Silica-merrihueite/roedderite-bearing chondrules and clasts in ordinary chondrites: New occurrences and possible origin

Abstract Merrihueite (K,Na)₂(Fe, Mg)₅Si₁₂O₃₀ (na < 0.5, fe > 0.5, where na = Na/(Na + K), fe = Fe/(Fe + Mg) in atomic ratio) is a rare mineral described only in several chondrules and irregularly-shaped fragments in the Mezö-Madaras L3 chondrite (Dodd et al., 1965; Wood and Holmberg, 1994). Roedderite (Na,K)₂(Mg, Fe)₅Si₁₂O₃₀ (na > 0.5, fe < 0.5) has been found only in enstatite chondrites and in the reduced, subchondritic silicate inclusions in IAB irons (Fuchs, 1966; Rambaldi et al., 1984; Olsen, 1967). We describe silica-roedderite-bearing clasts in L/LL3.5 ALHA77011 and LL3.7 ALHA77278, a silica-roedderite-bearing chondrule in L3 Mezö-Madaras, and a silica-merrihueite-bearing chondrule in L/LL3.5 ALHA77115. The findings of merrihueite and roedderite in ALHA77011, ALHA77115, ALHA77278 and Mezö-Madaras fill the compositional gap between previously described roedderite in enstatite chondrites and silicate inclusions in IAB irons and merrihueite in Mezö-Madaras, suggesting that there is a complete solid solution of roedderite and merrihueite in meteorites. We infer that the silica- and merrihueite/roedderite-bearing chondrules and clasts experienced a complex formational history including: (a) fractional condensation in the solar nebula that produced Si-rich and Al-poor precursors, (b) melting of fractionated nebular solids resulting in the formation of silica-pyroxene chondrules, (c) in some cases, fragmentation in the nebula or on a parent body, (d) reaction of silica with alkali-rich gas that formed merrihueite/roedderite on a parent body, (e) formation of fayalitic olivine and ferrosilite-rich pyroxene due to reaction of silica with oxidized Fe on a parent body, and (f) minor thermal metamorphism, possibly generated by impacts.     

Application of Air Decks in Production Blasting to Improve Fragmentation and Economics of an Open Pit Mine

In blasting with air decks, repeated oscillation of shock waves within the air gap increases the time over which it acts on the surrounding rock mass by a factor at between 2 and 5. The ultimate effect lies in increasing the crack network in the surrounding rock and reducing the burden movement. Trials of air deck blasting in the structurally unfavourable footwall side of an open pit manganese mine has resulted in substantial improvements in fragmentation and blast economics. Better fragmentation resulted in improved shovel loading efficiency by 50–60%. Secondary blasting was almost eliminated. Use of ANFO explosive with this technique reduced explosive cost by 31.6%. Other benefits included reductions in overbreak, throw and ground vibration of the order of 60–70, 65–85 and 44% respectively. This paper reviews the theory of air deck blasting and describes in detail the air deck blast trials conducted in a manganese open pit mine in India. The blast performance data have been analysed to evaluate the benefits of air decking over conventional blasting.     

Buckling of Piles under Liquefied Soil Conditions

The paper pertains to the analysis of piles embedded in liquefiable soils to predict its’ critical buckling load under partial to full loss of lateral support over a portion of the pile length. The analysis is based on extension of Mindlin solution for a point load acting inside a semi infinite elastic half space. Degenerated solutions obtained by using the developed method compares very well with reported results. Parametric studies showed that the depth of liquefiable soil, degradation of soil strength on liquefaction, slenderness ratio, pile stiffness factor and end conditions have significant influence on the buckling behavior of the piles.     

The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment)

²³⁰Th, ²³²Th and ²³⁴Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between ²³⁴Th and ²³⁰Th. ²³⁴Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. ²³⁰Th_xs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between ²³⁰Th_xs and CaCO₃ or biogenic silica (bSi) indicates that CaCO₃ and bSi are not responsible for ²³⁰Th scavenging in the deep waters of this oceanic region. ²³⁰Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for ²³⁰Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO₂ could be the prevalent ²³⁰Th_xs-bearing phase. The narrow range of K_{d_MnO2}^Th obtained for very contrasted oceanic environments supports a global control of ²³⁰Th_xs scavenging by MnO₂ and raises the possibility that the ²³⁰Th–²³¹Pa fractionation is controlled by the amount of colloidal MnO₂ in seawater.     

Temporality of disasters: The politics of women's livelihoods ‘after’ the 2004 tsunami in Sri Lanka

The devastation caused by the 2004 Indian Ocean tsunami in Sri Lanka is represented as a ‘natural disaster’. Yet, the tsunami did not occur in a sociopolitical and historical vacuum. How people responded to the tsunami, the challenges of and attitudes to relocation and post‐tsunami livelihoods, were/are shaped by uneven development, social exclusion and ethnonationalist war. All these responses are embedded in structures of gender, caste, class, and ethnicity. The tsunami, thus, brought to the forefront preexisting inequalities, showing up complexities in the temporality of disasters. Drawn from fieldwork in two coastal areas in the Southern and Eastern provinces, this paper shows how gendered structures within the local political economy influenced the ways that institutional actors as well as the displaced communities and women initially devised livelihood strategies. These reactions show how place matters as much as preexisting gendered political economy conditions and reveal the complex ways in which women continue to mediate and negotiate everyday responses in the aftermath of a ‘natural’ disaster.     

Organic matter of the North Atlantic

The areas that we studied in the North Atlantic (53 and 60°N) and in the Labrador Sea in the summer were characterized by a wide variability of the concentrations of dissolved and particulate organic matter and its elemental composition both in the surface and in the deep waters. The concentrations of dissolved and particulate C_org varied within 69–360 μM and 0.7–25.6 μM, respectively; the N_org and P_org contents varied within 1.4–22.2 μM and 0.02–0.86 μM, respectively. The maximal concentrations were registered in the photic layer and in the zones of mixing between the waters of different genesis. The particulate matter contribution to the total organic matter (OM) content varied from 0.5 to 15.4%. The waters of the photic layer contained more particulate C_org than those of the near-bottom layer. The values of the C/N molar ratios from the surface to the bottom over the entire aquatic area surveyed varied 5-to 6-fold; at that, the values of the C/P molar ratios varied more than tenfold. In the most productive waters, the values of the C/N ratios were close to the Redfield ratios (6–10). The values of the C/P molar ratios varied from 160 in the photic layer to 4831 in the deep waters. The pronounced non-uniformity in the spatial distribution of the OM and its elemental composition is caused not only by the penetration of the waters of different origins but also by the changes in the microplankton metabolism under mixing of these waters.     

Reanalysis of seasonal and interannual variability of Black Sea fields for 1993–2012

A retrospective analysis has been done for the hydrophysical fields of the Black Sea for 1993–2012 with the assimilation of undisturbed monthly average profiles of temperature and salinity that were obtained by using an original procedure of joint processing of satellite altimetry and rare hydrological observations. The accuracy of the reconstructed fields of temperature and salinity of the Black Sea is evaluated by comparison with the data of sounding from the hydrological stations and the Argo floats. A comparative analysis is performed for the integral characteristics of the fields of temperature, salinity, and kinetic energy with the same characteristics of the reanalysis for 1992–2012 that assimilated the average annual profiles of temperature and salinity, surface temperature and altimetry level of the sea after being adjusted with respect to climate seasonal variability. The proposed procedure of the reanalysis execution allows a more precise reconstruction of the interannual variability of temperature and salinity stratification in the main pycnocline. The correlation between the annual and seasonal variability of the eddy of the wind friction tangential stress and the average kinetic energy at the levels is revealed.     

Estimation of the deep density distribution in the lithosphere of central and Southern Asia using data about free mantle surface depth

The results of the selection of a model of the deep density distribution in the lithosphere of Central and Southern Asia, which explains the previously revealed dependence of the free mantle surface depth on the thickness of the crust [Artemjev, 1975], are described. It is shown that this dependence can be caused by variations in the mantle’s density with depth. Models of the continental and oceanic mantles with an increase in the linear density over depth are selected for the region of Asia. The level of the free surface depth in the oceanic mantle is higher than in the continental mantle. The observed dependence on the crustal thickness can also be used for determining nonlinear density variations with depth under the assumption that lateral density variations in this dependence are of a random character.     

Variability of sediment diatom assemblages in an upland,wind-stressed lake (Loch Fleet,Galloway, S.W. Scotland)

The variability of diatom distribution in an acidified, upland wind-stressed lake (Loch Fleet, Galloway, S. W. Scotland) was assessed by analysis of 28 surface sediment samples and 11 cores. Correspondence analysis (CA) and cluster analysis were used to illustrate the variability of the surface sediment and core samples. There was reasonable uniformity of taxa in most of the surface sediment samples, although 7 samples, as indicated by both CA and cluster analyses were atypical. Most cores recorded clearly the acidification of the lake, although percentages of individual taxa varied up to 20% between cores. Two cores had old, preacidification diatom assemblages (of indeterminate age) close to the sediment surface. These old sediments were probably the source of the re-worked diatoms found in the atypical surface sediment assemblages. Diatom trends, as CA ordinations and pH profiles, were less variable than the surface sediment assemblages. It is argued that non-uniform sediment accumulation rates and diatom deposition cause variability in surface sediment diatom samples. This variability may be reduced in core profiles by homogenization during further resuspension/deposition cycles and burial. Cores, and the associated time component they offer, may be useful in assessing the variability of surface sediment assemblages.