The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell:

Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag

where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell:

Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag

The results have been fitted to the equations:

lnK^*₁ = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S^0.5 + 0.08468345S − 0.00654208S¹

InK^*₂ = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S^0.5 + 0.1130822S − 0.00846934S^1.5

where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.     

Lake Floor Morphology and Sediment Architecture of Lake Torneträsk,Northern Sweden

Here we present datasets from a hydroacoustic survey in July 2011 at Lake Torneträsk, northern Sweden. Our hydroacoustic data exhibit lake floor morphologies formed by glacial erosion and accumulation processes, insights into lacustrine sediment accumulation since the beginning of deglaciation, and information on seismic activity along the Pärvie Fault. Features of glacial scouring with a high‐energy relief, steep slopes, and relative reliefs of more than 50 m are observed in the large W‐basin. The remainder of the lacustrine subsurface appears to host a broad variety of well preserved formations from glacial accumulation related to the last retreat of the Fennoscandian ice sheet. Deposition of glaciolacustrine and lacustrine sediments is focused in areas situated in proximity to major inlets. Sediment accumulation in distal areas of the lake seldom exceeds 2 m or is not observable. We assume that lack of sediment deposition in the lake is a result of different factors, including low rates of erosion in the catchment, a previously high lake level leading to deposition of sediments in higher elevated paleodeltas, tributaries carrying low suspension loads as a result of sedimentation in upstream lakes, and an overall low productivity in the lake. A clear off‐shore trace of the Pärvie Fault could not be detected from our hydroacoustic data. However, an absence of sediment disturbance in close proximity to the presumed fault trace implies minimal seismic activity since deposition of the glaciolacustrine and lacustrine sediments.     

A Holocene high-resolution record of aquatic productivity,seasonal anoxia and meromixis from varved sediments of Lake Łazduny,North-Eastern Poland: insight from a novel multi-proxy approach

Anthropogenic eutrophication and spreading anoxia in freshwater systems is a global concern. Little is known about anoxia in earlier historic times under weaker human impact, or under prehistoric natural conditions with different trophic, land cover and climatic regimes. We use a novel approach that combines high-resolution hyperspectral imaging with µ-XRF and HPLC-pigment data, which allows us to assess chloropigments (productivity) and bacteriopigments (anoxia) at seasonal subvarve-scale resolution. Our ~9700 cal a bp varved sediment record from NE Poland suggests that productivity increased stepwise from oligotrophic Early Holocene conditions (until ~9200 cal a bp ) to mesotrophic conditions in the Mid- and Late Holocene. Natural eutrophication was mainly a function of progressing landscape evolution with intense weathering under dense forest and warm-moist climatic conditions. Generally, anoxia increased with increasing productivity. Seasonal anoxia and some multi-decadal periods of meromixis were the common mixing patterns throughout the Holocene except for a period of persisting meromixis between ~5200 and 2000 cal a bp. Anthropogenic deforestation around 400 cal a bp resulted in substantially better lake oxygenation despite high productivity. In this small lake, aquatic productivity and lakeshore forest cover (wind shield) were more important factors controlling oxic/anoxic conditions than Holocene temperature variability.     

The Berchtesgaden National Park (Bavaria, Germany): a platform for interdisciplinary catchment research

The Berchtesgaden National Park (Bavaria, Germany), a study site of the UNESCO Man and the Biosphere program in the catchment of Berchtesgadener Ache, is introduced as a platform for interdisciplinary research. As the investigation of how human activities affect the natural resources in the park area, which has been defined a main aim of the program, naturally requires expertise from different scientific fields, interdisciplinary research has been fostered in the national park plan since the very beginning of the Man and the Biosphere program in 1981. To analyze the complex interactions and mutual dependencies between socio-economic and natural systems, a variety of monitoring programs have been initialized in different disciplines (e.g. climate sciences, zoology, botany) that are addressed in this paper. As a result of these research efforts, the park offers a profound data basis to be used in future studies (e.g. land cover classifications, maps of geological and soil conditions). Detailed information is provided on a climate monitoring network that has been installed in the park starting in the year 1993. The network has been continuously extended over the years and now provides extraordinary comprehensive information on meteorological conditions in the park, setting the basis for current as well as for potential future climate-related studies. A special characteristic of the station network is the fact that it covers a large range of elevations from 600 m a.s.l in the valleys to 2,600 m a.s.l in the summit regions and is therefore able to capture altitudinal gradients in meteorological variables as typical for Alpine regions. Due to the large number of stations in high elevations (15 stations are in elevations higher than 1,500 m a.s.l) the network provides information on the complex hydrometeorological conditions in summit regions which are often insufficiently represented in observation networks due to the increased costs for maintenance of climate stations in these locations. Beside the various monitoring programs, a variety of numerical models have been (further) developed for application in the park area that make extensive use of the different data collected and therefore largely benefit from the comprehensive data pool. The potential and necessity of the climate monitoring network for modelling studies is demonstrated by utilizing the meteorological recordings in the framework of a hydrometeorological simulation experiment. Further examples of environmental modelling efforts are shortly described together with preliminary model results.     

Hypercube-Based Visualization Architecture for Web-Based Environmental Geospatial Information Systems

The geospatial field significantly influences the development of the environmental domain, including a wide range of geospatial and cartographic information systems, such as Geographic Information Systems (GIS), Multimedia Atlas Information Systems (MAIS) and more recently web-based GIS (Web-GIS). In this context, we introduce web-based environmental geospatial information systems (Web-EGIS) as a special case of Web-GIS, aiming to integrate the functionalities of geospatial information systems with the enormous quantity of specialized, distributed and highly heterogeneous environmental geo-referenced data and services. We define three main characteristics of the Web-EGIS. The first is a generic hypercube-based data organization and visualization. The next characteristic is a standard-based, three-tier service-oriented architecture. The third and last characteristic is the traceability of the architectural and design decisions, for which we introduce the new concept of an ‘Environmental Application Context’, arguing that not only the functional but also the non-functional requirements (NFRs) have an important role in defining the architecture, software components and data services of such systems. In a nutshell, a Web-EGIS is characterized by a coherent user experience through the hypercube-based visualization concept, technically supported by a service-oriented architecture that is structured according to an extensive analysis of NFRs. On this basis, we introduce the Geodata visualization and interactive training environment (GeoVITe) Platform for Interdisciplinary Environmental Research as a reference implementation of a Web-EGIS with its basic design requirements, integrative hypercube-based visualization for heterogeneous data sources, extended web cartography functionalities, and its de facto system architecture. The concept of the hypercube-based visualization is better transferred to the system architecture by understanding the ‘Environmental Application Context’ of this particular Web-EGIS, which also makes it easier to maintain and enhance. The resulting system is a support platform for research activities in the environmental domain.     

Geomagnetic paleosecular variation at Hawaii around 3 Ma from a sequence of 107 lava flows at Kaena Point (Oahu)

We have sampled a sequence of 107 lava flows in the Waianae series on Oahu, Hawaii, in two separate stretches. The first (51 flows) at Kaena Point extends from sea level to an altitude of 190 m, and the second (56 flows) follows the Satellite Tracking Station road from 218 m to 360 m above sea level. Thermal and af demagnetization yield very similar results, and reveal only normal polarities. K/Ar dating at five different horizons combined with the paleomagnetic results indicate that the sequence was emplaced entirely in the normal polarity interval between the Upper Mammoth and the Lower Kaena polarity transitions (3.22–3.11 Ma). Some of the flows are serially correlated. Filtering does not, however, drastically affect the final results. Inclinations are shallower than those expected from a centered dipole field. Although large (13°), the inclination anomaly is consistent with results from other sites at the same latitude. The scatter of the VGPs about the geographic pole is consistent with available data from other regions at similar latitudes. The scatter of the directions is also consistent with the predictions of recent statistical models of paleosecular variation. Therefore, these results do not support the hypothesis of a Pacific dipole window.     

Une approche innovante pour modéliser la biodégradation des composés organochlorés volatils en aquifères poreux

The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006).     

Geochemistry of silicic magmas in the Macolod Corridor, SW Luzon, Philippines: evidence of distinct, mantle-derived, crustal sources for silicic magmas

Silicic volcanic deposits (>65 wt% SiO₂), which occur as domes, lavas and pyroclastic deposits, are relatively abundant in the Macolod Corridor, SW Luzon, Philippines. At Makiling stratovolcano, silicic domes occur along the margins of the volcano and are chemically similar to the silicic lavas that comprise part of the volcano. Pyroclastic flows are associated with the Laguna de Bay Caldera and these are chemically distinct from the domes and lavas at Makiling stratovolcano. As a whole, samples from the Laguna de Bay Caldera contain lower concentrations of MgO and higher concentrations of Fe₂O_3(t) than the samples from domes and lavas. The Laguna de Bay samples are more enriched in incompatible trace elements. The silicic rocks from the domes, Makiling Volcano and Laguna de Bay Caldera all contain high alkalis and high K₂O/Na₂O ratios. Melting experiments of primitive basalts and andesites demonstrate that it is difficult to produce high K₂O/Na₂O silicic magmas by fractional crystallization or partial melting of a low K₂O/Na₂O source. However, recent melting experiments (Sisson et al., Contrib Mineral Petrol 148:635–661, 2005) demonstrate that extreme fractional crystallization or partial melting of K-rich basalts can produce these silicic magmas. Our model for the generation of the silicic magmas in the Macolod Corridor requires partial melting of mantle-derived, evolved, moderate to K-rich, crystallized calc-alkaline magmas that ponded and crystallized in the mid-crust. Major and trace element variations, along with oxygen isotopes and ages of the deposits, are consistent with this model. Electronic Supplementary Material Supplementary material is available for this article at     

Magma mixing: the Marsco suite,Isle of Skye,Scotland

Magma mixing has been proposed as a major mechanism for the origin of a wide variety of rock suites. In mid-ocean basalts there are few obstacles to mixing because of the similarities in chemical and physical properties of the proposed end-members. However, in calc-alkaline rocks the proposed end-members have disparate properties and these present obstacles to mixing.The Marsco suite is ideal to evaluate the process of magma mixing because it is considered to be a classic example of magma mixing of diverse magma types and because compositionally diverse, coexisting liquids were present throughout the area.The results of this study are that the chemical data for the Marsco suite fit a mixing model remarkably well and that the mixing did not take place at the present level of exposure. The Marsco mixed suite is similar to the experiments of Kouchi and Sunagawa (1982, 1983) in which mixing was produced by forced convection. Based on the Marsco suite, a similar occurrence in Ardnamurchan, and the experimental data, we conclude that mixing was dominated by mechanical mixing and this mechanical mixing was efficient enough to allow diffusional processes to homogenize the liquids.It is postulated that injection of mafic magma into the base of a silicic magma system leads to mixing and mobilization of the system. The mechanical interaction that produces the mixing also leads to disruption of the system. Liquids involved with the mixing process at depth are mobilized and coexist at shallower levels.