-optical model of Nechad et al. (Rem Sens Environ 114: 854–866, 2010). In this study, the DINEOF time series are compared to the in situ OBS measured in moderately to very turbid waters respectively in West Gabbard and Warp Anchorage, in the southern North Sea. The discrepancies between instantaneous RS, DINEOF-filled RS data and Cefas data are analysed in terms of TSM algorithm uncertainties, space–time variability and DINEOF reconstruction uncertainty.     

Age,origin and climatic controls on vegetated linear dunes in the northwestern Negev Desert (Israel)

The stabilized northwestern (NW) Negev vegetated linear dunes (VLD) of Israel extend over 1300 km² and form the eastern end of the Northern Sinai – NW Negev Erg. This study aimed at identifying primary and subsequent dune incursions and episodes of dune elongation by investigating dune geomorphology, stratigraphy and optically stimulated luminescence (OSL) dating. Thirty-five dune and interdune exposed and drilled section were studied and sampled for sedimentological analyses and OSL dating, enabling spatial and temporal elucidation of the NW Negev dunefield evolution.In a global perspective the NW Negev dunefield is relatively young. Though sporadic sand deposition has occurred during the past 100 ka, dunes began to accumulate over large portions of the dunefield area only at ～23 ka. Three main chronostratigraphic units, corresponding to three (OSL) age clusters, were found throughout most of the dunefield, indicating three main dune mobilizations: late to post last glacial maximum (LGM) at 18–11.5 ka, late Holocene (2–0.8 ka), and modern (150–8 years). The post-LGM phase is the most extensive and it defined the current dunefield boundaries. It involved several episodes of dune incursions and damming of drainage systems. Dune advancement often occurred in rapid pulses and the orientation of VLD long axes indicates similar long-term wind directions. The late Holocene episode included partial incursion of new sand, reworking of Late Pleistocene dunes as well as limited redeposition. The modern sand movement only reactivated older dunes and did not lengthen VLDs.This aeolian record fits well with other regional aeolian sections. We suggest that sand supply and storage in Sinai was initiated by the Late Pleistocene exposure of the Nile Delta sands. Late Pleistocene winds, substantially stronger than those usually prevailing since the onset of the Holocene, are suggested to have transported the dune sands across Sinai and into the northwestern Negev.Our results demonstrate the sensitivity of vegetated linear dunes located along the (northern) fringe of the sub-tropical desert belt to climate change (i.e. wind) and sediment supply.     

Introduction to hydromechanical well tests in fractured rock aquifers

This article introduces hydromechanical well tests as a viable field method for characterizing fractured rock aquifers. These tests involve measuring and analyzing small displacements along with pressure transients. Recent developments in equipment and analyses have simplified hydromechanical well tests, and this article describes initial field results and interpretations during slug and constant-rate pumping tests conducted at a site underlain by fractured biotite gneiss in South Carolina. The field data are characterized by displacements of 0.3 μm to more than 10 μm during head changes up to 10 m. Displacements are a hysteretic function of hydraulic head in the wellbore, with displacements late in a well test always exceeding those at similar wellbore pressures early in the test. Displacement measurements show that hydraulic aperture changes during well tests, and both scaling analyses and field data suggest that T changed by a few percent per meter of drawdown during slug and pumping tests at our field site. Preliminary analyses suggest that displacement data can be used to improve estimates of storativity and to reduce nonuniqueness during hydraulic well tests involving single wells.     

On the inclusion of ground-based gravity measurements to the calibration process of a global rainfall-discharge reservoir model: case of the Durzon karst system (Larzac, southern France)

This work examines the relevance of the inclusion of ground-based gravity data in the calibration process of a global rainfall-discharge reservoir model. The analysis is performed for the Durzon karst system (Larzac, France). The first part of the study focuses on the hydrological interpretation of the ground-based gravity measurements. The second part of the study investigates further the information content of the gravity data with respect to water storage dynamics modelling. The gravity-derived information is found unable to either reduce equifinality of the single-objective, discharge-based model calibration process or enhance model performance through assimilation.