The stable isotope signature of kilometre-scale fracturedominated metamorphic fluid pathways, Mary Kathleen, Australia

Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ¹³C_calcite values of –2 to –7% and δ¹⁸O_calcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ¹⁸O_whole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ¹³C_calcite of –1.6 to –0.6%, and δ¹⁸O_calcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ¹⁸O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ¹⁸O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ¹³C vs. δ¹⁸O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.     

Timing and tectonic setting of Grenvillian metamorphism—constraints from a transect along Georgian Bay,Ontario*

Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.     

A high-velocity ionized outflow and XUV photosphere in the narrow emission line quasar PG1211+143

We report on the analysis of a ∼60-ks XMM–Newton observation of the bright, narrow emission line quasar PG1211+143. Absorption lines are seen in both European Photon Imaging Camera and Reflection Grating Spectrometer spectra corresponding to H- and He-like ions of Fe, S, Mg, Ne, O, N and C. The observed line energies indicate an ionized outflow velocity of ∼24 000 km s⁻¹. The highest energy lines require a column density of   N _H∼ 5 × 10²³ cm⁻²  , at an ionization parameter of  log ξ∼ 3.4  . If the origin of this high-velocity outflow lies in matter being driven from the inner disc, then the flow is likely to be optically thick within a radius of ∼130 Schwarzschild radii, providing a natural explanation for the big blue bump (and strong soft X-ray) emission in PG1211+143.     

Hysteresis‐based analysis of overland metal transport

Introducing a concept of equivalent mass depth of flow, this study describes the phenomenon of non‐point source pollutant (metal) transport for pavement (or overland) flow in analogy with wave propagation in wide open channels. Hysteretic and normal mass rating curves are developed for runoff rate and mass of 12 dissolved and particulate‐bound metal elements (pollutants) using the rainfall‐runoff and water quality data of the 15 × 20 m² instrumented pavement in Cincinnati, USA. Normal mass rating curves developed for easy computation of pollutant load are found to be of a form similar to Manning's, which is valid for open channel flows. Based on the hysteresis analysis, wave types for dissolution and mixing of particulate‐bound metals are identified. The analysis finds that the second‐order partial‐differential equation normally used for metal transport does not have the efficacy to describe fully the strong non‐linear phenomena such as is described for various metal elements by dynamic waves. In addition, the proportionality concept of the popular SCS‐CN concept is extended for determining the potential maximum metal mass M_p of all the 12 elements transported by a rain storm and related to the antecedent dry period (ADP). For the primary metal zinc element, M_p is found to increase with the ADP and vice versa. Copyright © 2003 John Wiley & Sons, Ltd.     

North European last glacial–interglacial transition (LGIT; 15–9 ka) tephrochronology: extended limits and new events

High‐precision correlation of palaeoclimatic and palaeoenvironmental records is crucial for testing hypotheses of synchronous change. Although radiocarbon is the traditional method for dating late Quaternary sedimentary sequences, particularly during the last glacial–interglacial transition (LGIT; 15–9 ka), there are inherent problems with the method, particularly during periods of climate change which are often accompanied by major perturbations in atmospheric radiocarbon content. An alternative method is the use of tephras that act as time‐parallel marker horizons. Within Europe, numerous volcanic centres are known to have erupted during the LGIT, providing considerable potential for high‐precision correlation independent of past radiocarbon fluctuations. Here we report the first identification of the Vedde Ash and Askja Tephra in Ireland, significantly extending the known provenance of these events. We have also identified two new horizons (the Roddans Port Tephras A and B) and tentatively recognise an additional horizon from Vallensgård Mose (Denmark) that provide crucial additional chronological control for the LGIT. Two phases of the Laacher See Tephra (LST) are reported, the lower Laacher See Tephra (LLST) and probably the C2 phase of the Middle Laacher See Tephra (MLST‐C2) indicating a more northeasterly distribution of this fan than reported previously. Copyright © 2006 John Wiley & Sons, Ltd.     

Intercomparison of the seasonal cycle of tropical surface stress in 17 AMIP atmospheric general circulation models

 The mean state of the tropical atmosphere is important as the nature of the coupling between the ocean and the atmosphere depends nonlinearly on the basic state of the coupled system. The simulation of the annual cycle of the tropical surface wind stress by 17 atmospheric general circulation models (AGCMs) is examined and intercompared. The models considered were part of the Atmospheric Model Intercomparison Project (AMIP) and were integrated with observed sea surface temperature (SST) for the decade 1979–1988. Several measures have been devised to intercompare the performance of the 17 models on global tropical as well as regional scales. Within the limits of observational uncertainties, the models under examination simulate realistic tropical area-averaged zonal and meridional annual mean stresses. This is a noteworthy improvement over older generation low resolution models which were noted for their simulation of surface stresses considerably weaker than the observations. The models also simulate realistic magnitudes of the spatial distribution of the annual mean surface stress field and are seen to reproduce realistically its observed spatial pattern. Similar features are observed in the simulations of the annual variance field. The models perform well over almost all the tropical regions apart from a few. Of these, the simulations over Somali are interesting. Over this region, the models are seen to underestimate the annual mean zonal and meridional stresses. There is also wide variance between the different models in simulating these quantities. Large model-to-model variations were also seen in the simulations of the annual mean meridional stress field over equatorial Indian Ocean, south central Pacific, north east Pacific and equatorial eastern Pacific oceans. It is shown that the systematic errors in simulating the surface winds are related to the systematic errors in simulating the Inter-Tropical Convergence Zone (ITCZ) in its location and intensity. Weaker than observed annual mean southwesterlies simulated by most models over Somali is due to weaker than observed southwesterlies during the Northern Hemisphere summer. This is related to the weaker than observed land precipitation simulated by most models during the Northern Hemisphere summer. The diversity in simulation of the surface wind over Somali and equatorial Indian ocean is related to the diversity of AGCMs in simulating the precipitation zones in these regions. Received: 2 August 1996 / Accepted: 7 February 1997