Measurements in N2-CH4(C2H2) discharges of reaction rates and thermochemical constants for Titan atmosphere study

The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K.     

Preliminary Results from the Magnetic Field Measurements Using MAGDAS at Ilorin, Nigeria

MAGDAS, the Magnetic Data Acquisition System, was successfully installed at the University of Ilorin, Nigeria—an equatorial station—in August 2006. MAGDAS is an important component of the International Heliophysical Year, IHY. We examined the preliminary results obtained from the analysis of the geomagnetic data obtained from the MAGDAS measurement. Diurnal variations of the solar quiet daily variation in the three geomagnetic elements, H, D, Z were studied. The obtained signatures of the magnetic field variations were discussed in the context of the literature. The day-to-day variability of the horizontal and vertical intensities as well as the declination of the geomagnetic field were examined. The study justified the need for a partner magnetic field observatory along same meridian as Ilorin, north or south of it, to facilitate synthesis of the equatorial electrojet effect.     

Post-solidification cooling and the age of Io's lava flows

The modeling of thermal emission from active lava flows must account for the cooling of the lava after solidification. Models of lava cooling applied to data collected by the Galileo spacecraft have, until now, not taken this into consideration. This is a flaw as lava flows on Io are thought to be relatively thin with a range in thickness from ∼1 to 13 m. Once a flow is completely solidified (a rapid process on a geological time scale), the surface cools faster than the surface of a partially molten flow. Cooling via the base of the lava flow is also important and accelerates the solidification of the flow compared to the rate for the ‘semi-infinite’ approximation (which is only valid for very deep lava bodies). We introduce a new model which incorporates the solidification and basal cooling features. This model gives a superior reproduction of the cooling of the 1997 Pillan lava flows on Io observed by the Galileo spacecraft. We also use the new model to determine what observations are necessary to constrain lava emplacement style at Loki Patera. Flows exhibit different cooling profiles from that expected from a lava lake. We model cooling with a finite-element code and make quantitative predictions for the behavior of lava flows and other lava bodies that can be tested against observations both on Io and Earth. For example, a 10-m-thick ultramafic flow, like those emplaced at Pillan Patera in 1997, solidifies in ∼450 days (at which point the surface temperature has cooled to ∼280 K) and takes another 390 days to cool to 249 K. Observations over a sufficient period of time reveal divergent cooling trends for different lava bodies [examples: lava flows and lava lakes have different cooling trends after the flow has solidified (flows cool faster)]. Thin flows solidify and cool faster than flows of greater thickness. The model can therefore be used as a diagnostic tool for constraining possible emplacement mechanisms and compositions of bodies of lava in remote-sensing data.     

Biosorption of methylene blue from aqueous solutions by Typha angustata phytomass

The objective of this study was to investigate the biosorption of an azo dye (Methylene blue) by a wetland phytomass (Typha angustata) under post-phytoremediation scenario. Thus, the phytomass was used without any chemical modification. The batch adsorption experiments were conducted to evaluate the effects of contact time and temperatures (25–45 °C) on the adsorption of methylene blue (MB) from aqueous solution by cattail phytomass (CP). More than 80 % of MB dye was removed from the aqueous solution within first 10 min of the experiment. Langmuir isotherm was modeled to describe the monolayer adsorption of MB dye (R ² = 0.995) with the maximum adsorption capacity of 8.1 mg/g at 25 °C. Pseudo-second-order kinetic model adequately described the kinetics of absorption process (R ² = 0.999). The adsorption of MB on the cattail phytomass was a spontaneous and endothermic process that was governed by chemisorption. Hence, CP could be applied as a potential low cost biosorbent to treat dyeing wastewater.     

Micromechanics approach to poroelastic behavior of a jointed rock

The formulation of macroscopic poroelastic behavior of a jointed rock is investigated within the framework of a micro–macro approach. The joints are modeled as interfaces, and their behavior is modeled by means of generalized poroelastic state equations. Starting from Hill's lemma extended for a jointed medium and extending the concept of strain concentration to relate the joint displacement jump to macroscopic strain, the overall poroelastic constitutive equations for the jointed rock are formulated. The analysis emphasizes the main differences and similarities of the resulting behavior with respect to that characterizing ordinary porous media. It is shown that, unlike ordinary porous media, conditions on the poroelastic parameters of joints are required for the macroscopic drained stiffness to entirely define the poroelastic behavior. This is achieved, for instance, if the joint network is characterized by a unique Biot coefficient. Extension of the analysis to non‐linear poroelasticity is also outlined. Finally, the theoretical formulation is applied to two particular cases of jointed rock for which explicit expressions of the overall poroelastic parameters are derived. Copyright © 2011 John Wiley & Sons, Ltd.     

Crustal structure of the Ordovician Macquarie Arc,Eastern Lachlan Orogen,based on seismic‐reflection profiling

In the Eastern Lachlan Orogen, the mineralised Molong and Junee‐Narromine Volcanic Belts are two structural belts that once formed part of the Ordovician Macquarie Arc, but are now separated by younger Silurian‐Devonian strata as well as by Ordovician quartz‐rich turbidites. Interpretation of deep seismic reflection and refraction data across and along these belts provides answers to some of the key questions in understanding the evolution of the Eastern Lachlan Orogen—the relationship between coeval Ordovician volcanics and quartz‐rich turbidites, and the relationship between separate belts of Ordovician volcanics and the intervening strata. In particular, the data provide evidence for major thrust juxtaposition of the arc rocks and Ordovician quartz‐rich turbidites, with Wagga Belt rocks thrust eastward over the arc rocks of the Junee‐Narromine Volcanic Belt, and the Adaminaby Group thrust north over arc rocks in the southern part of the Molong Volcanic Belt. The seismic data also provide evidence for regional contraction, especially for crustal‐scale deformation in the western part of the Junee‐Narromine Volcanic Belt. The data further suggest that this belt and the Ordovician quartz‐rich turbidites to the east (Kirribilli Formation) were together thrust over ?Cambrian‐Ordovician rocks of the Jindalee Group and associated rocks along west‐dipping inferred faults that belong to a set that characterises the middle crust of the Eastern Lachlan Orogen. The Macquarie Arc was subsequently rifted apart in the Silurian‐Devonian, with Ordovician volcanics preserved under the younger troughs and shelves (e.g. Hill End Trough). The Molong Volcanic Belt, in particular, was reworked by major down‐to‐the‐east normal faults that were thrust‐reactivated with younger‐on‐older geometries in the late Early ‐ Middle Devonian and again in the Carboniferous.