Space-time interaction amongst clusters of mining induced seismicity

Elementary cluster analysis of induced seismicity in a South African gold mine has shown that there is a clear interaction amongst the clusters; and that the level of the interaction is a function of the distance. The clusering algorithm used is an adaptation of the single-link cluster analysis which considers both three-dimensional space and time. A high level of interaction between the clusters is demonstrated from the cross-correlation analysis of seismic activity rates and radiated energy. A distinct decrease in the value of correlation coefficients was detectable as distance increased. This was somewhat surprising, considering the simplicity of the technique used. Since no attempt is made to study the physical mechanisms of interaction, these results are very preliminary, but interesting from an observational point of view.     

The use of acidimetric titration as a novel approach to study particulate trace metal speciation and mobility: Application to sediments of the Scheldt estuary

The study of trace metal speciation has benefited from a great deal of interest leading to the development and the diversification of sequential extraction schemes (SES), which triggered the need for harmonization by the standard, measurements and testing programme (SM & T). However, some uncertainties still persist in the application of the harmonized 3-step protocol, because of the difficulty in conceptualizing a technique that can be applied to environmental samples irrespective of their nature. The alternative method proposed in this study is based on the solubility of the sample components progressively dissolved during the course of an acidimetric titration by 1 mol L⁻¹ HCl. The major HCl-reactive mineralogical components are identified using mass balance calculation of H⁺ consumed by their dissolution together with the amount of major elements released into solution. The speciation of minor and trace elements is investigated by comparing their titrations to those of the major elements. This approach is much simpler than SES because it uses simple non-selective H⁺ at room temperature instead of a complex experimental design of so-called specific reagents. The different mineral components of the solid are no longer operationally defined and the problem of selectivity is irrelevant to the titration approach. The method was applied to several sediment samples from the Scheldt estuary and the particulate phase was further examined by Scanning Electron Microprobe and X-ray Diffraction techniques. The nearly complete consumption of H⁺ in the suspension is balanced by the total dissolution of carbonates and Fe-oxyhydroxides. In contrast to the speciation inferred from the Tessier SES, the acidimetric titration has demonstrated that the carbonate phase does not significantly contain trace metals with the exceptions of 40% of the Mn and 30% of the Co. In contrast, the Fe-oxyhydroxides seem to play a major role and account for 70% of Pb and 20% of Cr, in addition to 60% of P and additional amounts of 20% Co and 40% Mn. 70% of the Cu also occur in the oxyhydroxide phase, more likely coprecipitated with gibbsite. 90% of the Cd and 85% of Zn can be attributed to the Acid Volatile Sulfide (AVS) phase as evidenced from S titration. The acidimetric titration method not only provides information on the speciation of trace metals but also allows the quantification of their reactivity and mobility, if one considers that the titration roughly mimics pH changes that may occur as a result of chemical disequilibrium in the environment. The results demonstrate the potential of the acidimetric titration as an alternative to SES protocols in geochemical and environmental regulation studies. This method is applicable to a wide variety of environmental materials with little or minor adjustments.     

PROBLEMS IN CONSTRUCTING A BATHYMETRIC BASE MAP FOR THE GULF OF FINLAND

The various steps required for compilation of a bathymetric chart of the Gulf of Finland are outlined, taking into account the specific conditions characteristic of that water body. The use of available initial source materials and special survey work required for supplementing these sources is discussed. Translated by Edward Torrey, Alexandria, VA 22308 from: Geodeziya i kartografiya, 1988, No. 8, pp. 40-42.     

Saturn's electrostatic discharges: Could lightning be the cause?

It is proposed that Saturn's electrostatic discharges (SED) might be generated in the planet's equatorial atmosphere, perhaps as lightning from a storm system. The 10^h10^m periodicity of the signal envelope duplicates that of Saturn's equatorial jet. The rings shield the atmosphere from solar EUV photons, and thereby substantially reduce the local ionospheric cutoff frequency to allow low-frequency SED to leak out. Many of the unusual properties of SED could be explained in terms of changes in the storm system, the relative spacecraft position in the beaming pattern of the source, local refraction of the signal by the highly disturbed ionosphere, and the influence of the ring particles on the highest frequency component of SED. A comparison of SED with planetary lightning on other planets shows that the two are similar in general character and some time behavior; the power output of SED may be higher than most planetary lightnings but that is unclear because of uncertainties in the measurements and variations in the signal's spectrum. Our simple discussion suggests that lightning could be a viable source for SED and that exotic ring mechanisms are not necessarily required.     

Experimental determination of the reaction dolomite + 2 coesite = diopside + 2 CO2 to 6 GPa

 The carbonation reaction CaMg(CO₃)₂ (dolomite)+2SiO₂ (coesite)=CaMgSi₂O₆ (diopside)+2 CO₂ (vapor) has been determined experimentally between 3.5 and 6 GPa in a multiple-anvil, solid-media apparatus. This reaction, a candidate for carbonation of eclogites (garnet+clinopyroxene) in the Earth’s mantle, lies at higher pressure for a given temperature than do the carbonation reactions for peridotites (olivine+orthopyroxene±clinopyroxene). A depth interval may exist within the Earth’s mantle under either ‘normal’ or ‘subduction’ thermal regimes where carbonated peridotite could coexist with carbonate-free, CO₂-bearing eclogite. Received: 25 May 1994/Accepted: 13 June 1995     

Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia)

The results of the first study of the PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia) are presented here. The complex character of evolution of the PGE composition in the Deformed lherzolites is assumed to be the result of silicate metasomatism. At the first stage, growth in the amount of clinopyroxene and garnet in the rock is accompanied by a decrease in the concentration of the compatible PGE (Os, Ir). During the final stage, the rock is enriched with incompatible PGE (Pt, Pd) and Re possible due to precipitation of submicron-sized particles of sulfides in the interstitial space of these mantle rocks.     

Sensitive observations of radio recombination lines in Orion and W51: the data and detection of systematic recombination line blueshifts proportional to impact broadening

Sensitive spectral observations made in two frequency bands near 6.0 and 17.6 GHz are described for Orion and W51. Using frequency switching we were able to achieve a dynamic range in excess of 10,000 without fitting sinusoidal or polynomial baselines. This enabled us to detect lines as weak as T _A ∼1 mK in these strong continuum sources. Hydrogen recombination lines with Δn as high as 25 have been detected in Orion. In the Orion data, where the lines are stronger, we have also detected a systematic shift in the line center frequencies proportional to linewidth that cannot be explained by normal optical depth effects.