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11.
Nancy L. Chabot 《Geochimica et cosmochimica acta》2004,68(17):3607-3618
Magmatic
iron meteorites are thought to be samples of the central metallic cores
of asteroid-sized parent bodies. Sulfur is believed to have been an
important constituent of these parental cores, but due to the low
solubility of S in solid metal, initial S-contents for the magmatic
groups cannot be determined through direct measurements of the iron
meteorites. However, experimental solid metal-liquid metal partition
coefficients show a strong dependence on the S-content of the metallic
liquid. Thus, by using the experimental partition coefficients to model
the fractional crystallization trends within magmatic iron meteorite
groups, the S-contents of the parental cores can be indirectly
estimated. Modeling the Au, Ga, Ge, and Ir fractionations in four of
the largest magmatic iron meteorite groups leads to best estimates for
the S-contents of the parental cores of 12 ± 1.5 wt% for
the IIIAB group, 17 ± 1.5 wt% for the IIAB group, and 1
± 1 wt% for the IVB group. The IVA elemental
fractionations are not adequately fit by a simple fractional
crystallization model with a unique initial S-content. These S-content
estimates are much higher than those recently inferred from
crystallization models involving trapped melt. The discrepancy is due
largely to the different partition coefficients that are used by the
two models. When only partition coefficients that are consistent with
the experimental data are used, the trapped melt model, and the low
S-contents it advocates, cannot match the Ge and Ir fractionations that
are observed in IIIAB iron
meteorites. 相似文献
12.
Derek G. Turner Brent C. Ward Duane G. Froese Michel Lamothe Jeffrey D. Bond Nancy H. Bigelow 《Boreas: An International Journal of Quaternary Research》2016,45(3):521-536
At least five Middle to Late Pleistocene advances of the northern Cordilleran Ice Sheet are preserved at Silver Creek, on the northeastern edge of the St Elias Mountains in southwest Yukon, Canada. Silver Creek is located 100 km up‐ice of the Marine Isotope Stage (MIS) 2 McConnell glacial limit of the St Elias lobe. This site contains ~3 km of nearly continuous lateral exposure of glacial and non‐glacial sediments, including multiple tills separated by thick gravel, loess and tilted lake beds. Infrared‐stimulated luminescence (IRSL) and AMS radiocarbon dating constrain the glacial deposits to MIS 2, 4, either MIS 6 or mid‐MIS 7, and two older Middle Pleistocene advances. This chronology and the tilt of the lake beds suggest Pleistocene uplift rates of up to 1.9 mm a?1 along the Denali Fault since MIS 7. The non‐glacial sediment consists of sand, gravel, loess and organic beds from MIS 7, MIS 3 and the early Holocene. The MIS 3 deposits date to between 30–36 14C ka BP, making Silver Creek one of the few well‐constrained MIS 3‐aged sites in Yukon. This confirms that ice receded close to modern limits in MIS 3. Pollen and macrofossil analyses show that a meadow‐tundra to steppe‐tundra mosaic with abundant herbs and forbs and few shrubs or trees, dominated the environment at this time. The stratigraphy at Silver Creek provides a palaeoclimatic record since at least MIS 8 and comprises the oldest direct record of Pleistocene glaciation in southwest Yukon. 相似文献
13.
Nancy England April L. James Krystopher J. Chutko Richard S. Pyrce Huaxia Yao 《水文研究》2019,33(6):905-919
Stable water isotope surveys have increasingly been integrated into river basins studies, but fewer have used them to evaluate impact of hydropower regulation. This study applies hydrologic and water isotope survey approaches to a Canadian Shield river basin with both regulated and natural flows. Historical streamflow records were used to evaluate the influence of three hydroelectric reservoirs and unregulated portions of the basin on downstream flows and changes in water level management implemented after an extreme flood year (1979). In 2013, water isotope surveys of surface and source waters (e.g., rainfall, groundwater, snowmelt) were conducted to examine spatial and temporal variation in contributions to river flow. Seasonal changes in relative groundwater contribution were assessed using a water‐isotope mass balance approach. Within the basin, two regulated reservoirs exhibited inverted hydrographs with augmented winter flows, whereas a third exhibited a hydrograph dominated by spring snowmelt. In 2013, spatial variation in rain‐on‐snow and air temperatures resulted in a critical lag in snowmelt initiation in the southern and northern portions of the basin resulting in a dispersed, double peak spring hydrograph, contrasting with 1979 when a combination of rain‐on‐snow and coincident snowmelt led to the highest flood on record. Although eastern basin reservoirs become seasonally enriched in δ18O and δ2H values, unregulated western basin flows remain less variable due to groundwater driven baseflow with increasing influence downstream. Combined analysis of historical streamflow (e.g., flood of 1979, drought of 2010) and the 2013 water isotope surveys illustrate extreme meteorological conditions that current management activities are unable to prevent. In this study, the influence of evaporative fractionation on large surface water reservoirs provides important evidence of streamflow partitioning, illustrating the value of stable water isotope tracers for study of larger catchments. 相似文献
14.
15.
Sibel Bargu Melissa M. Baustian Nancy N. Rabalais Ross Del Rio Benjamin Von Korff R. Eugene Turner 《Estuaries and Coasts》2016,39(5):1345-1356
The presence of domoic acid (DA) toxin from multiple species of Pseudo-nitzschia is a concern in the highly productive food webs of the northern Gulf of Mexico. We documented the Pseudo-nitzschia presence, abundance, blooms, and toxicity over three years along a transect ~100 km west of the Mississippi River Delta on the continental shelf. Pseudo-nitzschia were present throughout the year and occurred in high abundances (>104 cells l?1) in the early spring months during high Mississippi River (MSR) flow (~20,000 m3 s?1) but were most abundant (>106 cells l?1) when MSR discharge was relatively lower among the spring months. A high particulate toxin production (maximum reaching 13 μg DA l?1) was associated with the high cell abundances and exceeded, by an order of magnitude, prior reports of particulate DA concentrations in Louisiana coastal waters. Differences in Pseudo-nitzschia peak times and its toxicity were correlated mainly with the timing and magnitude of MSR discharge and changes in associated parameters such as nutrient stoichiometry and salinity. A negative relationship between high MSR discharge and Pseudo-nitzschia and particulate DA concentrations was documented. These riverine dynamics have the potential to influence DA contamination in pelagic and benthic food webs in the coastal waters of the northern Gulf of Mexico. 相似文献
16.
Nancy L. Chabot Rachel H. Cueva Andrew W. Beck Richard D. Ash 《Meteoritics & planetary science》2020,55(4):726-743
Some of the defining characteristics of the IIG iron meteorite group are their high bulk P contents and massive, coarse schreibersite, which have been calculated to make up roughly 11–14 wt% of each specimen. In this study, we produced two data sets to investigate the formation of schreibersites in IIG irons: measurements of trace elements in the IIG iron meteorite Twannberg and experimental determinations of trace element partitioning into schreibersite. The schreibersite‐bearing experiments were conducted with schreibersite in equilibrium with a P‐rich melt and with bulk Ni contents ranging from 0 to 40 wt%. The partitioning behavior for the 20 elements measured in this study did not vary with Ni content. Comparison of the Twannberg measurements with the experimental results required a correction factor to account for the fact that the experiments were conducted in a simplified system that did not contain a solid metal phase. Previously determined solid metal/P‐rich melt partition coefficients were applied to infer schreibersite/solid metal partitioning behavior from the experiments, and once this correction was applied, the two data sets showed broad similarities between the schreibersite/solid metal distribution of elements. However, there were also differences noted, in particular between the Ni and P contents of the solid metal relative to the schreibersite inferred from the experiments compared to that measured in the Twannberg sample. These differences support previous interpretations that subsolidus schreibersite evolution has strongly influenced the Ni and P content now present in the solid metal phase of IIG irons. Quantitative attempts to match the IIG solid metal composition to that of late‐stage IIAB irons through subsolidus schreibersite growth were not successful, but qualitatively, this study corroborates the striking similarities between the IIAB and IIG groups, which are highly suggestive of a possible genetic link between the groups as has been previously proposed. 相似文献
17.
Kastelein RA Verboom WC Jennings N de Haan D van der Heul S 《Marine environmental research》2008,66(3):319-326
Two harbor porpoises in a floating pen were subjected to five pure tone underwater signals of 70 or 120kHz with different signal durations, amplitudes and duty cycles (% of time sound is produced). Some signals were continuous, others were intermittent (duty cycles varied between 8% and 100%). The effect of each signal was judged by comparing the animals' surfacing locations and number of surfacings (i.e. number of respirations) during test periods with those during baseline periods. In all cases, both porpoises moved away from the sound source, but the effect of the signals on respiration rates was negligible. Pulsed 70kHz signals with a source level (SL) of 137dB had a similar effect as a continuous 70kHz signal with an SL of 148dB (re 1muPa, rms). Also, a pulsed 70kHz signal with an SL of 147dB had a much stronger deterring effect than a continuous 70kHz signal with a similar SL. For pulsed 70kHz signals (2s pulse duration, 4s pulse interval, SL 147dB re 1muPa, rms), the avoidance threshold sound pressure level (SPL), in the context of the present study, was estimated to be around 130dB (re 1muPa, rms) for porpoise 064 and around 124dB (re 1muPa, rms) for porpoise 047. This study shows that ultrasonic pingers (70kHz) can deter harbor porpoises. Such ultrasonic pingers have the advantage that they do not have a "dinner bell" effect on pinnipeds, and probably have no, or less, effect on other marine fauna, which are often sensitive to low frequency sounds. 相似文献
18.
19.
20.
Mysid shrimps are an important component of estuarine food webs because they play a key role in energy transfer as intermediate prey. We investigated the seasonal, tidal and depth specific variation in the diet of the estuarine mysids Neomysis integer and Rhopalophthalmus tartessicus and explored its implications for the planktonic community structure of a temperate estuary (Guadalquivir Estuary, SW Spain). Neomysis integer is an opportunistic omnivore feeding mainly on mesozooplankton and on members of the detrital–microbial loop, shifting prey seasonally according to availability. In contrast, R. tartessicus showed a more carnivorous diet and shifted its target prey during seasons of low resource availability. Despite statistically significant differences in diet composition, both species shared prey of similar size, particularly juvenile Mesopodopsis slabberi, the most abundant mysid species in this estuary, and copepods. Although these similarities imply inter-specific resource competition, their co-existence is achieved by niche partitioning and spatial segregation: the higher osmoregulatory capacity and foraging plasticity of N. integer confers a broader niche breadth for this species allowing N. integer to inhabit the more stressful oligohaline region of the estuary where R. tartessicus cannot survive. We propose that this mechanism relaxes the potential for competition between N. integer and R. tartessicus. 相似文献