Acute toxicity of bromochlorinated seawater to selected estuarine species with a comparison to chlorinated seawater toxicity

The acute toxicity of bromochlorinated estuarine water (ca. 20%) was determined for several estuarine organisms. The most sensitive species were oysters (Crassostrea virginica, larvae and juveniles) and copepods (Acartia tonsa) with 48-h LC₅₀'s of 0·10 to 0·21 mg BrCl/litre. Palaemonetes pugio was most tolerant with a 96-h LC₅₀ of 0·70 mg BrCl/litre. The fish species tested (Menidia menidia, Brevoortia tyrannus and Leiostomus xanthurus) all had a 96-h LC₅₀ of 0·21–0·23 mg BrCl/litre.The BrCl toxicity data are compared with Cl₂ toxicity data for the same species. When the LC₅₀'s are expressed as equivalents per litre, BrCl is found to be two to four times less toxic than Cl₂. The ranking of species in terms of sensitivity is the same for both disinfectants.Some data are provided concerning the decay rates of BrCl and Cl₂ in estuarine water. BrCl was found to decay more rapidly than Cl₂ at higher ammonia levels (0·25 mg NH₄-N/litre). The question of chemical speciation is discussed with particular reference to the differential toxicities.     

Europan surface phenomena

The interaction of corotating iogenic plasma with the surface of Europa in light of recent ice sputtering, experimental results, and published Voyager data has been examined. It has been found that the residual atmosphere of Europa is made up of sputtered molecular oxygen and is exospheric from the surface outwards. It was also found that if sputtering, redistribution, and escape are considered and the sulfur dioxide/water mixing ratio is held constant over a UV observing depth, the observed sulfur dioxide density on the trailing hemisphere lends support to the hypothesis that liquid water from the interior of Europa is boiling out and being deposited as a frost layer on the surface at the rate of about 0.04 μm/year.     

Experimental study of the response of a gravel streambed to increased sediment supply

If increased sediment supply to a river channel exceeds its transport capacity, deposition necessarily occurs as the bed adjusts to accommodate the increased supply. Both the mean and spatial patterns in bed elevation and grain size may change and an ability to understand their relative importance is needed to predict bed response. We report on an experiment in a field‐scale flume in which sediment supply is increased to a gravel bed with alternate bars. Sediment was recirculated in the experiments, but augmented in two steps, after which the bed was allowed to reach a new steady state. The transport rate at the end of the experiment was three times larger than at the start. High‐resolution sediment flux and topographic measurements, grain size derived from photographs, and hydrodynamic modeling allow us to document the topographic and textural response of the bed to increased sediment supply. The spatial patterns of bed topography and texture were forced by the flume setup and the initial and final steady states included long stationary alternate bars with associated grain size sorting. The transient bed contained several scales of shorter wavelength migrating bedforms superimposed on, and temporarily replacing the stationary alternate bars. Bed topography and textural patterns adjusted to increased sediment supply over different timescales. Bed slope and mean stress increased directly with sediment supply rate to produce a new transport steady state in a time about 2.5 times the minimum needed to deposit the required sediment wedge, indicating a trap efficiency of about 40% for the aggrading wedge. Adjustments in local topography and sorting, primarily in the form of smaller, migrating bars, continued for a period approximately equal to that required to initially reach transport steady state. Copyright © 2013 John Wiley & Sons, Ltd.     

The sensitivity of climate simulations to the specification of mixed phase clouds

In the prognostic stratiform cloud scheme used in the UK Meteorological Office Unified Model, mixed phase clouds are assumed to exist between 0 and –15 °C. Recent observations of such clouds, carried out using the C-130 aircraft of the Meteorological Research Flight, suggest that a smaller range of 0 to –9°C may be more appropriate. The sensitivity of cloud and radiation fields as simulated by a 5 × 7.5° latitude-longitude version of the Unified Model to such a reduction in the temperature range of mixed phase clouds is considered. Using a smaller temperature range systematic errors in the radiation budget of the model are reduced in mid-latitudes, bringing the model into closer agreement with ERBE data. The sensitivity of model albedo to an increase in the temperature range over which mixed phase clouds are assumed to exist, suggested by previous observational studies, is also considered together with the impact of removing the mixed phase part of the precipitation parametrization altogether.     

Effect of chelation on toxicity of copper

Metals in the sea may form complexes with organic compounds, a process known as chelation, and this may modify their properties very greatly. Here the effect of chelation on the toxicity of copper to algae has been studied in the laboratory using the powerful chelating agent EDTA. Similar phenomena in the sea have implications both for anti-fouling paints, which usually contain copper, and for metal pollution in waters with a high organic content.